4-BENZYLOXY-2-HYDROXYBENZALDEHYDE

Product Name: 4-BENZYLOXY-2-HYDROXYBENZALDEHYDE
CAS No.: 52085-14-0
Chemical Name: 4-BENZYLOXY-2-HYDROXYBENZALDEHYDE
Synonyms: 4-Benzyloxysalicylaldehyde;4-BENZYLOXY-2-HYDROXYBENZALDEHYDE;2-hydroxy-4-phenylmethoxybenzaldehyde;Benzaldehyde, 2-hydroxy-4-(phenylmethoxy)-
CBNumber: CB6170446
Molecular Formula: C14H12O3
Formula Weight: 228.24
MOL File: 52085-14-0.mol

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4-BENZYLOXY-2-HYDROXYBENZALDEHYDE Property

Melting point:: 78-80°C
Boiling point:: 165-175 °C(Press: 1 Torr)
Density: 1.238±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: solid
pka: 7.80±0.10(Predicted)
Appearance: Light brown to brown Solid
Sensitive: Air Sensitive
BRN: 982995

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Safety

Hazard Codes: Xi,N
Risk Statements: 36/37/38-50-43
Safety Statements: 26-36-61-36/37
HS Code: 2912210000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: CDS001087
Product name: 4-(Benzyloxy)-2-hydroxybenzaldehyde
Purity: AldrichCPR
Packaging: 250MG
Price: $73.1
Updated: 2025/07/31

TCI Chemical

Product number: H1904
Product name: 4-(Benzyloxy)-2-hydroxybenzaldehyde
Purity: min. 98.0 %
Packaging: 1G
Price: $45
Updated: 2025/07/31

TCI Chemical

Product number: H1904
Product name: 4-(Benzyloxy)-2-hydroxybenzaldehyde
Purity: min. 98.0 %
Packaging: 5G
Price: $135
Updated: 2025/07/31

TRC

Product number: B404978
Product name: 4-Benzyloxy-2-hydroxybenzaldehyde
Packaging: 100mg
Price: $60
Updated: 2021/12/16

TRC

Product number: B404978
Product name: 4-Benzyloxy-2-hydroxybenzaldehyde
Packaging: 500mg
Price: $75
Updated: 2021/12/16

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4-BENZYLOXY-2-HYDROXYBENZALDEHYDE Chemical Properties,Usage,Production

Synthesis

100-39-0

95-01-2

52085-14-0

2,4-Dihydroxybenzaldehyde (3.0 g, 1.0 eq.) was dissolved in acetonitrile (220 mL), sodium bicarbonate (2.2 eq.) was added at room temperature and stirred for 45 minutes. Subsequently, benzyl bromide (1.1 eq.) was slowly added to the reaction system. The reaction mixture was heated to reflux and stirred continuously. Upon completion of the reaction, the reaction was quenched with deionized water (100 mL) and subsequently extracted with ethyl acetate (3 x 25 mL). The organic phases were combined, washed with saturated saline (2 × 15 mL), dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to remove the solvent, to afford the crude product 4-phenylmethoxy-2-hydroxybenzaldehyde 12 as a white solid, which could be used in subsequent reactions without further purification.

References

[1] Bioorganic and Medicinal Chemistry, 2013, vol. 21, # 15, p. 4502 - 4510
[2] Synlett, 2011, # 11, p. 1605 - 1607
[3] Organic Process Research and Development, 2011, vol. 15, # 5, p. 1149 - 1162
[4] Tetrahedron Letters, 2013, vol. 54, # 31, p. 4121 - 4124
[5] Organic Letters, 2008, vol. 10, # 21, p. 5007 - 5010

4-BENZYLOXY-2-HYDROXYBENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BENZYLOXY-2-HYDROXYBENZALDEHYDE Suppliers

China 73 Germany 4 India 2 The Netherlands 1 United Kingdom 4 United States 11 Global 95

Meryer (Shanghai) Chemical Technology Co., Ltd.

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Advantage: 62

Alfa Aesar

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Energy Chemical

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Tel: 18030648795
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Country: China
ProdList: 1998
Advantage: 58

Wuhan TCASChem Technology Co., Ltd.

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Bide Pharmatech Ltd.

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ShangHai KenEn Chemical Technology Co., Ltd.

Tel: 13120367189
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ProdList: 1994
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Shanghai Xingui Biotechnology Co., Ltd.

Tel: 15121041756
Email: xingui2022@126.com
Country: China
ProdList: 9979
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View Lastest Price from 4-BENZYLOXY-2-HYDROXYBENZALDEHYDE manufacturers

Career Henan Chemical Co

Product: 4-BENZYLOXY-2-HYDROXYBENZALDEHYDE 52085-14-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%-99.9%
Supply Ability: 200KG
Release date: 2020-01-07

52085-14-0, 4-BENZYLOXY-2-HYDROXYBENZALDEHYDERelated Search:

FUMARPROTOCETRARIC ACID LECANORIC ACID GYROPHORIC ACID 4'-BENZYLOXY-2'-HYDROXY-3'-METHYLACETOPHENONE ATRANORIN 4'-BENZYLOXY-2'-METHOXY-3'-METHYLACETOPHENONE EVERNIC ACID Salicylaldehyde STICTIC ACID KS 502 LOBARIC ACID 4'-Benzyloxy-2'-hydroxyacetophenone 5-(benzyloxy)-2-hydroxybenzaldehyde 4-(Benzyloxy)-3-hydroxybenzaldehyde p-Toluenesulfonate 4-BENZYLOXY-3-HYDROXYBENZALDEHYDE PHYSODIC ACID 1-[4-(BENZYLOXY)-2-HYDROXYPHENYL]-3-(4-METHOXYPHENYL)PROP-2-EN-1-ONE 2,4-BIS(BENZYLOXY)BENZALDEHYDE

Benzaldehyde, 2-hydroxy-4-(phenylmethoxy)-

2-hydroxy-4-phenylmethoxybenzaldehyde

4-BENZYLOXY-2-HYDROXYBENZALDEHYDE

4-Benzyloxysalicylaldehyde

52085-14-0

ALDEHYDE