ChemicalBook > CAS DataBase List > 4-HYDROXY-B-NITROSTYRENE

4-HYDROXY-B-NITROSTYRENE

Product Name
4-HYDROXY-B-NITROSTYRENE
CAS No.
3179-08-6
Chemical Name
4-HYDROXY-B-NITROSTYRENE
Synonyms
4-(2-Nitrovinyl)phenol;4-Hydroxy--nitrostyrene;4-HYDROXY-B-NITROSTYRENE;4-Hydroxy-β-Nitrostyrene;Phenol, 4-(2-nitroethenyl)-;4-HYDROXY-BETA-NITROSTYRENE;4'-HYDROXY-BETA-NITROSTYRENE;4-Hydroxy-alpha-nitrostyrene;2-(4-HYDROXYPHENYL)NITROETHENE;TRANS-4-HYDROXY-BETA-NITROSTYRENE
CBNumber
CB6324179
Molecular Formula
C8H7NO3
Formula Weight
165.15
MOL File
3179-08-6.mol
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4-HYDROXY-B-NITROSTYRENE Property

Melting point:
167-171 °C(lit.)
Boiling point:
318.3±17.0 °C(Predicted)
Density 
1.320±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
8.04±0.13(Predicted)
Appearance
Yellow to brown Solid
InChI
InChI=1S/C8H7NO3/c10-8-3-1-7(2-4-8)5-6-9(11)12/h1-6,10H
InChIKey
CTJKRKMPTRJAIT-UHFFFAOYSA-N
SMILES
C1(O)=CC=C(C=C[N+]([O-])=O)C=C1
CAS DataBase Reference
3179-08-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
2908990000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Matrix Scientific
Product number
126612
Product name
4-(2-Nitrovinyl)phenol
Purity
>95%
Packaging
1g
Price
$28
Updated
2021/12/16
Matrix Scientific
Product number
126612
Product name
4-(2-Nitrovinyl)phenol
Purity
>95%
Packaging
5g
Price
$82
Updated
2021/12/16
Matrix Scientific
Product number
126612
Product name
4-(2-Nitrovinyl)phenol
Purity
>95%
Packaging
10g
Price
$144
Updated
2021/12/16
AK Scientific
Product number
J56748
Product name
4-(2-Nitrovinyl)phenol
Packaging
25g
Price
$197
Updated
2021/12/16
AK Scientific
Product number
J56748
Product name
4-(2-Nitrovinyl)phenol
Packaging
10g
Price
$100
Updated
2021/12/16
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4-HYDROXY-B-NITROSTYRENE Chemical Properties,Usage,Production

Synthesis

7400-08-0

3179-08-6

General procedure for the synthesis of 4-(2-nitrovinyl)phenol from 4-hydroxycinnamic acid: 0.01 mol of 4-hydroxycinnamic acid, about 0.01 mol of TCICA/DMF reagent, 1 g of sodium nitrite, and 25 mL of CH2Cl2 or acetonitrile were added to a pre-cleaned round-bottomed flask with stirring and the reaction was carried out under refluxing conditions for 8 to 10 hours. The progress of the reaction was monitored by TLC. Upon completion of the reaction, the reaction mixture was washed with NaHCO3 solution and subsequently extracted with ethyl acetate. The organic layer was separated, dried with anhydrous MgSO4 and concentrated in vacuum. Finally, purification by column chromatography using ethyl acetate-hexane as eluent gave the pure product 4-(2-nitrovinyl)phenol as a yellow powder.

References

[1] Synthetic Communications, 2013, vol. 43, # 19, p. 2672 - 2677
[2] Catalysis Science and Technology, 2016, vol. 6, # 5, p. 1430 - 1434
[3] Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2013, vol. 43, # 8, p. 977 - 983
[4] Synthetic Communications, 2015, vol. 45, # 19, p. 2251 - 2258

4-HYDROXY-B-NITROSTYRENE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-HYDROXY-B-NITROSTYRENE Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
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62
Carbott PharmTech Inc.
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0535-6385396
Fax
+86 (535) 638-9971
Email
info@carbottpharm.com
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China
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957
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Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
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56
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
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+86-21-54098501
Fax
+86-21-54096319
Email
sales@sinch.com.cn
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China
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Clearsynth Labs Limited
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+91-22-26355700
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+91-22-26355701
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info@clearsynth.com
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India
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Shanghai YuLue Chemical Co., Ltd.
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021-60345187 13671753212
Fax
021-34702061
Email
lzz841106@aliyun.com
Country
China
ProdList
10263
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Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
15873
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55
Wuhan Chemwish Technology Co., Ltd
Tel
027-67849912
Fax
027-87531808
Email
sales@chemwish.com
Country
China
ProdList
9148
Advantage
60
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
71826
Advantage
60
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View Lastest Price from 4-HYDROXY-B-NITROSTYRENE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
4-HYDROXY-B-NITROSTYRENE 3179-08-6
Price
US $1.00/Kg
Min. Order
1Kg
Purity
98%
Supply Ability
20T
Release date
2024-07-08
Career Henan Chemical Co
Product
4-Hydroxy-β-nitrostyrene 3179-08-6
Price
US $1.00/g
Min. Order
1g
Purity
97%
Supply Ability
100kg
Release date
2020-01-09