1,4,7-tris-Boc-1,4,7,10-tetraaza-cyclododecane
- Product Name
- 1,4,7-tris-Boc-1,4,7,10-tetraaza-cyclododecane
- CAS No.
- 175854-39-4
- Chemical Name
- 1,4,7-tris-Boc-1,4,7,10-tetraaza-cyclododecane
- Synonyms
- TriBoc-Cyclen;Cyclen Derivatives 1;N,N',N''-tris-Boc-cyclen;1,4,7-Tri-Boc-1,4,7,10-tetraazacyclododecane;1,4,7-tris-Boc-1,4,7,10-tetraaza-cyclododecane;1,4,7-tris-Boc-1,4,7,11-tetraaza-cyclododecane;1,4,7-tert butoxycarbonyl-1,4,7,10-tetraazacyclododecane;1,4,7-tris-Boc-1,4,7,10-tetraaza-cyclododecane (TriBOC-Cyclen);Tri-tert-Butyl 1,4,7,10-tetraazacyclododecane-1,4,7-tricarboxylate;Tri-tert-butyl 1,4,7,10-tetraazacyclotetradecane-1,4,7-tricarboxylate
- CBNumber
- CB61466593
- Molecular Formula
- C23H44N4O6
- Formula Weight
- 472.62
- MOL File
- 175854-39-4.mol
1,4,7-tris-Boc-1,4,7,10-tetraaza-cyclododecane Property
- Melting point:
- 72-73℃
- Boiling point:
- 542.8±35.0 °C(Predicted)
- Density
- 1.065
- storage temp.
- 2-8°C
- pka
- 9.52±0.20(Predicted)
- form
- powder
- Sensitive
- Hygroscopic
- InChI
- InChI=1S/C23H44N4O6/c1-21(2,3)31-18(28)25-12-10-24-11-13-26(19(29)32-22(4,5)6)15-17-27(16-14-25)20(30)33-23(7,8)9/h24H,10-17H2,1-9H3
- InChIKey
- ZXASHTYJQJMCQR-UHFFFAOYSA-N
- SMILES
- N1(C(OC(C)(C)C)=O)CCNCCN(C(OC(C)(C)C)=O)CCN(C(OC(C)(C)C)=O)CC1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 711683
- Product name
- 1,4,7-Tri-Boc-1,4,7,10-tetraazacyclododecane
- Purity
- 98%
- Packaging
- 250mg
- Price
- $495
- Updated
- 2022/05/15
- Product number
- 291462
- Product name
- 1,4,7-tri-Boc-1,4,7,10-tetraaza-cyclododecane
- Packaging
- 250mg
- Price
- $372
- Updated
- 2021/12/16
- Product number
- B662085
- Product name
- Tris-BOC-Cyclen
- Packaging
- 1g
- Price
- $580
- Updated
- 2021/12/16
- Product number
- AK103030
- Product name
- Tri-tert-Butyl1,4,7,10-tetraazacyclododecane-1,4,7-tricarboxylate
- Purity
- 97%
- Packaging
- 250mg
- Price
- $26
- Updated
- 2021/12/16
- Product number
- AK103030
- Product name
- Tri-tert-Butyl1,4,7,10-tetraazacyclododecane-1,4,7-tricarboxylate
- Purity
- 97%
- Packaging
- 1g
- Price
- $86
- Updated
- 2021/12/16
1,4,7-tris-Boc-1,4,7,10-tetraaza-cyclododecane Chemical Properties,Usage,Production
Chemical Properties
White powder
Uses
Building block used to attach the Cyclen azacrown to a molecular scaffold, building block for a trifold cyclen Zn complex as phosphate dianion receptor in aqueous solution
Synthesis
24424-99-5
294-90-6
175854-39-4
A solution of chloroform (10 mL) of di-tert-butyl dicarbonate (1.77 g, 8.12 mmol) was slowly added dropwise through a constant pressure dropping funnel to a solution of chloroform (40 mL) containing rotundin (0.51 g, 2.90 mmol) and triethylamine (1.25 mL, 8.99 mmol). The reaction mixture was stirred at room temperature overnight and then concentrated by rotary evaporator. The resulting crude product was purified by silica gel column chromatography using gradient elution from ethyl acetate to 5% methanol/dichloromethane to afford the target compound 1,4,7-tri-tert-butoxycarbonyl-1,4,7,10-tetraazacyclododecane as a white solid (1.02 g, 80% yield). The product characterization data were in agreement with literature reports.
References
[1] Journal of Materials Chemistry, 2012, vol. 22, # 36, p. 18784 - 18787
[2] Journal of the American Chemical Society, 2004, vol. 126, # 30, p. 9248 - 9256
[3] RSC Advances, 2016, vol. 6, # 28, p. 23645 - 23652
[4] Journal of Organic Chemistry, 2005, vol. 70, # 1, p. 115 - 123
[5] Chemical Communications, 2011, vol. 47, # 21, p. 6036 - 6038
1,4,7-tris-Boc-1,4,7,10-tetraaza-cyclododecane Preparation Products And Raw materials
Raw materials
Preparation Products
1,4,7-tris-Boc-1,4,7,10-tetraaza-cyclododecane Suppliers
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- sales@ajchem.in
- Country
- India
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View Lastest Price from 1,4,7-tris-Boc-1,4,7,10-tetraaza-cyclododecane manufacturers
- Product
- 1,4,7-tri-Boc-1,4,7,10-Tetraazacyclododecane 175854-39-4
- Price
- US $3.00-9.00/KG
- Min. Order
- 0.1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2025-06-27
- Product
- Tris-BOC-Cyclen 175854-39-4
- Price
- US $0.00/g
- Min. Order
- 5g
- Purity
- >95.00%
- Supply Ability
- 5g
- Release date
- 2024-04-01
- Product
- 1,4,7-tris-Boc-1,4,7,10-tetraaza-cyclododecane 175854-39-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.7%
- Supply Ability
- 100 tons
- Release date
- 2022-01-14