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DIETHYL ETHYLIDENEMALONATE

Product Name
DIETHYL ETHYLIDENEMALONATE
CAS No.
1462-12-0
Chemical Name
DIETHYL ETHYLIDENEMALONATE
Synonyms
Diethylidene malonate;DIETHYL ETHYLIDENEMALONATE;Diethyl 2-ethylidenemalonate;Diethyl ethylideneMalonate 99%;Diethyl 2-ethylidenemalonate 95+%;diethyl 2-ethylidenepropanedioate;Diethyl 1-propene-1,1-dicarboxylate;1,3-diethyl 2-ethylidenepropanedioate;2-ethylidenemalonic acid diethyl ester;Diethyl 2-ethylidenepropane-1,3-dioate
CBNumber
CB6195614
Molecular Formula
C9H14O4
Formula Weight
186.21
MOL File
1462-12-0.mol
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DIETHYL ETHYLIDENEMALONATE Property

Boiling point:
115-118 °C/17 mmHg (lit.)
Density 
1.019 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.442(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
liquid
color 
Clear, colourless
Specific Gravity
1.019
BRN 
1773932
InChI
InChI=1S/C9H14O4/c1-4-7(8(10)12-5-2)9(11)13-6-3/h4H,5-6H2,1-3H3
InChIKey
LBBAWVLUOZVYCC-UHFFFAOYSA-N
SMILES
C(OCC)(=O)/C(=C/C)/C(OCC)=O
CAS DataBase Reference
1462-12-0(CAS DataBase Reference)
EPA Substance Registry System
Propanedioic acid, ethylidene-, diethyl ester (1462-12-0)
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Safety

Hazard Codes 
Xi
Safety Statements 
24/25
WGK Germany 
3
HS Code 
2917198090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P342+P311IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
D94801
Product name
Diethyl ethylidenemalonate
Purity
99%
Packaging
5g
Price
$80.7
Updated
2025/07/31
TCI Chemical
Product number
D4827
Product name
Diethyl Ethylidenemalonate
Purity
min. 95.0 %
Packaging
5G
Price
$115
Updated
2025/07/31
TCI Chemical
Product number
D4827
Product name
Diethyl Ethylidenemalonate
Purity
min. 95.0 %
Packaging
25G
Price
$345
Updated
2025/07/31
SynQuest Laboratories
Product number
2323-1-33
Product name
Diethyl 2-ethylidenemalonate
Packaging
10g
Price
$92
Updated
2021/12/16
SynQuest Laboratories
Product number
2323-1-33
Product name
Diethyl 2-ethylidenemalonate
Packaging
25g
Price
$183
Updated
2021/12/16
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DIETHYL ETHYLIDENEMALONATE Chemical Properties,Usage,Production

Uses

Diethyl Ethylidenemalonate is a useful intermediate for 1,4-addition and [3+2] cycloaddition reactions and in 2,4-dienoates synthesis.

Preparation

Diethyl ethylidenemalonate is obtained by heating paraldehyde, Acetic Anhydride, and Diethyl Malonate.

storage

Store at 5 °C. Use in a fume hood.

DIETHYL ETHYLIDENEMALONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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DIETHYL ETHYLIDENEMALONATE Suppliers

Apollo Scientific Ltd.
Tel
--
Fax
--
Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
Advantage
88
CARBONE SCIENTIFIC CO.,LTD
Tel
--
Fax
--
Email
sales@carbonesci.com
Country
United Kingdom
ProdList
6666
Advantage
30
UK GREEN SCIENTIFIC CO.,LIMITED
Tel
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Fax
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Email
sales@gs-chem.com
Country
United Kingdom
ProdList
6098
Advantage
47
ARIAC - Armenian Institute of Applied Chemistry
Tel
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Fax
--
Email
ariac@web.am
Country
United Kingdom
ProdList
2466
Advantage
46
Eurolabs Limited
Tel
--
Fax
--
Country
United Kingdom
ProdList
6309
Advantage
46
VWR International
Tel
--
Fax
--
Email
solutions@vwr.com
Country
United Kingdom
ProdList
6548
Advantage
82
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View Lastest Price from DIETHYL ETHYLIDENEMALONATE manufacturers

Career Henan Chemical Co
Product
DIETHYL ETHYLIDENEMALONATE 1462-12-0
Price
US $1.00/KG
Min. Order
1IU
Purity
99.0%
Supply Ability
100kg
Release date
2020-01-07

1462-12-0, DIETHYL ETHYLIDENEMALONATERelated Search:


  • Diethyl 2-ethylidenemalonate
  • Propanedioic acid, ethylidene-, diethyl ester
  • DIETHYL ETHYLIDENEMALONATE
  • Diethyl 2-ethylidenepropane-1,3-dioate
  • 1-Propene-1,1-dicarboxylic acid diethyl ester
  • Diethyl 1-propene-1,1-dicarboxylate
  • 2-ethylidenemalonic acid diethyl ester
  • diethyl 2-ethylidenepropanedioate
  • Diethyl ethylideneMalonate 99%
  • nonanoic acid [3-(1-oxononoxy)-2,2-bis(1-oxononoxymethyl)propyl] ester
  • Diethyl 2-ethylidenemalonate 95+%
  • Diethylidene malonate
  • Propanedioic acid, 2-ethylidene-, 1,3-diethyl ester
  • 1,3-diethyl 2-ethylidenepropanedioate
  • 1462-12-0
  • CH3CHCCO2C2H52
  • Building Blocks
  • Carbonyl Compounds
  • C8 to C9
  • Esters
  • Organic Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Esters