Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate
- Product Name
- Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate
- CAS No.
- 135321-84-5
- Chemical Name
- Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate
- Synonyms
- Methyl-4- (N-BOC-aMidino) benzoate;Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate;methyl 4-[N'-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]benzoate;Benzoic acid, 4-[[[(1,1-dimethylethoxy)carbonyl]amino]iminomethyl]-, methyl ester
- CBNumber
- CB62651442
- Molecular Formula
- C14H18N2O4
- Formula Weight
- 278.3
- MOL File
- 135321-84-5.mol
Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate Property
- Density
- 1.15±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C
- pka
- 9.73±0.46(Predicted)
- Appearance
- White to off-white Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M330073
- Product name
- Methyl4-(N-(tert-butoxycarbonyl)carbamimidoyl)benzoate
- Packaging
- 50mg
- Price
- $110
- Updated
- 2021/12/16
- Product number
- CS-0037726
- Product name
- Methyl4-[N'-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]benzoate
- Packaging
- 250mg
- Price
- $53
- Updated
- 2021/12/16
- Product number
- CS-0037726
- Product name
- Methyl4-[N'-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]benzoate
- Packaging
- 1g
- Price
- $106
- Updated
- 2021/12/16
- Product number
- CS-0037726
- Product name
- Methyl4-[N'-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]benzoate
- Packaging
- 5g
- Price
- $319
- Updated
- 2021/12/16
- Product number
- 131935
- Product name
- Methyl4-(N-(tert-butoxycarbonyl)-carbAmimidoyl)benzoate
- Purity
- 97%
- Packaging
- 1g
- Price
- $424
- Updated
- 2021/12/16
Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate Chemical Properties,Usage,Production
Synthesis
24424-99-5
50466-15-4
135321-84-5
Example 17: Methyl 4-(N-carbamoylimino)benzoate (2.18 g, 9.18 mmol) and triethylamine (1.02 mL, 7.32 mmol) were dissolved in anhydrous methanol (100 mL), followed by addition of di-tert-butyl dicarbonate (3.0 g, 13.8 mmol). The reaction mixture was heated at 40 °C for 5 h under nitrogen protection. After completion of the reaction, the mixture was cooled and concentrated under reduced pressure. The resulting residue was diluted with ethyl acetate (100 mL) and subsequently washed with aqueous sodium bicarbonate. The aqueous layer was then extracted with dichloromethane (2 x 30 mL). The organic phases were combined, dried and concentrated. Purification by fast column chromatography (silica gel, 80 g, eluent: 0-30% ethyl acetate/hexane) afforded methyl 4-(N-(tert-butoxycarbonyl)formamidinyl)benzoate as a white solid (1.98 g, 77% yield).The NMR (500 MHz, CDCl3) data were as follows: δ 8.09 (d, 2H), 7.91 (d, 2H), 3.94 (s 3H), 1.55 (s, 9H); no amidine NH protons were observed.
References
[1] Patent: WO2013/174937, 2013, A1. Location in patent: Page/Page column 81
[2] Patent: US2015/152048, 2015, A1. Location in patent: Paragraph 0487-0488
Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate Preparation Products And Raw materials
Raw materials
Preparation Products
Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate Suppliers
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- sales@ajchem.in
- Country
- India
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View Lastest Price from Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate manufacturers
- Product
- Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate 135321-84-5
- Price
- US $2.00-6.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-07-30
- Product
- Methyl 4-(N-(tert-butoxycarbonyl)carbaMiMidoyl)benzoate 135321-84-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1kg; 2kg；10kg; 100kg
- Release date
- 2019-08-30