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Copper(II) phthalocyanine

Product Name
Copper(II) phthalocyanine
CAS No.
147-14-8
Chemical Name
Copper(II) phthalocyanine
Synonyms
CUPC;PIGMENT BLUE 15;PHTHALOCYANINE BLUE;COPPER PHTHALOCYANINE;CI 74160;COPPER(II) PHTHALOCYANINE;cyanine blue;C.I. Pigment Blue 15:1;C.I. Pigment Blue 15:3;Monastral blue
CBNumber
CB6255035
Molecular Formula
C32H16CuN8
Formula Weight
576.07
MOL File
147-14-8.mol
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Copper(II) phthalocyanine Property

Melting point:
600°C (dec.)
Density 
1.62[at 20℃]
storage temp. 
Inert atmosphere,Room Temperature
solubility 
insoluble in H2O, ethanol; soluble in concHSO 4
Colour Index 
74160
form 
Fine Crystalline Powder
color 
Dark blue
Odor
odorless
Water Solubility 
<0.1 g/100 mL at 20 ºC
λmax
602nm(CHCl3)(lit.)
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Merck 
14,2520
BRN 
4121848
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChIKey
XCJYREBRNVKWGJ-UHFFFAOYSA-N
LogP
-1 at 23℃
NIST Chemistry Reference
Copper phthalocyanine(147-14-8)
EPA Substance Registry System
C.I. Pigment Blue 15 (147-14-8)
Absorption
λmax 678 nm (DMF)
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Safety

Safety Statements 
22-24/25
WGK Germany 
-
RTECS 
GL8510000
TSCA 
Yes
HS Code 
32041300
Hazardous Substances Data
147-14-8(Hazardous Substances Data)
Toxicity
LD50 intraperitoneal in rat: > 3gm/kg
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
252980
Product name
Copper(II) phthalocyanine
Purity
β-form, Dye content 90 %
Packaging
5g
Price
$34.5
Updated
2024/03/01
Sigma-Aldrich
Product number
252980
Product name
Copper(II) phthalocyanine
Purity
β-form, Dye content 90 %
Packaging
25g
Price
$59.3
Updated
2024/03/01
TCI Chemical
Product number
P0655
Product name
Pigment Blue 15
Packaging
25g
Price
$64
Updated
2024/03/01
TCI Chemical
Product number
P1005
Product name
Copper(II) Phthalocyanine (α-form)
Purity
>90.0%(T)
Packaging
25g
Price
$21
Updated
2024/03/01
Alfa Aesar
Product number
043650
Product name
Copper(II) phthalocyanine
Packaging
10g
Price
$36
Updated
2024/03/01
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Copper(II) phthalocyanine Chemical Properties,Usage,Production

Description

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor?with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV).?Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer . CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device . Device stability was achieved by?depositing a copper phthalocyanine CuPc hole-injection layer?HIL on the ITO anode.

Chemical Properties

dark blue fine crystalline powder

Uses

Copper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. Photoisomerizable phthalocyanines are used in rewritable CD or DVD printing.Other applications in organic solar cells, biosensitizers and display devices such as OLED , OTFT, Wearable Display, and e-paper.

Application

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV). Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer.
CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device. Device stability was achieved by depositing a copper phthalocyanine CuPc hole-injection layer HIL on the ITO anode. The improved stability could be contributed to the good match of its highest-occupied molecular orbital (HOMO) level to the work function of ITO, and the improved wetting property of organic materials on ITO. Moreover, CuPc has very weak absorption of light, with wavelengths from 400 to 500 nm, making it suitable for use in blue and green OLEDs.
Effective electron-blocking was also observed for inorganic&ndash;organic hybrid perovskite solar cells when CuPc-doped spiro-OMeTAD was used as the hole-transporting layer.

General Description

Copper(II) phthalocynaine (CuPc) is a metal phthalocyanine dye that acts as a p-type semiconductor. It has a charge mobility of 10-4 cm2/Vs. It forms a chemically stable thin film that exhibits photoconductivity and catalytic activity.

Flammability and Explosibility

Not classified

Purification Methods

Precipitate it twice from conc H2SO4 by slow dilution with water. It has also been purified by two or three sublimations at 580o in an argon flow at 300-400Pa. [Beilstein 26 III/IV 4256.]

Properties and Applications

TEST ITEMS

SPECIFICATION

APPEARANCE

BLUE POWDER

SHADE

REDDISH

HEAT RESISTANCE

300 °C min

LIGHT FASTNESS

7-8

ACID RESISTANCE

5

ALKALI RESISTANCE

5

FASTNESS TO BLEEDING

5

OIL ABSORPTION

40-45%

SPECIFIC SURFACE

29 m 2 /g

DENSITY

1.60 g/cm 3

RESIDUE ON 80 MESH

5.0% max

WATER SOLUBLE

1.0% max

VOLATITE 105 °C

1.0% max

TINTING STRENGTH

100-105 %

Toxics Screening Level

The initial threshold screening level (ITSL) for phthalocyanine blue is 21 μg/m3 (annual average).

Copper(II) phthalocyanine Preparation Products And Raw materials

Raw materials

Xylene FUMING SULFURIC ACID Copper(II) chloride dihydrate Ammonium molybdate tetrahydrate Potassium iodide Calcium chloride Chlorine Ammonium molybdate Urea Ammonium chloride Copper(II) chloride dihydrate Copper(I) chloride Phthalic anhydride Hydrochloric acid Sodium hydroxide 1,2,4-Trichlorobenzene Sulfuric acid Zinc stearate

Preparation Products

4923 Spirit Light Fast Ball-pen Blue GR Reactive Turquoise Blue Kn-G Various color alkyd primer Various color amino baking enamel A04-9 POLYSULFONE Alkyd enamel CI Pigment Blue 15:3 (74160) Direct Blue 199 Various color nitrocellulose exterior enamel Q04-2 Amino resin paint Reactive Blue 231 Direct Blue 86 Chromium(III) oxide Reactive Blue 14 Ferro phthalocyanine green Pigment Geen 7 Sulphur Green 14
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View Lastest Price from Copper(II) phthalocyanine manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
CuPC 147-14-8
Price
US $0.00/g
Min. Order
1g
Purity
99.5%
Supply Ability
100kgs
Release date
2021-09-16
Hebei Andu Technology Com.,Ltd
Product
Copper(II) phthalocyanine 147-14-8
Price
US $3.50/kg
Min. Order
1kg
Purity
≥99%
Supply Ability
3000tons/month
Release date
2024-08-17
Hebei Weibang Biotechnology Co., Ltd
Product
Copper(II) phthalocyanine 147-14-8
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5tons
Release date
2024-11-04

147-14-8, Copper(II) phthalocyanineRelated Search:

Iron(III) phthalocyanine-4,4',4'',4'''-tetrasulfonic acid,compound with oxygen monosodium salt hydrate Dye content 80 % COBALT(II) PHTHALOCYANINE Pigment Yellow 110 3,4,9,10-Perylenetetracarboxylic diimide Pigment Yellow 147 Vat Orange 3 Pigment Red 190 Direct Blue 86 ALCIAN BLUE 8GX 2,9,16,23-TETRAPHENOXY-29H,31H-PHTHALOCYANINE COPPER(II) 2,3-NAPHTHALOCYANINE TETRAKIS(4-CUMYLPHENOXY)PHTHALOCYANINE Copper(II) phthalocyanine [1,3,8,16,18,24-hexabromo-2,4,9,10,11,15,17,22,23,25-decachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper DILITHIUM PHTHALOCYANINE [2,9,16,23-tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper (SP-4-1)-[1,8,15,22-Tetrakis[2-methyl-1-(1-methylethyl)propoxy]-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper [trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

  • Copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (SP-4-1)- Copper, [phthalocyaninato(2-)]-
  • phthalocyanine blueB15:0
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  • ciingrainblue2
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  • congoblueb-4
  • Copper phthalocyanine,CI 74160
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  • copper,(29h,31h-phthalocyaninato(2-)-n(sup29),n(sup30),n(sup31),n(sup32)
  • Copper,[29H,31H-phthalocyaninato(2(-))-N<sup>29</sup>,N<sup>30</sup>,N<sup>31</sup>,N<sup>32</sup>]-(SP-4-1)-
  • copperphthalocyanin
  • copperphthalocyanineblue
  • cromophtalblue4g
  • cyanbluebnc55-3745
  • cyanbluebnf55-3753
  • cyanbluegt55-3295
  • cyaninebluebb
  • CyanineBlueBB,BF,GC,HB,LB
  • cyaninebluec
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  • dainichicyanineblueb
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  • daltolitefastblueb
  • duratintblue1001
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  • heliofastbluebrn
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  • heliogenblueb
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  • HostapermBlueAFN,A3R
  • indolenblue3g
  • irgalitefastbrilliantbluebl
  • isolfastblueb
  • lbx5
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  • phthaloblue
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  • pigmentblue15:4
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