Copper(I) bromide-dimethyl sulfide
- Product Name
- Copper(I) bromide-dimethyl sulfide
- CAS No.
- 54678-23-8
- Chemical Name
- Copper(I) bromide-dimethyl sulfide
- Synonyms
- COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEX;COPPER(I) BROMIDE DIMETHYL SULFIDE;Bromocopper;Copper(I) bromide methyL;Copper, bromothiobismethane-;COPPER(1)BROMIDE DMS COMPLEX;bromo[thiobis[methane]]copper;COPPER BROMIDE-DIMETHYL SULFIDE;BROMO(DIMETHYLSULFIDE)COPPER(I);COPPER(1) BROMIDE DMS COMPLEX 95%
- CBNumber
- CB6332325
- Molecular Formula
- C2H6BrCuS
- Formula Weight
- 205.58
- MOL File
- 54678-23-8.mol
Copper(I) bromide-dimethyl sulfide Property
- Melting point:
- 132 °C (dec.)(lit.)
- form
- Crystalline Powder and/or Chunks
- color
- Pale brown or pale green
- Water Solubility
- Soluble in water. Reacts with water and decomposes.
- Sensitive
- Moisture Sensitive/Air Sensitive
- BRN
- 4386581
- Exposure limits
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 - InChIKey
- PMHQVHHXPFUNSP-UHFFFAOYSA-M
- CAS DataBase Reference
- 54678-23-8(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-24/25
- RIDADR
- 1759
- WGK Germany
- 3
- F
- 10-13-21
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 230502
- Product name
- Copper(I) bromide dimethyl sulfide complex
- Purity
- 99%
- Packaging
- 10g
- Price
- $118
- Updated
- 2024/03/01
- Product number
- 230502
- Product name
- Copper(I) bromide dimethyl sulfide complex
- Purity
- 99%
- Packaging
- 50g
- Price
- $320
- Updated
- 2024/03/01
- Product number
- 019368
- Product name
- Copper(I) bromide-dimethyl sulfide complex
- Packaging
- 2g
- Price
- $22.65
- Updated
- 2024/03/01
- Product number
- 019368
- Product name
- Copper(I) bromide-dimethyl sulfide complex
- Packaging
- 10g
- Price
- $84.6
- Updated
- 2024/03/01
- Product number
- 29-0225
- Product name
- Copper(I) bromide, dimethyl sulfide complex, 99%
- Packaging
- 25g
- Price
- $225
- Updated
- 2021/12/16
Copper(I) bromide-dimethyl sulfide Chemical Properties,Usage,Production
Chemical Properties
off-white to beige, grey or green crystalline
Uses
Copper(I) bromide-dimethyl sulfide complex is used as catalyst for adding Grignard reagents to fullerenes.
Uses
Catalyst employed in the addition of Grignard reagents (alkyl, alkenyl, aryl) to fullerenes. This process adds 5 organic groups to [60]fullerene and 3 groups to [70]fullerene.
Uses
Copper(I) bromide-dimethyl sulfide can be used as catalyst for adding Grignard reagents to fullerenes.
Purification Methods
Purify it by recrystallisation in the presence of Me2S. A solution of the complex (1.02g) in Me2S (5mL) is slowly diluted with hexane (20mL), and the pure colourless prisms of the complex (0.96g) separate and are collected and dried, m 124-129o(dec). The complex is insoluble in hexane, Et2O, Me2CO, CHCl3 and CCl4. It dissolves in DMF and DMSO, but the solution becomes hot and green indicating decomposition. It dissolves in *C6H6, Et2O, MeOH and CHCl3 if excess of Me2S is added and a colourless solution is obtained. [House et al. J Org Chem 40 1460 1975.] Prior to use, the complex is dissolved in Me2S and evaporated to dryness in the weighed reaction flask [Bourgain-Commer.on et al. J Organomet Chem 228 321 1983].
Copper(I) bromide-dimethyl sulfide Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Copper(I) bromide-dimethyl sulfide manufacturers
- Product
- Copper(I) bromide-dimethyl sulfide 54678-23-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-10-16
- Product
- Copper(I) bromide-dimethyl sulfide 54678-23-8
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2023-03-10
- Product
- Copper(I) bromide-dimethyl sulfide 54678-23-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 10KG
- Release date
- 2019-08-05