ChemicalBook > CAS DataBase List > Ethyl 3-oxocyclohexane-1-carboxylate

Ethyl 3-oxocyclohexane-1-carboxylate

Product Name
Ethyl 3-oxocyclohexane-1-carboxylate
CAS No.
33668-25-6
Chemical Name
Ethyl 3-oxocyclohexane-1-carboxylate
Synonyms
ETHYL 3-OXOCYCLOHEXANECARBOXYLATE;Ethyl 3-oxo-cyclohexane formate;Ethyl Cyclohexanone-β-carboxylate;ETHYL 3-OXOCYCLOHEXANE-l-CARBOXYLATE;ETHYL 3-OXOCYCLOHEXANE-1-CARBOXYLATE;Ethyl 3-oxocyclohexane-1-carboxylate 97+%;3-Cyclohexanonecarboxylic acid ethyl ester;3-Oxocyclohexanecarboxylic acid ethyl ester;3-Oxocyclohexane-1-carboxylic acid ethyl ester;Cyclohexanecarboxylic acid, 3-oxo-, ethyl ester
CBNumber
CB6265528
Molecular Formula
C9H14O3
Formula Weight
170.21
MOL File
33668-25-6.mol
More
Less

Ethyl 3-oxocyclohexane-1-carboxylate Property

Boiling point:
249℃
Density 
1.083
Flash point:
104℃
storage temp. 
2-8°C
InChI
InChI=1S/C9H14O3/c1-2-12-9(11)7-4-3-5-8(10)6-7/h7H,2-6H2,1H3
InChIKey
YLRVJPQVDQQBOX-UHFFFAOYSA-N
SMILES
C1(C(OCC)=O)CCCC(=O)C1
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
41
Safety Statements 
26-39
Hazard Note 
Irritant
HS Code 
2918199890
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

TRC
Product number
E908940
Product name
EthylCyclohexanone-β-carboxylate
Packaging
2.5g
Price
$250
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0003534
Product name
ethyl 3-oxocyclohexane-1-carboxylate
Purity
95.00%
Packaging
1G
Price
$941.33
Updated
2021/12/16
Rieke Metals
Product number
7591
Product name
ethyl 3-oxocyclohexane-1-carboxylate
Purity
97%
Packaging
5g
Price
$1514
Updated
2021/12/16
SynQuest Laboratories
Product number
2229-1-X3
Product name
Ethyl 3-oxocyclohexane-1-carboxylate
Packaging
100mg
Price
$31
Updated
2021/12/16
Oakwood
Product number
067079
Product name
Ethyl3-Oxocyclohexanecarboxylate
Purity
98%
Packaging
250mg
Price
$40
Updated
2021/12/16
More
Less

Ethyl 3-oxocyclohexane-1-carboxylate Chemical Properties,Usage,Production

Uses

Ethyl Cyclohexanone-β-carboxylate is an intermediate used to prepare carbazole-carboxamides with selective JAK2 inhibitory activities.

Synthesis Reference(s)

Journal of the American Chemical Society, 110, p. 2565, 1988 DOI: 10.1021/ja00216a033

Synthesis

To a round bottom flask was added 3-oxo-1-cyclohexanecarboxylic acid (3.85 g, 27.1 mmol), ethanol (7.91 mL), p-toluenesulfonic acid (0.097 g, 0.56 mmol) and toluene (65.9 mL). The mixture was refluxed with a Dean-star trap overnight. The reaction mixture was cooled down and concentrated under reduced pressure to afford 4.61 g (100 %) of the title compound, 3-oxo-cyclohexanecarboxylic acid ethyl ester (Ethyl 3-oxocyclohexane-1-carboxylate), as a yellow oil.

Ethyl 3-oxocyclohexane-1-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Ethyl 3-oxocyclohexane-1-carboxylate Suppliers

Belgium 1 China 113 France 1 Germany 1 India 2 United Kingdom 2 United States 14 Global 134
Apollo Scientific Ltd.
Tel
--
Fax
--
Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
Advantage
88
Atlantic Research Chemicals Ltd.
Tel
--
Fax
--
Email
info@atlantic-chemicals.com
Country
United Kingdom
ProdList
5618
Advantage
63
More
Less

View Lastest Price from Ethyl 3-oxocyclohexane-1-carboxylate manufacturers

Shanghai Yongzeng Technology Co.,Ltd
Product
ethyl-3-oxocyclohexanecarboxylate 33668-25-6
Price
US $0.00/gm
Min. Order
100gm
Purity
96%min
Supply Ability
100kgs
Release date
2024-09-10
Shaanxi Dideu Medichem Co. Ltd
Product
ETHYL 3-OXOCYCLOHEXANE-1-CARBOXYLATE 33668-25-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2024-08-15
Zhuozhou Wenxi import and Export Co., Ltd
Product
Ethyl 3-oxocyclohexane-1-carbo xylate 33668-25-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10

33668-25-6, Ethyl 3-oxocyclohexane-1-carboxylateRelated Search:

ethyl 3-oxocyclopentane-1-carboxylate 1-N-Ethoxycarbonyl-3-pyrrolidone ETHYL 3-OXO CYCLOBUATNE CARBOXYLATE ETHYL 3-OXOCYCLOHEXANE-1-CARBOXYLATE (1SR,3RS,5RS,6SR)-ETHYL-2-OXO-3-METHYLBICYCLO[3.1.0]-HEXANE 6-CARBOXYLATE Trinexapac-ethyl DIETHYL 2,5-DIOXOBICYCLO[2.2.2]OCTANE-1,4-DICARBOXYLATE Diethyl succinosuccinate

  • ETHYL 3-OXOCYCLOHEXANE-1-CARBOXYLATE
  • ETHYL 3-OXOCYCLOHEXANECARBOXYLATE
  • 3-Cyclohexanonecarboxylic acid ethyl ester
  • 3-Oxocyclohexane-1-carboxylic acid ethyl ester
  • 3-Oxocyclohexanecarboxylic acid ethyl ester
  • 1-(Ethoxycarbonyl)-3-oxocyclohexane, 3-(Ethoxycarbonyl)cyclohexan-1-one
  • Ethyl 3-oxocyclohexane-1-carboxylate 97+%
  • Ethyl 3-oxo-cyclohexane formate
  • Cyclohexanecarboxylic acid, 3-oxo-, ethyl ester
  • Ethyl Cyclohexanone-β-carboxylate
  • ETHYL 3-OXOCYCLOHEXANE-l-CARBOXYLATE
  • 33668-25-6
  • Esters
  • Ring Systems