2-METHYL-N-(PHENYLMETHYLENE)-2-PROPYLAMINE Property

Melting point:

-30

Boiling point:

209 °C(lit.)

Density 

0.906 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.52(lit.)

Flash point:

173 °F

pka

6.31±0.50(Predicted)

form 

liquid

color 

Colourless to light yellow

Specific Gravity

0.906

EPA Substance Registry System

2-Propanamine, 2-methyl-N-(phenylmethylene)- (6852-58-0)

Safety

Hazard Codes 

Xn,Xi

Risk Statements 

22-36/37/38-40-42/43

Safety Statements 

26-36

WGK Germany 

3

Hazard Note 

Irritant

HS Code 

29215900

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P342+P311IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.

2-METHYL-N-(PHENYLMETHYLENE)-2-PROPYLAMINE Chemical Properties,Usage,Production

Chemical Properties

Colorless to yellow liquid

Synthesis Reference(s)

The Journal of Organic Chemistry, 53, p. 5856, 1988 DOI: 10.1021/jo00260a012

General Description

In vitro metabolism of N-benzyl-tert-butylamine in male hamster hepatic microsomal preparations has been studied. Kinetic studies of frustrated Lewis pair (FLP)-catalyzed hydrogenation and deuteration of N-benzylidene-tert-butylamine suggests that the reaction proceeds via autoinductive catalysis.