ChemicalBook > CAS DataBase List > Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate

Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate

Product Name
Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate
CAS No.
135321-84-5
Chemical Name
Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate
Synonyms
Methyl-4- (N-BOC-aMidino) benzoate;Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate;methyl 4-[N'-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]benzoate;Benzoic acid, 4-[[[(1,1-dimethylethoxy)carbonyl]amino]iminomethyl]-, methyl ester
CBNumber
CB62651442
Molecular Formula
C14H18N2O4
Formula Weight
278.3
MOL File
135321-84-5.mol
More
Less

Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate Property

Density 
1.15±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
pka
9.73±0.46(Predicted)
Appearance
White to off-white Solid
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

TRC
Product number
M330073
Product name
Methyl4-(N-(tert-butoxycarbonyl)carbamimidoyl)benzoate
Packaging
50mg
Price
$110
Updated
2021/12/16
ChemScene
Product number
CS-0037726
Product name
Methyl4-[N'-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]benzoate
Packaging
250mg
Price
$53
Updated
2021/12/16
ChemScene
Product number
CS-0037726
Product name
Methyl4-[N'-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]benzoate
Packaging
1g
Price
$106
Updated
2021/12/16
Matrix Scientific
Product number
131935
Product name
Methyl4-(N-(tert-butoxycarbonyl)-carbAmimidoyl)benzoate
Purity
97%
Packaging
1g
Price
$424
Updated
2021/12/16
AK Scientific
Product number
2256AQ
Product name
METHYL4-(N-(TERT-BUTOXYCARBONYL)CARBAMIMIDOYL)BENZOATE
Packaging
5g
Price
$447.2
Updated
2021/12/16
More
Less

Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate Chemical Properties,Usage,Production

Synthesis

24424-99-5

50466-15-4

135321-84-5

Example 17: Methyl 4-(N-carbamoylimino)benzoate (2.18 g, 9.18 mmol) and triethylamine (1.02 mL, 7.32 mmol) were dissolved in anhydrous methanol (100 mL), followed by addition of di-tert-butyl dicarbonate (3.0 g, 13.8 mmol). The reaction mixture was heated at 40 °C for 5 h under nitrogen protection. After completion of the reaction, the mixture was cooled and concentrated under reduced pressure. The resulting residue was diluted with ethyl acetate (100 mL) and subsequently washed with aqueous sodium bicarbonate. The aqueous layer was then extracted with dichloromethane (2 x 30 mL). The organic phases were combined, dried and concentrated. Purification by fast column chromatography (silica gel, 80 g, eluent: 0-30% ethyl acetate/hexane) afforded methyl 4-(N-(tert-butoxycarbonyl)formamidinyl)benzoate as a white solid (1.98 g, 77% yield).The NMR (500 MHz, CDCl3) data were as follows: δ 8.09 (d, 2H), 7.91 (d, 2H), 3.94 (s 3H), 1.55 (s, 9H); no amidine NH protons were observed.

References

[1] Patent: WO2013/174937, 2013, A1. Location in patent: Page/Page column 81
[2] Patent: US2015/152048, 2015, A1. Location in patent: Paragraph 0487-0488

Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate Suppliers

China 50 India 1 United States 2 Global 53
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9309
Advantage
66
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
18270980682
Fax
021 51613951
Email
mlcheng@sunwaypharm.cn
Country
China
ProdList
8669
Advantage
57
Nanjing JinruiJiuAn Biotechnology Co., Ltd.
Tel
025-58196018 800028039
Fax
025-83453306
Email
sales@fartop.net
Country
China
ProdList
2229
Advantage
55
Shanghai Yolne Chemical Co., Ltd.
Tel
021-62960152
Fax
021-52212593
Email
934678158@qq.com
Country
China
ProdList
9899
Advantage
55
AstaTech (Chengdu) Pharma. Co., Ltd.
Tel
15928766785 15928766785
Fax
QQ961458712
Email
wupengcheng@astatech.cn
Country
China
ProdList
1987
Advantage
55
Suzhou yacoo science co.,Ltd
Tel
0512-87182056 18013166090
Fax
0512-87182056
Email
lingling.qi@yacoo.com.cn
Country
China
ProdList
6295
Advantage
60
NINGBO INNO PHARMCHEM CO.,LTD.
Tel
86-574-27787657
Fax
86-574-27912196
Email
info@dearchem.com
Country
China
ProdList
4613
Advantage
58
SanoChem (Chengdu) Tech. Co., Ltd.
Tel
28-87999436 02887999436
Fax
QQ:2746983436
Email
sales@sano-chem.com
Country
China
ProdList
3795
Advantage
55
Nanjing River Chemical Co., Ltd.
Tel
13951936332 18305166317
Fax
-
Email
info@serpharm.com
Country
China
ProdList
493
Advantage
55
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Jiaxing Deyi Chemical Co., Ltd.
Tel
86-0573-85866609 13325730825
Fax
0573-85866609
Email
945717149@qq.com
Country
China
ProdList
8595
Advantage
58
Aikon International Limited
Tel
025-58851090 15955137747
Fax
(6)02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
15949
Advantage
58
Henan Alfachem Co.,Ltd.
Tel
0371-55051623 18137891487
Fax
QQ：2853979817
Email
2853979817@qq.com
Country
China
ProdList
9981
Advantage
58
3A Chemicals
Tel
400-668-9898
Fax
010-51582189
Email
service@3achem.com
Country
China
ProdList
20557
Advantage
58
Nanjing crow LuNing pharmaceutical technology co., LTD
Tel
13382066392
Country
CHINA
ProdList
4877
Advantage
58
Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
4009004166/18616739031 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52687
Advantage
58
Hefei Molake Biotechnology Co., Ltd.
Tel
0551-66336380 18956014586
Fax
055166336380
Email
983438788@qq.com
Country
China
ProdList
2297
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
+86-0551-65418684 +8618949823763
Fax
0086-551-65418684
Email
sales@tnjchem.com
Country
China
ProdList
25356
Advantage
58
Blocksynth Pharmaceutical Technology Co.,Ltd
Tel
0086-19817745290; +8619817745290
Email
bd@blocksynth.com
Country
China
ProdList
5661
Advantage
58
Dayang Chem (Hangzhou) Co.,Ltd.
Tel
+86-0571-88938639 +8617705817739
Fax
+86-571-88938652，+86-571- 88492614
Email
info@dycnchem.com
Country
China
ProdList
52846
Advantage
58
Baoji Guokang Healthchem co.,ltd
Tel
+8615604608665 15604608665
Email
dominicguo@gk-bio.com
Country
CHINA
ProdList
9414
Advantage
58
AFINE CHEMICALS LIMITED
Tel
+86-0571-85134551
Fax
008657185134895
Email
sales@afinechem.com
Country
China
ProdList
15107
Advantage
58
Guizhou Yituo Chemical Technology Co., Ltd
Tel
18628235590
Fax
QQ:444176500
Email
wuliming@yituochem.cn
Country
China
ProdList
1242
Advantage
58
Neostar United (Changzhou) Industrial Co., Ltd.
Tel
+86-0519-85551759 +8613506123987
Fax
+0086-519-85557389
Email
marketing1@neostarunited.com
Country
China
ProdList
8830
Advantage
58
Wuhan Topule
Tel
+86-02787215551 +86-19945035818
Fax
027-87215551
Email
2936752263@qq.com
Country
China
ProdList
7984
Advantage
58
Shaanxi Dideu Medichem Co. Ltd
Tel
029-81124267 17392282731
Fax
029-88380327
Email
1073@dideu.com
Country
China
ProdList
9992
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 4008210725
Email
malulu@leyan.com
Country
China
ProdList
40000
Advantage
58
AstaTech(Chengdu) Biopharmaceutical Corp.
Tel
028-82666846 18080826311
Fax
QQ 2917178106
Email
sales@astatech.com.cn
Country
China
ProdList
499
Advantage
58
Bide Pharmatech Ltd.
Tel
400-6005915
Email
sales@picasso-e.com
Country
China
ProdList
39653
Advantage
58
Nanjing Wogni Chemical Co., Ltd.
Tel
15996452985
Email
foxerhy@163.com
Country
China
ProdList
4939
Advantage
58
Henan Dobe Chemical Co. , Ltd.
Tel
0370-6999054 17550096163
Email
3189729795@qq.com
Country
China
ProdList
7172
Advantage
58
Beijing Solarbio Science & Tecnology Co., Ltd.
Tel
010-50973130 17801761073
Email
Gsiyu@solarbio.com
Country
China
ProdList
50464
Advantage
58
https://www.shachemlin.cn/
Tel
021-68080707 18079794756
Email
soloman.lee@chemlin.com.cn
Country
China
ProdList
8480
Advantage
58
Ningbo Zhenyue Pharmaceutical Technology Co., Ltd
Tel
19817745290
Email
bd@blocksynth.com
Country
China
ProdList
5870
Advantage
58
Jining Yize Pharmaceutical Technology Co., Ltd
Tel
15192473210
Email
302633902@qq.com
Country
China
ProdList
4480
Advantage
58
Tiancheng Chemical (Jiangsu) Co., Ltd
Tel
0512-66387919 18662433356
Email
18662433356@163.com
Country
China
ProdList
10970
Advantage
58
Jiangsu Xinsu New Materials Co., Ltd
Tel
0512-66387919 15251950002
Email
15251950002@163.com
Country
China
ProdList
11046
Advantage
58
Nanxing Chemical (Jiangsu) Co., Ltd
Tel
0512-66387035 18662433356
Email
18662433356@163.com
Country
China
ProdList
10929
Advantage
58
Anyang Xiyan Technology Co., LTD
Tel
17525889330
Email
17525889330@163.com
Country
China
ProdList
7849
Advantage
58
career henan chemical co
Tel
+86-0371-86658258 +8613203830695
Email
sales@coreychem.com
Country
China
ProdList
29846
Advantage
58
Nanjing ChemLin Chemical Industry Co., Ltd.
Tel
025-83697070
Email
product@chemlin.com.cn
Country
CHINA
ProdList
3009
Advantage
60
Zibo Hangyu Biotechnology Development Co., Ltd
Tel
+86-0533-2185556 +8615965530500
Email
nickzhang@hangyubiotech.com
Country
China
ProdList
8510
Advantage
58
Shanghai Scibiotron Pharmaceutical Co., Ltd
Tel
+86-16621589600
Email
contact@scibiotron.com
Country
China
ProdList
5535
Advantage
58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Tel
+86-13017695106 +86-13676922317
Email
jiuyitime@fdachem.com
Country
China
ProdList
16513
Advantage
58
HANGZHOU LEAP CHEM CO., LTD.
Tel
+86-571-87711850
Email
market18@leapchem.com
Country
China
ProdList
43339
Advantage
58
Zhengzhou Lingzhiyue Technology Co., Ltd
Tel
+86-0371-55074660 +8613523716970
Email
Lingzhiyue@aliyun.com
Country
China
ProdList
3145
Advantage
58
GIHI CHEMICALS CO.,LIMITED
Tel
+8618058761490
Email
info@gihichemicals.com
Country
China
ProdList
49934
Advantage
58
AstaTech(Chengdu) Biopharmaceutical Corp.
Tel
+86-02882666559 +86-15884417729
Email
gjpu@astatech.com.cn
Country
China
ProdList
308
Advantage
58
Lianyungang Kelian Chemical Co., Ltd.
Tel
--
Fax
--
Email
sales@klinechem.com
Country
CHINA
ProdList
507
Advantage
58
Ganyu Unitechemical Co., Ltd
Tel
--
Fax
--
Email
sales@unitechemical.com
Country
China
ProdList
207
Advantage
38
More
Less

View Lastest Price from Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate 135321-84-5
Price
US $2.00-6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-07-30
Career Henan Chemical Co
Product
Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate 135321-84-5
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg; 2kg；10kg; 100kg
Release date
2019-08-30

135321-84-5, Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoateRelated Search:


  • Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate
  • Methyl-4- (N-BOC-aMidino) benzoate
  • methyl 4-[N'-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]benzoate
  • Benzoic acid, 4-[[[(1,1-dimethylethoxy)carbonyl]amino]iminomethyl]-, methyl ester
  • 135321-84-5