ChemicalBook > CAS DataBase List > 9-phenanthrenylboronic acid

9-phenanthrenylboronic acid

Product Name
9-phenanthrenylboronic acid
CAS No.
68572-87-2
Chemical Name
9-phenanthrenylboronic acid
Synonyms
PHENANTHREN-9-YLBORONIC ACID;9-Phenanthrene;9-PHENANTHRENEBORONIC ACID;9-BAPA;9- phenoborate;RARECHEM AH PB 0056;9-Phenanthracenylbor;9-Phenanthrene boronic;Phenanthreneboronicacid;9-PhenanthreneboronicAci
CBNumber
CB6360739
Molecular Formula
C14H11BO2
Formula Weight
222.05
MOL File
68572-87-2.mol
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9-phenanthrenylboronic acid Property

Melting point:
165-170 °C
Boiling point:
479.5±28.0 °C(Predicted)
Density 
1.26±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Soluble in DMSO.
pka
8.53±0.30(Predicted)
form 
Solid
color 
Pale Yellow
InChI
InChI=1S/C14H11BO2/c16-15(17)14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9,16-17H
InChIKey
JCDAUYWOHOLVMH-UHFFFAOYSA-N
SMILES
B(C1=CC2C(C3C1=CC=CC=3)=CC=CC=2)(O)O
CAS DataBase Reference
68572-87-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-26
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
696552
Product name
9-Phenanthracenylboronic acid
Purity
≥95%
Packaging
5g
Price
$63
Updated
2023/06/20
TCI Chemical
Product number
P1093
Product name
9-Phenanthreneboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$23
Updated
2025/07/31
TCI Chemical
Product number
P1093
Product name
9-Phenanthreneboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$74
Updated
2025/07/31
Usbiological
Product number
286619
Product name
9-Phenanthracenylboronic acid
Packaging
10g
Price
$389
Updated
2021/12/16
Usbiological
Product number
019346
Product name
9-Phenanthreneboronic Acid
Packaging
1g
Price
$418
Updated
2021/12/16
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9-phenanthrenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

White solid

Uses

9-Phenanthreneboronic Acid is used as an fluorescent analytical reagent in sensing systems for glucose-specific detection.

Uses

9-Phenanthracenylboronic acid is used as an fluorescent analytical reagent in sensing systems for glucose-specific detection and in suzuki reaction.

Synthesis

5419-55-6

573-17-1

68572-87-2

The general procedure for the synthesis of 9-phenanthrenylboronic acid from triisopropyl borate and 9-bromophenanthrene is as follows: Step a: Preparation of 9-phenanthracenylboronic acid Under argon protection, 9-bromophenanthrene (1 g, 3.9 mmol) and triisopropyl borate (1.35 ml, 1.1 g, 5.85 mmol) were dissolved in anhydrous THF (30 ml) and the solution was cooled to -78 °C. Subsequently, n-BuLi (1.6 M hexane solution, 2.9 ml, 4.68 mmol) was added slowly dropwise over 1 h. The reaction temperature was maintained at -78 °C and stirring was continued for 1 h. The reaction mixture was then cooled to -78 °C. The reaction temperature was then adjusted to -78 °C. After that, the reaction mixture was slowly warmed up to -20°C, 2M HCl (20 ml) was added, and the temperature was continued to 18°C and stirring was continued for 1 hour. After completion of the reaction, ether (300 ml) was added for extraction, the organic phase was dried with MgSO4, filtered and concentrated under reduced pressure to afford the crude product 9-phenanthrenylboronic acid (770 mg, 89% yield) as a white solid, which can be used in subsequent reactions without further purification.

References

[1] Patent: WO2006/135973, 2006, A1. Location in patent: Page/Page column 31
[2] Patent: CN107652224, 2018, A. Location in patent: Paragraph 0086; 0089-0091
[3] Patent: CN107382748, 2017, A. Location in patent: Paragraph 0037; 0038; 0039; 0040

9-phenanthrenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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9-phenanthrenylboronic acid Suppliers

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View Lastest Price from 9-phenanthrenylboronic acid manufacturers

Hebei Xinsheng New Material Technology Co., LTD.
Product
9-phenanthrenylboronic acid 68572-87-2
Price
US $35.00-25.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 Ton
Release date
2023-09-22
Hebei Xinsheng New Material Technology Co., LTD.
Product
9-Phenanthracenylboronic acid 68572-87-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99.9%
Supply Ability
30000 Kg
Release date
2023-11-09
Hebei Xinsheng New Material Technology Co., LTD.
Product
9-Phenanthracenylboronic acid 68572-87-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99.9%
Supply Ability
30000 Kg
Release date
2023-11-14

68572-87-2, 9-phenanthrenylboronic acidRelated Search:

Boric acid Citric acid 9-Anthraceneboronic acid Folic acid Ethyl 2-(Chlorosulfonyl)acetate Zinc borate Phenanthrene Glycine Fluoroboric acid Stearic acid Ascoric Acid 1-Naphthylboronic acid 2-Naphthaleneboronic acid Methylboronic acid Phenylboronic acid 9-phenanthrenylboronic acid phosphoric acid

  • 9-Phenanthracenylbor
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  • PHENANTHRENE-9-YLBORONIC ACID
  • 9-Phenanthrene
  • 9- phenoborate
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  • 68572-87-2 9-Phenanthracenylboronic acid
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  • phenanthraceny|boronic acid
  • 68572-87-2
  • 6872-87-2
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  • 8572-87-2
  • B (Classes of Boron Compounds)
  • Boronic Acids
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  • Electronic Chemicals
  • B (Classes of Boron Compounds)
  • Boronic Acids
  • Boron Compounds
  • Aromatics
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  • Fluorescent Labels & Indicators
  • bc0001