ChemicalBook > CAS DataBase List > (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
- Product Name
- (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
- CAS No.
- 148461-14-7
- Chemical Name
- (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
- Synonyms
- (S)-iPr-Phox;Diphenylphosphinophenylmethylethyldihydrooxazole;(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-;)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline;(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydroo;(-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE;2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole;(-)(4S)-2-[2-(Diphenylphosphino)phenyl]-4-(2-propyl)oxazoline 97%;(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
- CBNumber
- CB6159670
- Molecular Formula
- C24H24NOP
- Formula Weight
- 373.43
- MOL File
- 148461-14-7.mol
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(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Property
- Melting point:
- 85-90 °C
- alpha
- -44° (c 1.4, CHCl3)
- Boiling point:
- 492.7±28.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 4.31±0.70(Predicted)
- form
- Powder
- color
- white
- optical activity
- [α]20/D 48±3°, c = 1% in chloroform
- Sensitive
- air sensitive
- BRN
- 5879302
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 37/39-26-24/25
- WGK Germany
- 3
- F
- 10-23
- Hazard Note
- Irritant
- HS Code
- 29349990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 15-1822
- Product name
- (S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX
- Packaging
- 50mg
- Price
- $103
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1822
- Product name
- (S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX
- Packaging
- 250mg
- Price
- $361
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1822
- Product name
- (S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX
- Packaging
- 1g
- Price
- $1084
- Updated
- 2024/03/01
ChemScene
- Product number
- CS-W011786
- Product name
- (S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
- Purity
- >97.0%
- Packaging
- 250mg
- Price
- $68
- Updated
- 2021/12/16
AK Scientific
- Product number
- 5316AQ
- Product name
- (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole
- Packaging
- 250mg
- Price
- $599.6
- Updated
- 2021/12/16
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(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Chemical Properties,Usage,Production
Chemical Properties
White crystalline powder
Reactions
- Chiral ligand used in the asymmetric reduction of highly substituted olefins.
- Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
- Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
- Decarboxylative allylic alkylation.
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Preparation Products And Raw materials
Raw materials
Preparation Products
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(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Suppliers
- Tel
- --
- Fax
- --
- sales@apolloscientific.co.uk
- Country
- United Kingdom
- ProdList
- 6084
- Advantage
- 88
- Tel
- --
- Fax
- --
- kevinbanks@molekula.com
- Country
- United Kingdom
- ProdList
- 6140
- Advantage
- 66
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View Lastest Price from (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE manufacturers
XINXIANG RUNYU MATERIAL CO., LTD.
- Product
- (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE 148461-14-7
- Price
- US $0.00-0.00/g
- Min. Order
- 1g
- Purity
- 97%
- Supply Ability
- 5kg
- Release date
- 2024-03-22
Career Henan Chemical Co
- Product
- (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE 148461-14-7
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-10
148461-14-7, (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLERelated Search:
Phenyl phosphine
Oxazoline
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
(4R)-(+)-4,5-DIHYDRO-2-(2'-(DIPHENYLPHOSPHINO)PHENYL)-4-ISOPROPYLOXAZOLE
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
DIPHENYL(P-TOLYL)PHOSPHINE