ChemicalBook > CAS DataBase List > 4-Bromobenzylamine hydrochloride

4-Bromobenzylamine hydrochloride

Product Name
4-Bromobenzylamine hydrochloride
CAS No.
26177-44-6
Chemical Name
4-Bromobenzylamine hydrochloride
Synonyms
4-BBA X HCL;4-BROMOBENZYLAMINE HCL;p-Bromo Benzylamine Hcl;4-BROMOBENZYLAMINE HYDROCHLORIDE;P-BROMOBENZYLAMINE HYDROCHLORIDE;4-Bromobenzylamine Hydrochloride >4-Bromobenzylamine hydrochloride,98%;4-BROMOBENZYLAMINE HYDROCHLORIDE 98%;4-Bromobenzylamine hydrochloride 99+%;(4-Bromophenyl)methamine hydrochloride
CBNumber
CB6136325
Molecular Formula
C7H9BrClN
Formula Weight
222.51
MOL File
26177-44-6.mol
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4-Bromobenzylamine hydrochloride Property

Melting point:
274-276 °C(lit.)
refractive index 
1,5855-1,5875
storage temp. 
Inert atmosphere,Room Temperature
form 
powder to crystal
color 
White to Almost white
Water Solubility 
Soluble in water.
Sensitive 
Hygroscopic
BRN 
3693458
InChI
InChI=1S/C7H8BrN.ClH/c8-7-3-1-6(5-9)2-4-7;/h1-4H,5,9H2;1H
InChIKey
BVYUYDBWQMSOKM-UHFFFAOYSA-N
SMILES
C1(CN)=CC=C(Br)C=C1.Cl
CAS DataBase Reference
26177-44-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-21/22
Safety Statements 
26-37/39-36/37/39-36
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29214900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
205214
Product name
4-Bromobenzylamine hydrochloride
Purity
98%
Packaging
5g
Price
$153
Updated
2025/07/31
TCI Chemical
Product number
B1841
Product name
4-Bromobenzylamine Hydrochloride
Purity
>97.0%(N)(T)
Packaging
5g
Price
$102
Updated
2025/07/31
TCI Chemical
Product number
B1841
Product name
4-Bromobenzylamine Hydrochloride
Purity
>97.0%(N)(T)
Packaging
25g
Price
$473
Updated
2025/07/31
TRC
Product number
B678305
Product name
4-Bromobenzylamine Hydrochloride
Packaging
10mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
J99793
Product name
4-BromobenzylamineHCl
Packaging
100g
Price
$185
Updated
2021/12/16
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4-Bromobenzylamine hydrochloride Chemical Properties,Usage,Production

Chemical Properties

OFF-WHITE TO BEIGE CRYSTALLINE POWDER

Uses

4-Bromobenzylamine hydrochloride is used to study the characteristics of C-terminal polyamine modification in the presence of protease and amine. Further, it is used to prepare 1-(4-Brombenzyl)-pyrrole by reacting with 2,5-dimethoxy-tetrahydro-furan.

Synthesis

623-00-7

26177-44-6

General procedure: in a glove box, to a flame-dried GLC vial fitted with a magnetic stirring bar was added [3a] + [BArF4]? (1.0 mol%) and Me2PhSiH(2a) (2.1 or 5.0 equivalents). The specified 4-bromobenzonitrile was added to the glove box (in case of solid material) or via a microsyringe outside the glove box. The resulting reaction mixture was kept at room temperature for the indicated time. Upon completion of the reaction, a mixture of cyclohexane and tert-butyl methyl ether (90:10) containing 4% Et3N (0.5 mL) was added to quench the reaction. The resulting solution was filtered through a diatomaceous earth pad coated with a small amount of silica gel, and a solution of cyclohexane and tert-butyl methyl ether (90:10) containing 4% Et3N (3-4 mL) was used as the eluent. The solvent was removed under reduced pressure and the residue was dissolved in Et2O (1 mL), followed by the addition of HCl (2M in Et2O, 1.0 mL, 2.0 mmol, 10 equiv). The resulting suspension was stirred for 1 h and filtered to give 4-bromobenzylamine hydrochloride as a white to yellow solid.

References

[1] Synlett, 2017, vol. 28, # 18, p. 2411 - 2414
[2] Tetrahedron, 2014, vol. 70, # 4, p. 975 - 983
[3] Tetrahedron Letters, 2009, vol. 50, # 50, p. 7005 - 7007
[4] Journal of the American Chemical Society, 2016, vol. 138, # 28, p. 8809 - 8814
[5] ACS Catalysis, 2018, vol. 8, # 10, p. 9125 - 9130

4-Bromobenzylamine hydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-Bromobenzylamine hydrochloride manufacturers

Career Henan Chemical Co
Product
4-Bromobenzylamine hydrochloride 26177-44-6
Price
US $3.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-04

26177-44-6, 4-Bromobenzylamine hydrochlorideRelated Search:

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  • P-BROMOBENZYLAMINE HYDROCHLORIDE
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  • 4-Bromobenzylamine hydrochloride,98%
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  • 4-Bromobenzylamine hydrochloride ISO 9001：2015 REACH
  • (4-Bromophenyl)methamine hydrochloride
  • 26177-44-6
  • C7H9BRNCl
  • BrC6H4CH2NH2HCl
  • C7H8BrNHCl
  • AMINE
  • Building Blocks
  • Amine Salts
  • Organic Building Blocks
  • Nitrogen Compounds
  • Piperidines ,Homopiperidines ,Heterocyclic Acids
  • Anilines, Aromatic Amines and Nitro Compounds
  • Anilines, Amides & Amines
  • Bromine Compounds
  • Amine Salts
  • Nitrogen Compounds
  • Organic Building Blocks