methyl 3-amino-5-chlorobenzoate
- Product Name
- methyl 3-amino-5-chlorobenzoate
- CAS No.
- 21961-31-9
- Chemical Name
- methyl 3-amino-5-chlorobenzoate
- Synonyms
- methyl 3-amino-5-chlorobenzoate;Methyl3-amino-5-chlorobenzoate98%;Methyl 3-amino-5-chlorobenzoate 98%;3-AMINO-5-CHLORO-BENZOIC ACID METHYL ESTER;Benzoic acid, 3-aMino-5-chloro-, Methyl ester
- CBNumber
- CB61561289
- Molecular Formula
- C8H8ClNO2
- Formula Weight
- 185.61
- MOL File
- 21961-31-9.mol
methyl 3-amino-5-chlorobenzoate Property
- Boiling point:
- 329.4±22.0 °C(Predicted)
- Density
- 1.311±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- pka
- 2.39±0.10(Predicted)
- Appearance
- White to yellow Solid
Safety
- HS Code
- 2916399090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M331700
- Product name
- Methyl3-Amino-5-chlorobenzoate
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 4H58-5-7E
- Product name
- Methyl 3-amino-5-chlorobenzoate
- Purity
- 98%
- Packaging
- 5G
- Price
- $576
- Updated
- 2021/12/16
- Product number
- HCH0044086
- Product name
- METHYL 3-AMINO-5-CHLOROBENZOATE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $925.31
- Updated
- 2021/12/16
- Product number
- X6549
- Product name
- Methyl3-amino-5-chlorobenzoate
- Packaging
- 1g
- Price
- $124
- Updated
- 2021/12/16
- Product number
- 4H58-5-7E
- Product name
- Methyl 3-amino-5-chlorobenzoate
- Purity
- 98%
- Packaging
- 1g
- Price
- $176
- Updated
- 2021/12/16
methyl 3-amino-5-chlorobenzoate Chemical Properties,Usage,Production
Synthesis
36138-28-0
21961-31-9
Step 2: Synthesis of methyl 3-amino-5-chlorobenzoate A dioxane solution (0.13 M) of methyl 3-chloro-5-nitrobenzoate (from Step 1) was placed in a reaction flask and SnCl2 (3.9 equiv) was added. The reaction mixture was stirred at 70 °C for 2 hours. After completion of the reaction, it was cooled to room temperature and EtOAc and saturated aqueous NaHCO3 solution was added. The reaction mixture was filtered to remove the precipitate formed. The aqueous phase was separated and extracted with EtOAc. All organic layers were combined and dried with anhydrous Na2SO4. Evaporation of the solvent under reduced pressure afforded the title compound methyl 3-amino-5-chlorobenzoate in 88% yield as a yellow solid. Mass spectrum (ES+) m/z 186,188 (M+H)+.
References
[1] Patent: WO2007/28789, 2007, A1. Location in patent: Page/Page column 35
[2] Patent: US2010/261687, 2010, A1. Location in patent: Page/Page column 60
methyl 3-amino-5-chlorobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
methyl 3-amino-5-chlorobenzoate Suppliers
- Tel
- --
- Fax
- --
- sales@apolloscientific.co.uk
- Country
- United Kingdom
- ProdList
- 6084
- Advantage
- 88
View Lastest Price from methyl 3-amino-5-chlorobenzoate manufacturers
- Product
- methyl 3-amino-5-chlorobenzoate 21961-31-9
- Price
- US $0.01/KG
- Min. Order
- 1KG
- Purity
- 98%; 99%
- Supply Ability
- 500g;1kg； 25kg
- Release date
- 2020-01-09