Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate

Product Name: Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate
CAS No.: 135321-84-5
Chemical Name: Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate
Synonyms: Methyl-4- (N-BOC-aMidino) benzoate;Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate;methyl 4-[N'-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]benzoate;Benzoic acid, 4-[[[(1,1-dimethylethoxy)carbonyl]amino]iminomethyl]-, methyl ester
CBNumber: CB62651442
Molecular Formula: C14H18N2O4
Formula Weight: 278.3
MOL File: 135321-84-5.mol

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Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate Property

Density: 1.15±0.1 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 9.73±0.46(Predicted)
Appearance: White to off-white Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M330073
Product name: Methyl4-(N-(tert-butoxycarbonyl)carbamimidoyl)benzoate
Packaging: 50mg
Price: $110
Updated: 2021/12/16

ChemScene

Product number: CS-0037726
Product name: Methyl4-[N'-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]benzoate
Packaging: 250mg
Price: $53
Updated: 2021/12/16

ChemScene

Product number: CS-0037726
Product name: Methyl4-[N'-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]benzoate
Packaging: 1g
Price: $106
Updated: 2021/12/16

Matrix Scientific

Product number: 131935
Product name: Methyl4-(N-(tert-butoxycarbonyl)-carbAmimidoyl)benzoate
Purity: 97%
Packaging: 1g
Price: $424
Updated: 2021/12/16

AK Scientific

Product number: 2256AQ
Product name: METHYL4-(N-(TERT-BUTOXYCARBONYL)CARBAMIMIDOYL)BENZOATE
Packaging: 5g
Price: $447.2
Updated: 2021/12/16

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Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate Chemical Properties,Usage,Production

Synthesis

24424-99-5

50466-15-4

135321-84-5

Example 17: Methyl 4-(N-carbamoylimino)benzoate (2.18 g, 9.18 mmol) and triethylamine (1.02 mL, 7.32 mmol) were dissolved in anhydrous methanol (100 mL), followed by addition of di-tert-butyl dicarbonate (3.0 g, 13.8 mmol). The reaction mixture was heated at 40 °C for 5 h under nitrogen protection. After completion of the reaction, the mixture was cooled and concentrated under reduced pressure. The resulting residue was diluted with ethyl acetate (100 mL) and subsequently washed with aqueous sodium bicarbonate. The aqueous layer was then extracted with dichloromethane (2 x 30 mL). The organic phases were combined, dried and concentrated. Purification by fast column chromatography (silica gel, 80 g, eluent: 0-30% ethyl acetate/hexane) afforded methyl 4-(N-(tert-butoxycarbonyl)formamidinyl)benzoate as a white solid (1.98 g, 77% yield).The NMR (500 MHz, CDCl3) data were as follows: δ 8.09 (d, 2H), 7.91 (d, 2H), 3.94 (s 3H), 1.55 (s, 9H); no amidine NH protons were observed.

References

[1] Patent: WO2013/174937, 2013, A1. Location in patent: Page/Page column 81
[2] Patent: US2015/152048, 2015, A1. Location in patent: Paragraph 0487-0488

Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate Suppliers

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ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate 135321-84-5
Price: US $2.00-6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-07-30

Career Henan Chemical Co

Product: Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate 135321-84-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg; 2kg；10kg; 100kg
Release date: 2019-08-30

135321-84-5, Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoateRelated Search:

Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate

Methyl-4- (N-BOC-aMidino) benzoate

methyl 4-[N'-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]benzoate

Benzoic acid, 4-[[[(1,1-dimethylethoxy)carbonyl]amino]iminomethyl]-, methyl ester

135321-84-5