DIBENZYL MALONATE

Product Name: DIBENZYL MALONATE
CAS No.: 15014-25-2
Chemical Name: DIBENZYL MALONATE
Synonyms: MALONIC ACID DIBENZYL ESTER;NSC 101027;Dibenzylmalonat;DIBENZYL MALONATE;Dibenzylmalonateca;DibenzylMalonate>D**DIBENZYL MALONATE;Malonic acid dibenzyl;Dibenzyl propanedioate;2,5-Dimethyl-3-Hezine-Diol
CBNumber: CB6222040
Molecular Formula: C17H16O4
Formula Weight: 284.31
MOL File: 15014-25-2.mol

More

Less

DIBENZYL MALONATE Property

Boiling point:: 188 °C/0.2 mmHg (lit.)
Density: 1.137 g/mL at 25 °C (lit.)
refractive index: n20/D 1.546(lit.)
Flash point:: >230 °F
storage temp.: Sealed in dry,Room Temperature
pka: 11.65±0.46(Predicted)
form: clear liquid
color: Colorless to Light yellow to Light orange
Specific Gravity: 1.17
Water Solubility: Sparingly soluble in water; miscible in all proportions with ether and alcohol.
BRN: 1998264
InChIKey: RYFCSKVXWRJEOB-UHFFFAOYSA-N
CAS DataBase Reference: 15014-25-2(CAS DataBase Reference)

More

Less

Safety

Safety Statements: 23-24/25
WGK Germany: 3
HS Code: 29171910

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 160407
Product name: Dibenzyl malonate
Packaging: 10g
Price: $76.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 160407
Product name: Dibenzyl malonate
Packaging: 50g
Price: $145.8
Updated: 2024/03/01

TCI Chemical

Product number: M1080
Product name: Dibenzyl Malonate
Purity: >95.0%(GC)
Packaging: 25g
Price: $103
Updated: 2024/03/01

TCI Chemical

Product number: M1080
Product name: Dibenzyl Malonate
Purity: >95.0%(GC)
Packaging: 100g
Price: $254
Updated: 2024/03/01

Alfa Aesar

Product number: A10844
Product name: Dibenzyl malonate, 95%
Packaging: 10g
Price: $53.65
Updated: 2024/03/01

More

Less

DIBENZYL MALONATE Chemical Properties,Usage,Production

Chemical Properties

CLEAR YELLOWISH LIQUID

Uses

Dibenzyl malonate was used in the preparation of tetraethyl 3,3-bis(benzyloxycarbonyl)propylene bisphosphonate. It was also used in the preparation of benzyl umbelliferone-3-carboxylate via Knoevenagel condensation with 2,4-dihydroxybezaldehyde.

General Description

Direct asymmetric reaction of dibenzyl malonate with N-tert-butoxycarbonyl aldimines in the presence of Yb(OTf)₃ and iPr-pybox (pybox = pyridine bisoxazoline) complexes has been investigated.

Purification Methods

Dissolve the ester in toluene, wash it with aqueous NaHCO3, H2O, dry over MgSO4, filter, evaporate and distil it at high vacuum. [Ginsburg & Pappo J Am Chem Soc 75 1094 1953, Baker et al. J Org Chem 17 77 1952, Beilstein 6 IV 2270.]

DIBENZYL MALONATE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

DIBENZYL MALONATE Suppliers

Americas 1 Belgium 3 China 117 Europe 1 Germany 4 India 4 Japan 5 Sweden 1 Switzerland 2 United Kingdom 5 United States 23 Global 166

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

TCI Japan

Tel: --
Fax: --
Email: @TCIchemicals.com
Country: Japan
ProdList: 2741
Advantage: 58

FUJIFILM Wako Pure Chemical Corporation

Tel: --
Fax: --
Email: ffwk-cservice@fujifilm.com
Country: Japan
ProdList: 6222
Advantage: 58

Wako Pure Chemical Industries, Ltd.

Tel: --
Fax: --
Email: labchem-tec@wako-chem.co.jp
Country: Japan
ProdList: 6819
Advantage: 80

Kanto Chemical Co., Inc.

Tel: --
Fax: --
Email: reag-info@gms.kanto.co.jp
Country: Japan
ProdList: 6756
Advantage: 74

More

Less

View Lastest Price from DIBENZYL MALONATE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: Propanedioicacid,bis(phenylmethyl)ester 15014-25-2
Price: US $0.00-0.00/KG
Min. Order: 10mg
Purity: 99%HPLC
Supply Ability: 2000tons
Release date: 2020-01-19

Henan Aochuang Chemical Co.,Ltd.

Product: DIBENZYL MALONATE 15014-25-2
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-17

Career Henan Chemical Co

Product: DIBENZYL MALONATE 15014-25-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kg
Release date: 2019-08-30

15014-25-2, DIBENZYL MALONATERelated Search:

Dimethyl malonate 3-tert-Butoxy-3-oxopropanoic acid 1-Methoxy-2-propanol Di-tert-Butyl malonate TERT-BUTYL ETHYL MALONATE Ethyl potassium malonate Diisopropyl malonate Maleic acid ricinoleate p-Cresol DIBENZYL MALONATE MALONIC ACID BIS(4-NITROBENZYL) ESTER BOC-L-GLA(OBZL)2-OH BOC-DL-GLA(OBZL)2-OH FMOC-DL-GLA(OBZL)2-OH DIBENZYL MALONATE, (MALONIC ACID DIBENZYL ESTER) BOC-D-GLA(OBZL)2-OH FMOC-D-GLA(OBZL)2-OH FMOC-L-GLA(OBZL)2-OH

Propanedioic acid, bis(phenylmethyl) ester

Dibenzyl malonate, tech., 90%

propanedioic acid dibenzyl ester

MALONIC ACID DIBENZYL ESTER

2,5-Dimethyl-3-Hezine-Diol

Dibenzylmalonateca

Malonic acid dibenzyl ester~Propanedioic acid dibenzyl ester

DIBENZYL MALONATE

Propanedioicacid,bis(phenylmethyl

Dibenzylmalonat

D**DIBENZYL MALONATE

Dibenzyl malonate,90%,tech.

Propanedioic acid, 1,3-bis(phenylMethyl) ester

NSC 101027

Malonic acid dibenzyl

DibenzylMalonate&gt

Dibenzyl propanedioate

2-{2,3-Bis[(E)-2-phenylvinyl]phenoxy}ethanol

15014-25-2

CH2CO2CH2C6H52

CH2CO2C6H52

Organic Building Blocks

Esters

Carbonyl Compounds

C12 to C63

Building Blocks

C12 to C63

Carbonyl Compounds

Chemical Synthesis

Organic Building Blocks

C12 to C63

Carbonyl Compounds

Esters