TITANIUM(III) FLUORIDE

Product Name: TITANIUM(III) FLUORIDE
CAS No.: 13470-08-1
Chemical Name: TITANIUM(III) FLUORIDE
Synonyms: TiF3;TSCS(13470-08-1);TITANIUM FLUORIDE;TITANIUM TRIFLUORIDE;itanium(III)fluoride;TITANIUM(III) FLUORIDE;titaniumfluoride(tif3);Titanium fluoride(F3Ti);Titanium fluoride (TiF3);Titanium(III)fluoride99%
CBNumber: CB6377711
Molecular Formula: F3Ti
Formula Weight: 104.86
MOL File: 13470-08-1.mol

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TITANIUM(III) FLUORIDE Property

Melting point:

1200 °C

Boiling point:

1400 °C

Density

3.4 g/mL at 25 °C(lit.)

solubility

insoluble in H2O, dilute acid solutions, alkaline solutions

form

Crystalline Powder

Specific Gravity

3.4

color

Red to brown

Water Solubility

Sparingly soluble. It hydrolyses in water.

Sensitive

Air & Moisture Sensitive

Crystal Structure

VF3 type

crystal system

Three sides

Space group

R3c

Lattice constant

a/nm	b/nm	c/nm	α/o	β/o	γ/o	V/nm3
0.543	0.543	1.364	90	90	120	0.3488

Exposure limits

ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3

CAS DataBase Reference

13470-08-1(CAS DataBase Reference)

EPA Substance Registry System

Titanium fluoride (TiF3) (13470-08-1)

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Safety

Hazard Codes: C
Risk Statements: 20/21/22-34-32-14
Safety Statements: 26-36/37/39-45
RIDADR: UN 3260 8/PG 2
WGK Germany: 3
F: 10
Hazard Note: Corrosive
TSCA: Yes
HazardClass: 8
PackingGroup: II
HS Code: 28261990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 399817
Product name: Titanium(III) fluoride
Packaging: 5g
Price: $63.7
Updated: 2024/03/01

Alfa Aesar

Product number: 013079
Product name: Titanium(III) fluoride
Packaging: 10g
Price: $57.65
Updated: 2024/03/01

Alfa Aesar

Product number: 013079
Product name: Titanium(III) fluoride
Packaging: 50g
Price: $273
Updated: 2023/06/20

Strem Chemicals

Product number: 93-2224
Product name: Titanium(III) fluoride, min. 98%
Packaging: 5g
Price: $41
Updated: 2024/03/01

Strem Chemicals

Product number: 93-2224
Product name: Titanium(III) fluoride, min. 98%
Packaging: 25g
Price: $149
Updated: 2024/03/01

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TITANIUM(III) FLUORIDE Chemical Properties,Usage,Production

Chemical Properties

Red to brown crystalline powder
Blue rhombic crystals are stable in air and unusually resistant to acids and bases. Sublimation begins at about 930°C in a less than 0.1 mm vacuum. M.p. >1100°C; d%5 2.98. Insoluble in water and alcohol. Disproportionation to TiF4 and Ti begins at 950°C.

Uses

It is used as a laboratory chemicals & for manufacture of chemicals.

Production Methods

Titanium metal is hydrogenated at 600-700°C. It is then placed in a small nickel boat and inserted into the horizontal nickel tube (closed at one end). The hydride is fluorinated with gaseous HF. The open end of the tube has a cooling jacket and is sealed with picein to a copper cover. Two copper tubes are silver-soldered into the cover and serve as an inlet and outlet for the hydrogen; the inlet tube also contains a concentric silver tube for introducing HF. The output gases pass through an empty polyethylene bottle, a bubble counter filled with paraffin oil and a polyethylene trap to freeze excess HF gas. The closed end of the reaction tube is placed in a tubular furnace. The temperature is measured externally. After thoroughly flushing the apparatus with Hs, fluorination followed with a 1 4 mixture of H2 and HF for four to five hours. The HF flow is first started at a temperature above 200°C. The water temperature in the cooling jacket should be higher than 20°C to prevent condensation of the HF. After completion of the fluorination, the product is left to cool in a stream of hydrogen. The yield is 90%.

TITANIUM(III) FLUORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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TITANIUM(III) FLUORIDE Suppliers

Belgium 1 China 41 Europe 1 France 2 Germany 2 India 2 Japan 1 Switzerland 1 United Kingdom 8 United States 20 Global 79

Alfa Chemistry

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GFS Chemicals

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13470-08-1, TITANIUM(III) FLUORIDERelated Search:

Hexafluorotitanic acid TITANIUM (III) SULFATE Magnesium fluoride Magnesium nitride Ferrous chloride Titanous chloride TITANIUM(IV) BROMIDE TITANIUM(III) CHLORIDE-ALUMINUM(III) CHLORIDE Titanium (IV) Sulfate Titanium TITANIUM(III) FLUORIDE 97% POTASSIUM TITANIUM FLUORIDE CERIUM(III) SULFATE OCTAHYDRATE SODIUM TITANIUM FLUORIDE Titanium fluoride (TiF4), (T-4)- TITANIUM(III) FLUORIDE ammonium titanium fluoride LITHIUM HEXAFLUOROTITANATE

TiF3

Titanium fluoride (TiF3)

titaniumfluoride(tif3)

TITANIUM TRIFLUORIDE

TITANIUM(III) FLUORIDE

TITANIUM FLUORIDE

Titanium(III)fluoride99%

Titanium(III) fluoride, min. 98%

Titanium(III) trifluoride

TSCS(13470-08-1)

Titanium(III)fluoride,min.98%

Titanium(III) fluoride,98%

Titanium fluoride(F3Ti)

itanium(III)fluoride

Carbon Graphite (C) Sputtering Targets

13470-08-1

3FTi

Catalysis and Inorganic Chemistry

Titanium

metal halide