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tert-Butyl nitrite

Product Name
tert-Butyl nitrite
CAS No.
540-80-7
Chemical Name
tert-Butyl nitrite
Synonyms
t-BuNO2;T-BUTYL NITRITE;t-butyl ester;2-Methyl-2-nitrosooxy-propane;ert-buty nitrite;t-Buthyl nitrite;ert-Butylnitrite;Tert-buty nitrite;TERT-BUTYL NITRITE;TIMTEC-BB SBB007659
CBNumber
CB6853772
Molecular Formula
C4H9NO2
Formula Weight
103.12
MOL File
540-80-7.mol
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tert-Butyl nitrite Property

Boiling point:
61-63 °C(lit.)
Density 
0.867 g/mL at 25 °C(lit.)
vapor pressure 
13.466kPa at 25℃
refractive index 
n20/D 1.368(lit.)
Flash point:
−10 °F
storage temp. 
2-8°C
solubility 
alcohol: very soluble(lit.)
form 
Liquid
color 
Clear yellow
Water Solubility 
slightly soluble
Merck 
14,1583
BRN 
1209339
LogP
2.24 at 20℃
CAS DataBase Reference
540-80-7(CAS DataBase Reference)
NIST Chemistry Reference
(CH3)3CONO(540-80-7)
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Safety

Hazard Codes 
F,Xn
Risk Statements 
11-20/22
Safety Statements 
16-24-46
RIDADR 
UN 2351 3/PG 2
WGK Germany 
1
RTECS 
RA0802000
8
HazardClass 
3
PackingGroup 
II
HS Code 
29209085
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
20370
Product name
tert-Butyl nitrite
Purity
technical, ≥90% (GC)
Packaging
100mL
Price
$92
Updated
2024/03/01
Sigma-Aldrich
Product number
20370
Product name
tert-Butyl nitrite
Purity
technical, ≥90% (GC)
Packaging
500mL
Price
$323
Updated
2024/03/01
TCI Chemical
Product number
N0357
Product name
tert-Butyl Nitrite
Purity
>90.0%(GC)
Packaging
25mL
Price
$65
Updated
2024/03/01
TCI Chemical
Product number
N0357
Product name
tert-Butyl Nitrite
Purity
>90.0%(GC)
Packaging
250mL
Price
$392
Updated
2024/03/01
Alfa Aesar
Product number
L16135
Product name
tert-Butyl nitrite
Purity
tech. 90%
Packaging
25g
Price
$35.4
Updated
2023/06/20
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tert-Butyl nitrite Chemical Properties,Usage,Production

Chemical Properties

clear yellow liquid

Uses

tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

Uses

Jet propellant.

General Description

tert-Butyl nitrite (TBN) is an efficient NO source. TBN participates in photocatalyzed conversion of aryl- and heteroarylamines to selenides. It also participates in radical multifunctionalization reactions of aliphatic alkenes.

Purification Methods

If it is free from OH bands (IR) then distil it through a 12inch helices packed column under reduced pressure, otherwise wash with aqueous 5% NaHCO3 (effervescence), then H2O, dry (Na2SO4) and fractionate it through a 10 theoretical plates column at ca 10mm pressure. [Allen J Chem Soc 1968 1954, Coe & Doumani J Am Chem Soc 70 1516 1948, UV: Ungnade & Smiley J Org Chem 21 993 1956, IR: Terte Bull Soc Chim Belg 60 240 1951, Beilstein 1 IV 1622.]

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tert-Butyl nitrite Suppliers

Shanghai Heng Pan Biological Medicine Co., LTD
Tel
18217762875
Email
2136632918@qq.com
Country
China
ProdList
41
Advantage
58
Yangzhou Aoxin Chemical Co., Ltd
Tel
0514-87754778 13901446058
Fax
+86-514-87752291
Email
sales@aochem.com
Country
China
ProdList
73
Advantage
66
Changzhou Xiaqing Technological Co., Ltd.
Tel
519-519-88783621 13906127738
Fax
+86-519-88495082
Email
xjq@xialichem.com
Country
China
ProdList
170
Advantage
70
Hebei mo Jin biotechnology co., ltd
Tel
15097329902
Fax
18503279000
Email
sales@hebeimojin.com
Country
China
ProdList
2254
Advantage
58
Chongqing Xingcan Pharmaceutical Technology Co., Ltd.
Tel
15523000485
Email
xingcanyaoye@sina.com
Country
China
ProdList
1686
Advantage
58
Wuhan Yuqing Jiaheng Pharmaceutical Co., Ltd.
Tel
027-83850122 13343472658
Email
918571372@qq.com
Country
China
ProdList
1809
Advantage
58
Shanghai Yanze Chemical Co., Ltd.
Tel
15345144255
Email
260924549@qq.com
Country
China
ProdList
3134
Advantage
58
Shandong Hongyuan Chemical Technology Co., LTD
Tel
13561560789
Email
xinxiaoxiao2008@126.com
Country
China
ProdList
353
Advantage
58
Changzhou Liren Medical Technology Co. Ltd.
Tel
0519-85859058 13915836899
Email
2078957504@qq.com
Country
China
ProdList
178
Advantage
58
Creasyn Finechem(Tianjin) Co., Ltd.
Tel
022-022-83946278 13820372920
Fax
022-83945176
Email
sales@creasyn.com
Country
China
ProdList
1002
Advantage
68
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View Lastest Price from tert-Butyl nitrite manufacturers

airuikechemical co., ltd.
Product
Tert-Butyl nitrite 540-80-7
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.99%
Supply Ability
20 tons
Release date
2024-04-10
Henan Fengda Chemical Co., Ltd
Product
t-butyl nitrite 540-80-7
Price
US $8.00-0.80/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-22
Hebei Yanxi Chemical Co., Ltd.
Product
tert-Butyl nitrite 540-80-7
Price
US $50.00/KG
Min. Order
25KG
Purity
98%
Supply Ability
200 tons
Release date
2020-07-14

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