tert-Butyl nitrite

Product Name: tert-Butyl nitrite
CAS No.: 540-80-7
Chemical Name: tert-Butyl nitrite
Synonyms: t-BuNO2;T-BUTYL NITRITE;t-butyl ester;2-Methyl-2-nitrosooxy-propane;ert-buty nitrite;t-Buthyl nitrite;ert-Butylnitrite;Tert-buty nitrite;TERT-BUTYL NITRITE;TIMTEC-BB SBB007659
CBNumber: CB6853772
Molecular Formula: C4H9NO2
Formula Weight: 103.12
MOL File: 540-80-7.mol

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tert-Butyl nitrite Property

Boiling point:: 61-63 °C(lit.)
Density: 0.867 g/mL at 25 °C(lit.)
vapor pressure: 13.466kPa at 25℃
refractive index: n20/D 1.368(lit.)
Flash point:: −10 °F
storage temp.: 2-8°C
solubility: alcohol: very soluble(lit.)
form: Liquid
color: Clear yellow
Water Solubility: slightly soluble
Merck: 14,1583
BRN: 1209339
LogP: 2.24 at 20℃
CAS DataBase Reference: 540-80-7(CAS DataBase Reference)
NIST Chemistry Reference: (CH3)3CONO(540-80-7)

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Safety

Hazard Codes: F,Xn
Risk Statements: 11-20/22
Safety Statements: 16-24-46
RIDADR: UN 2351 3/PG 2
WGK Germany: 1
RTECS: RA0802000
F: 8
HazardClass: 3
PackingGroup: II
HS Code: 29209085

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 20370
Product name: tert-Butyl nitrite
Purity: technical, ≥90% (GC)
Packaging: 100mL
Price: $92
Updated: 2024/03/01

Sigma-Aldrich

Product number: 20370
Product name: tert-Butyl nitrite
Purity: technical, ≥90% (GC)
Packaging: 500mL
Price: $323
Updated: 2024/03/01

TCI Chemical

Product number: N0357
Product name: tert-Butyl Nitrite
Purity: >90.0%(GC)
Packaging: 25mL
Price: $65
Updated: 2024/03/01

TCI Chemical

Product number: N0357
Product name: tert-Butyl Nitrite
Purity: >90.0%(GC)
Packaging: 250mL
Price: $392
Updated: 2024/03/01

Alfa Aesar

Product number: L16135
Product name: tert-Butyl nitrite
Purity: tech. 90%
Packaging: 25g
Price: $35.4
Updated: 2023/06/20

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tert-Butyl nitrite Chemical Properties,Usage,Production

Chemical Properties

clear yellow liquid

Uses

tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

Uses

Jet propellant.

General Description

tert-Butyl nitrite (TBN) is an efficient NO source. TBN participates in photocatalyzed conversion of aryl- and heteroarylamines to selenides. It also participates in radical multifunctionalization reactions of aliphatic alkenes.

Purification Methods

If it is free from OH bands (IR) then distil it through a 12inch helices packed column under reduced pressure, otherwise wash with aqueous 5% NaHCO3 (effervescence), then H2O, dry (Na2SO4) and fractionate it through a 10 theoretical plates column at ca 10mm pressure. [Allen J Chem Soc 1968 1954, Coe & Doumani J Am Chem Soc 70 1516 1948, UV: Ungnade & Smiley J Org Chem 21 993 1956, IR: Terte Bull Soc Chim Belg 60 240 1951, Beilstein 1 IV 1622.]

tert-Butyl nitrite Preparation Products And Raw materials

Raw materials

Silver nitrate 2-Chloro-2-methylpropane Nitrogen Tetroxide NITRIC OXIDE

Preparation Products

8-Quinolineboronic acid 2-Bromo-5-hydroxypyridine radical ion(1+) 2-Chloro-5-cyano-3-methylpyridine Goserelin 2-CHLORO-5-IODO-3-METHYLPYRIDINE 4,7-DIHYDRO-4-OXO-3H-PYRROLO[2,3-D][1,2,3]TRIAZINE-5-CARBOXAMIDE 2-Bromo-5-fomylthiazole

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tert-Butyl nitrite Suppliers

Americas 1 Belgium 2 China 320 Europe 3 Germany 7 India 40 Italy 1 Japan 6 Switzerland 5 Ukraine 1 United Kingdom 12 United States 38 Global 436

GLR Innovations

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View Lastest Price from tert-Butyl nitrite manufacturers

Hebei Yanxi Chemical Co., Ltd.

Product: tert-Butyl nitrite 540-80-7
Price: US $50.00/KG
Min. Order: 25KG
Purity: 98%
Supply Ability: 200 tons
Release date: 2020-07-14

airuikechemical co., ltd.

Product: Tert-Butyl nitrite 540-80-7
Price: US $0.00-0.00/Kg
Min. Order: 1Kg
Purity: 99.99%
Supply Ability: 20 tons
Release date: 2024-04-10

Hebei Chuanghai Biotechnology Co,.LTD

Product: tert-Butyl nitrite 540-80-7
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-23

540-80-7, tert-Butyl nitriteRelated Search:

Isoamyl nitrite POTASSIUM NITRITE 1-Butyl nitrite Buprofezin Isobutyl nitrite BUTYL OLEATE Sodium nitrite Dibutyl phthalate Cyhalofop-butyl NITROUS ACID Pentyl nitrite ISOPROPYL NITRITE Nitrite ion standard solution SODIUM NITRITE-15N SODIUM COBALTINITRITE Nitrite solution standard substance Nitrosobenzene DIETHYL ETHYLIDENEMALONATE

TERT-BUTYL NITRITE: TECH., 90%

1,1-dimethylethylnitrite

2-methyl-2-nitritopropane

alpha,alpha-Dimethylethyl nitrite

alpha,alpha-dimethylethylnitrite

2-methyl-2-propyl nitrite

tert-Butyl nitrite, technical, 90%

tert-Butyl nitrite 90%

tert-Butyl nitrite technical, >=90% (GC)

ert-buty nitrite

tert-Butyl nitrite, 90%, pure

Nitrous acid tert-butyl

t-butyl ester

2-Methyl-2-nitrosooxy-propane

tert-Butyl nitrite ,95%

Tert-buty nitrite

tert-Butyl nitrite, pure, 90% 500GR

1,1-diMethylethyl ester Nitrous acid

TERT-BUTYL NITRITE FOR SYNTHESIS

t-BuNO2

Nitrous acid, 1,1-dimethylethyl ester

Nitrous acid, t-butyl ester

nitrousacid,1,1-dimethylethylester

nitrousacid,t-butylester

T-BUTYL NITRITE

TERT-BUTYL NITRITE

NITROUS ACID TERT-BUTYL ESTER

TIMTEC-BB SBB007659

tert-Butylnitrite,tech.90%

tert-Butyl nitrite, pure, 90%

t-Buthyl nitrite

α，α-Dimethylethyl nitrite

tert-Butyl nitrite, 95%, for synthesis

1,1-Dimethylethyl Nitrite (~90%)

tert-ButylNitrite&gt

ert-Butylnitrite

TERT-BUTYL NITRITE 540-80-7

tert-Butylnitrite,technical,90%

alpha,alpha-DimethylethylnitriChemicalbookte

α，α-Dimethylethyl nitrite

Tterobutyrate nitrite

tert-Butyl nitrite (6CI, 7CI)

tert-Butyl nitrite(TBN)

Borane-methyl sulfide complex 10m in Dimethylsilfide

Tertiary butyl nitrite

tert-Butyl Nitrite, ≥ 90.0%

tert-Butyl nitrite - 90% purity by G.C

540-80-7

CH33CONO

Organic Building Blocks

Nitrogen Compounds

Organic Nitrates/Nitrites

Building Blocks

Nitrogen Compounds

Organic Building Blocks

Organic Nitrates/Nitrites

Imidazoles

straight chain compounds