9-phenanthrenylboronic acid
- Product Name
- 9-phenanthrenylboronic acid
- CAS No.
- 68572-87-2
- Chemical Name
- 9-phenanthrenylboronic acid
- Synonyms
- PHENANTHREN-9-YLBORONIC ACID;9-PHENANTHRENEBORONIC ACID;9-Phenanthrene;9-BAPA;9- phenoborate;RARECHEM AH PB 0056;9-Phenanthracenylbor;9-Phenanthrene boronic;Phenanthreneboronicacid;9-PhenanthreneboronicAci
- CBNumber
- CB6360739
- Molecular Formula
- C14H11BO2
- Formula Weight
- 222.05
- MOL File
- 68572-87-2.mol
9-phenanthrenylboronic acid Property
- Melting point:
- 165-170 °C
- Boiling point:
- 479.5±28.0 °C(Predicted)
- Density
- 1.26±0.1 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Soluble in DMSO.
- pka
- 8.53±0.30(Predicted)
- form
- Solid
- color
- Pale Yellow
- InChI
- InChI=1S/C14H11BO2/c16-15(17)14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9,16-17H
- InChIKey
- JCDAUYWOHOLVMH-UHFFFAOYSA-N
- SMILES
- B(C1=CC2C(C3C1=CC=CC=3)=CC=CC=2)(O)O
- CAS DataBase Reference
- 68572-87-2(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 22-24/25-26
- WGK Germany
- 3
- HazardClass
- IRRITANT
- HS Code
- 29319090
- Storage Class
- 11 - Combustible Solids
- Hazard Classifications
- Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 696552
- Product name
- 9-Phenanthracenylboronic acid
- Purity
- ≥95%
- Packaging
- 5g
- Price
- $63
- Updated
- 2023/06/20
- Product number
- P1093
- Product name
- 9-Phenanthreneboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 1g
- Price
- $24
- Updated
- 2026/03/19
- Product number
- P1093
- Product name
- 9-Phenanthreneboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 5g
- Price
- $63
- Updated
- 2026/03/19
- Product number
- 286619
- Product name
- 9-Phenanthracenylboronic acid
- Packaging
- 10g
- Price
- $389
- Updated
- 2021/12/16
- Product number
- 019346
- Product name
- 9-Phenanthreneboronic Acid
- Packaging
- 1g
- Price
- $418
- Updated
- 2021/12/16
9-phenanthrenylboronic acid Chemical Properties,Usage,Production
Chemical Properties
White solid
Uses
9-Phenanthreneboronic Acid is used as an fluorescent analytical reagent in sensing systems for glucose-specific detection.
Uses
9-Phenanthracenylboronic acid is used as an fluorescent analytical reagent in sensing systems for glucose-specific detection and in suzuki reaction.
Synthesis
5419-55-6
573-17-1
68572-87-2
The general procedure for the synthesis of 9-phenanthrenylboronic acid from triisopropyl borate and 9-bromophenanthrene is as follows: Step a: Preparation of 9-phenanthracenylboronic acid Under argon protection, 9-bromophenanthrene (1 g, 3.9 mmol) and triisopropyl borate (1.35 ml, 1.1 g, 5.85 mmol) were dissolved in anhydrous THF (30 ml) and the solution was cooled to -78 °C. Subsequently, n-BuLi (1.6 M hexane solution, 2.9 ml, 4.68 mmol) was added slowly dropwise over 1 h. The reaction temperature was maintained at -78 °C and stirring was continued for 1 h. The reaction mixture was then cooled to -78 °C. The reaction temperature was then adjusted to -78 °C. After that, the reaction mixture was slowly warmed up to -20°C, 2M HCl (20 ml) was added, and the temperature was continued to 18°C and stirring was continued for 1 hour. After completion of the reaction, ether (300 ml) was added for extraction, the organic phase was dried with MgSO4, filtered and concentrated under reduced pressure to afford the crude product 9-phenanthrenylboronic acid (770 mg, 89% yield) as a white solid, which can be used in subsequent reactions without further purification.
References
[1] Patent: WO2006/135973, 2006, A1. Location in patent: Page/Page column 31
[2] Patent: CN107652224, 2018, A. Location in patent: Paragraph 0086; 0089-0091
[3] Patent: CN107382748, 2017, A. Location in patent: Paragraph 0037; 0038; 0039; 0040
9-phenanthrenylboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 9-phenanthrenylboronic acid manufacturers
- Product
- 9-phenanthrenylboronic acid 68572-87-2
- Price
- US $35.00-25.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 Ton
- Release date
- 2023-09-22
- Product
- 9-Phenanthracenylboronic acid 68572-87-2
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99.9%
- Supply Ability
- 30000 Kg
- Release date
- 2023-11-09
- Product
- 9-Phenanthracenylboronic acid 68572-87-2
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99.9%
- Supply Ability
- 30000 Kg
- Release date
- 2023-11-14