Performance
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Irganox 3052

Performance
Product Name
Irganox 3052
CAS No.
61167-58-6
Chemical Name
Irganox 3052
Synonyms
AN GM;HS 3052;At 3052;AO-3052;JADEADD GM;JADEWIN GM;Sumilizer GM;IRGANOX 3052;antioxygenGM;PowerNox 3052
CBNumber
CB6254573
Molecular Formula
C26H34O3
Formula Weight
394.55
MOL File
61167-58-6.mol
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Irganox 3052 Property

Melting point:
128-133°C
Boiling point:
491℃
Density 
1.03
Flash point:
185℃
storage temp. 
-20°C Freezer, Under inert atmosphere
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
pka
11.66±0.48(Predicted)
form 
Solid
color 
White to Off-White
Water Solubility 
123ng/L at 20℃
EPA Substance Registry System
2-tert-Butyl-6-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl acrylate (61167-58-6)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P321Specific treatment (see … on this label).

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
I764150
Product name
Irganox3052
Packaging
500mg
Price
$285
Updated
2021/12/16
TRC
Product number
I764150
Product name
Irganox3052
Packaging
1g
Price
$550
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM1031222
Product name
IRGANOX 3052
Purity
95.00%
Packaging
5MG
Price
$503.64
Updated
2021/12/16
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Irganox 3052 Chemical Properties,Usage,Production

Performance

2,2′-methylenebis(6-tert-butyl-4-methylphenol) monoacrylate, (also known under the trade names Sumilizer GM, BNX 3052, and Irganox 3052), is a heat and light stabilizer and an antioxidant used in a wide range of adhesive, plastic, and elastomer materials. Unlike traditional phenolic stabilizers/antioxidants, this substance is an effective alkyl radical scavenger. This property is especially useful in processes at high temperatures and in low oxygen environments, such as during the initial mixing of adhesives.
The stabilizing mechanism involves trapping of polymer alkyl radicals at the double bond of the acrylate group, and subsequent hydrogen transfer from the intramolecular hydrogen-bonded phenolic hydroxyl group, which results in a stable phenoxyl radical. 2,2′-methylenebis(6-tert-butyl-4-methylphenol) monoacrylate may also be grafted using the acrylate moeity.

Description

Irganox 3052 is an antioxidant. It contains 2-(1,1-dimethylethyl)-6-[[3-(1,1-dimethylethyl)-2-hydroxy-5-methylphenylymethyl-4-methylphenyl acrylate. It is non-staining, non-discoloring, has a low volatility and is resistant to extraction. It protects organic substrates against both, thermo-oxidative and purely thermal degradation. It is particularly active under high processing temperature and anaerobic polymerization and processing conditions. It is compatible with HIPS, ABS, BR, IIR, SBR, SBS, SEBS, EPDM, EPM, MBS, MABS, SMA, modified acrylate, hydrocarbon resins, terpene, terpene phenolic resins, rosin, polycarbonates, polyester-carbonates, polymethacrylates, polyolefins, polyamides or polyphenyleneoxides. Irganox 3052 is suitable for food contact applications. It is listed in AICS, EINECS, PICCS, DSL, MITI, TSCA, CHINA and ECL.

Uses

Irganox 3052 has been used in to study the mechanical properties and performance of stretch films of plasticized PVC and non-PVC alternatives used for retail fresh meat packaging; heat stabilizers for butadiene-styrene copolymers;

Flammability and Explosibility

Not classified

Synthesis

To a 2-liter four-necked flask equipped with a thermometer, stirring apparatus, condenser and dropping funnel were added 340.51 g (1.0 mol) of 2,2'-methylenebis(6-tert-butyl-4-methylphenol), 72.06 g (1.0 mol) of acrylic acid, 500 g of toluene and 209.47 g (2.07 mol) of triethylamine. After replacing the air in the container with nitrogen, 105.8 g (0.69 mol) of phosphorus oxychloride was added dropwise with stirring. After completion of the dropwise addition, the reaction solution was kept at 80 ℃. for 1 hour. After that, the organic layer was washed with water until it became neutral, and toluene was removed under reduced pressure. The residue was then recrystallized from n-hexane to obtain 374.8 g of a white crystalline 2,2'-methylenebis(6-tert-butyl-4-methylphenol) monoacrylate (Irganox 3052) having a melting point of 132 to 134 ℃. Yield, 95%.

Irganox 3052 Preparation Products And Raw materials

Raw materials

Preparation Products

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Irganox 3052 Suppliers

Tianjin Zhongxin Chemtech Co., Ltd.
Tel
022-66880623
Fax
86(0)22-66880086
Email
sales@tjzxchem.com
Country
China
ProdList
613
Advantage
60
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14103
Advantage
59
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
Chemwill Asia Co.,Ltd.
Tel
86-21-51086038
Fax
86-21-51861608
Country
China
ProdList
2930
Advantage
58
Deltachem (Qingdao) Co., Ltd
Tel
18766299236
Fax
0532-68856119
Email
summerzhai@deltachem.net
Country
China
ProdList
163
Advantage
58
Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939 15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
16166
Advantage
55
Hangzhou J&H Chemical Co., Ltd.
Tel
0571-+86-571-87396432
Fax
0571-87396431
Email
sales@jhechem.com
Country
China
ProdList
11497
Advantage
59
Qingdao Jade New Material Technology
Tel
0532-68077006 13658692156
Fax
0532-68077006
Email
zandrew@jadenmtc.com
Country
China
ProdList
310
Advantage
58
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View Lastest Price from Irganox 3052 manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Antioxidant 3052 61167-58-6
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
98%min
Supply Ability
1000kg
Release date
2021-08-25
Qingdao Truelight functional Material Technology Co., Ltd.
Product
ANTIOXIDANT TRUELICHT GM 61167-58-6
Price
US $0.00/KG
Min. Order
1drums
Purity
98.0%
Supply Ability
20 tons
Release date
2021-11-22
QINGDAO JADE NEW MATERIAL TECNOLOGY CO.,LTD
Product
antioxidant GM 61167-58-6
Price
US $0.00/KG
Min. Order
25KG
Purity
98%
Supply Ability
20 tons
Release date
2019-10-10

61167-58-6, Irganox 3052Related Search:


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