ChemicalBook > CAS DataBase List > 4-Chlorodiphenyl ether

4-Chlorodiphenyl ether

Product Name
4-Chlorodiphenyl ether
CAS No.
7005-72-3
Chemical Name
4-Chlorodiphenyl ether
Synonyms
SKL683;chlorodiphenylether;p-Chlorodiphenyloxide;4-CHLORODIPHENYLOXIDE;4-chlorophenoxybenzene;p-Chlorodiphenyl oxide;4-CHLORODIPHENYL ETHER;monochlorodiphenyloxide;PARA-CHLORODIPHENYLOXIDE;p-chlorophenylphenylether
CBNumber
CB6158961
Molecular Formula
C12H9ClO
Formula Weight
204.65
MOL File
7005-72-3.mol
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4-Chlorodiphenyl ether Property

Melting point:
-8 °C
Boiling point:
161-162 °C/19 mmHg (lit.)
Density 
1.193 g/mL at 25 °C (lit.)
vapor pressure 
2.7 x 10-3 mmHg at 25 °C (calculated, Branson, 1977)
refractive index 
n20/D 1.587(lit.)
Flash point:
>230 °F
storage temp. 
Refrigerator, under inert atmosphere
solubility 
3.3 mg/L at 25 °C (Branson, 1977)
form 
Liquid
Specific Gravity
1.193
color 
Colourless
Water Solubility 
3.3 mg/L (25 ºC)
Henry's Law Constant
2.2 x 10-4 atm?m3/mol(Pankow and Rosen, 1988)
CAS DataBase Reference
7005-72-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-chloro-4-phenoxy-(7005-72-3)
EPA Substance Registry System
p-Chlorophenyl phenyl ether (7005-72-3)
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Safety

Hazard Codes 
N-Xi,F,N,Xi,Xn
Risk Statements 
50/53-36/37/38-41-22-43
Safety Statements 
61-37/39-29-26-60-36/37/39
RIDADR 
UN 3082 9/PG 3
WGK Germany 
3
TSCA 
T
HS Code 
2909309090
Hazardous Substances Data
7005-72-3(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

P391Collect spillage. Hazardous to the aquatic environment

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
357650
Product name
4-Chlorodiphenyl ether
Purity
99%
Packaging
1g
Price
$64.5
Updated
2024/03/01
TRC
Product number
C292875
Product name
4-Chlorodiphenyl ether
Packaging
100mg
Price
$50
Updated
2021/12/16
TRC
Product number
C292875
Product name
4-Chlorodiphenyl ether
Packaging
10g
Price
$120
Updated
2021/12/16
Matrix Scientific
Product number
004220
Product name
4-Chlorodiphenyl ether
Purity
99%
Packaging
100g
Price
$215
Updated
2021/12/16
SynQuest Laboratories
Product number
2607-5-X4
Product name
4-Chlorodiphenyl ether
Purity
97%
Packaging
100g
Price
$240
Updated
2021/12/16
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4-Chlorodiphenyl ether Chemical Properties,Usage,Production

Chemical Properties

colorless to light yellow liquid

Uses

4-Chlorodiphenyl Ether is a standard for environmental testing and research. Biodegradability studies with organic priority pollutant compounds.

Uses

4-Chlorodiphenyl ether can be used in the preparation of 4′-chloro-2,2′,3,3′,4,5,5′,6,6′-nonabromodiphenyl ether (Cl-BDE-208), an internal standard used in the analysis of highly brominated diphenyl ethers.

Synthesis Reference(s)

The Journal of Organic Chemistry, 57, p. 391, 1992 DOI: 10.1021/jo00027a071

General Description

Liquid. Density 1.193 g / cm3. Insoluble or slightly soluble in water.

Air & Water Reactions

Insoluble or slightly soluble in water.

Reactivity Profile

4-Chlorodiphenyl ether oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164].

Fire Hazard

Combustible.

Environmental Fate

Biological. 4-Chlorophenyl phenyl ether (5 and 10 mg/L) did not significantly biodegrade following incubation in settled domestic wastewater inoculum at 25 °C. Percent losses reached a maximum after 2–3 wk but decreased thereafter suggesting a deadaptive process was occurring (Tabak et al., 1981). In activated sludge, a half-life of 4.0 h was measured (Branson, 1978).
Photolytic. In a methanolic solution irradiated with UV light (λ >290 nm), dechlorination of 4- chlorophenyl phenyl ether resulted in the formation of diphenyl ether (Choudhry et al., 1977). Photolysis of an aqueous solution containing 10% acetonitrile with UV light (λ = 230–400 nm) yielded 4-hydroxybiphenyl ether and chloride ion (Dulin et al., 1986).
At influent concentrations of 1.0, 0.1, 0.01, and 0.001 mg/L, the GAC adsorption capacities were 111, 61, 33, and 18 mg/g, respectively (Dobbs and Cohen, 1980).

4-Chlorodiphenyl ether Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Chlorodiphenyl ether Suppliers

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View Lastest Price from 4-Chlorodiphenyl ether manufacturers

Career Henan Chemical Co
Product
4-Chlorodiphenyl ether 7005-72-3
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
JD 336
Release date
2019-09-01

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