ChemicalBook > CAS DataBase List > Copper(I) bromide-dimethyl sulfide

Copper(I) bromide-dimethyl sulfide

Product Name
Copper(I) bromide-dimethyl sulfide
CAS No.
54678-23-8
Chemical Name
Copper(I) bromide-dimethyl sulfide
Synonyms
COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEX;COPPER(I) BROMIDE DIMETHYL SULFIDE;Bromocopper;Copper(I) bromide methyL;Copper, bromothiobismethane-;COPPER(1)BROMIDE DMS COMPLEX;bromo[thiobis[methane]]copper;COPPER BROMIDE-DIMETHYL SULFIDE;BROMO(DIMETHYLSULFIDE)COPPER(I);COPPER(1) BROMIDE DMS COMPLEX 95%
CBNumber
CB6332325
Molecular Formula
C2H6BrCuS
Formula Weight
205.58
MOL File
54678-23-8.mol
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Copper(I) bromide-dimethyl sulfide Property

Melting point:
132 °C (dec.)(lit.)
form 
Crystalline Powder and/or Chunks
color 
Pale brown or pale green
Water Solubility 
Soluble in water. Reacts with water and decomposes.
Sensitive 
Moisture Sensitive/Air Sensitive
BRN 
4386581
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChIKey
PMHQVHHXPFUNSP-UHFFFAOYSA-M
CAS DataBase Reference
54678-23-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25
RIDADR 
1759
WGK Germany 
3
F 
10-13-21
HazardClass 
8
PackingGroup 
III
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
230502
Product name
Copper(I) bromide dimethyl sulfide complex
Purity
99%
Packaging
10g
Price
$118
Updated
2024/03/01
Sigma-Aldrich
Product number
230502
Product name
Copper(I) bromide dimethyl sulfide complex
Purity
99%
Packaging
50g
Price
$320
Updated
2024/03/01
Alfa Aesar
Product number
019368
Product name
Copper(I) bromide-dimethyl sulfide complex
Packaging
2g
Price
$22.65
Updated
2024/03/01
Alfa Aesar
Product number
019368
Product name
Copper(I) bromide-dimethyl sulfide complex
Packaging
10g
Price
$84.6
Updated
2024/03/01
Strem Chemicals
Product number
29-0225
Product name
Copper(I) bromide, dimethyl sulfide complex, 99%
Packaging
25g
Price
$225
Updated
2021/12/16
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Copper(I) bromide-dimethyl sulfide Chemical Properties,Usage,Production

Chemical Properties

off-white to beige, grey or green crystalline

Uses

Copper(I) bromide-dimethyl sulfide complex is used as catalyst for adding Grignard reagents to fullerenes.

Uses

Catalyst employed in the addition of Grignard reagents (alkyl, alkenyl, aryl) to fullerenes. This process adds 5 organic groups to [60]fullerene and 3 groups to [70]fullerene.

Uses

Copper(I) bromide-dimethyl sulfide can be used as catalyst for adding Grignard reagents to fullerenes.

Purification Methods

Purify it by recrystallisation in the presence of Me2S. A solution of the complex (1.02g) in Me2S (5mL) is slowly diluted with hexane (20mL), and the pure colourless prisms of the complex (0.96g) separate and are collected and dried, m 124-129o(dec). The complex is insoluble in hexane, Et2O, Me2CO, CHCl3 and CCl4. It dissolves in DMF and DMSO, but the solution becomes hot and green indicating decomposition. It dissolves in *C6H6, Et2O, MeOH and CHCl3 if excess of Me2S is added and a colourless solution is obtained. [House et al. J Org Chem 40 1460 1975.] Prior to use, the complex is dissolved in Me2S and evaporated to dryness in the weighed reaction flask [Bourgain-Commer.on et al. J Organomet Chem 228 321 1983].

Copper(I) bromide-dimethyl sulfide Preparation Products And Raw materials

Raw materials

Preparation Products

Ethyl 3-furancarboxylate 3-FURANMETHANOL
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View Lastest Price from Copper(I) bromide-dimethyl sulfide manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Copper(I) bromide-dimethyl sulfide 54678-23-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-01
Hebei Mojin Biotechnology Co., Ltd
Product
Copper(I) bromide-dimethyl sulfide 54678-23-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-16
Career Henan Chemical Co
Product
Copper(I) bromide-dimethyl sulfide 54678-23-8
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
10KG
Release date
2019-08-05

54678-23-8, Copper(I) bromide-dimethyl sulfideRelated Search:

Dimethyl sebacate N,N-Dimethylformamide Dimethyl sulfoxide IRON (II) BROMIDE Phosphorus tribromide Dimethyl carbonate Borane-methyl sulfide complex Dacthal ETHANE Thioanisole Cupric bromide Cuprous bromide Dimethyl sulfate Zinc bromide Potassium bromide Boron tribromide Dimethyl sulfide Hydrogen bromide

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  • 54678-23-8
  • BrC2CuH6S
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  • CuBrSCH32
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  • Catalysis and Inorganic Chemistry