BENZENE CHROMIUM TRICARBONYL
- Product Name
- BENZENE CHROMIUM TRICARBONYL
- CAS No.
- 12082-08-5
- Chemical Name
- BENZENE CHROMIUM TRICARBONYL
- Synonyms
- Benchrotrene;Benzenechromotricarbonyl;Benzentrikarbonylchromium;tricarbonylbenzenechromium;Tricarbonylbenzene chromium;(benzene)tricarbonyl-chromiu;CHROMIUM BENZENE TRICARBONYL;(BENZENE)TRICARBONYLCHROMIUM;BENZENE CHROMIUM TRICARBONYL;pi-benzenechromiumtricarbonyl
- CBNumber
- CB6389602
- Molecular Formula
- C9H6CrO36*
- Formula Weight
- 214.14
- MOL File
- 12082-08-5.mol
BENZENE CHROMIUM TRICARBONYL Property
- Melting point:
- 163-166 °C (lit.)
- form
- crystal
- color
- yellow
- BRN
- 3571699
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- 119318
- Product name
- Benzene-chromium(0) tricarbonyl
- Purity
- 98%
- Packaging
- 1g
- Price
- $152
- Updated
- 2024/03/01
- Product number
- 24-0120
- Product name
- Benzene chromium tricarbonyl, 98%
- Packaging
- 1g
- Price
- $132
- Updated
- 2024/03/01
- Product number
- 24-0120
- Product name
- Benzene chromium tricarbonyl, 98%
- Packaging
- 5g
- Price
- $519
- Updated
- 2024/03/01
- Product number
- ING0002478
- Product name
- BENZENE CHROMIUM TRICARBONYL
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $196.14
- Updated
- 2021/12/16
BENZENE CHROMIUM TRICARBONYL Chemical Properties,Usage,Production
Chemical Properties
yellow crystalline powder
Uses
Catalyst for:
- Oxidation of alkenes
- Hydrogenation of alkynes
Preparation
For cases where large quantities are needed, benzene chromium tricarbonyl is easily prepared from the reaction of benzene with Hexacarbonylchromium.
reaction suitability
core: chromium
reagent type: catalyst
Solubility in organics
benzene chromium tricarbonyl is soluble in THF, ether, benzene.
Purification Methods
Purify the complex by sublimation in vacuo. A possible impurity is 2-picoline which can be removed by washing with pentane and drying. It is then purified further by sublimation at 80-85o/10-3mm, or by recrystallisation from Et2O to give yellow crystals. 1H NMR in CDCl3 should give a single peak at 4.68. [Rausch J Org Chem 39 1787 1974, Pauson in Houben-Weyl Meth Org Chem V, E 18 Pt I p226 Theme Verlag, Stuttgart 1986, Beilstein 5 IV 625.]
BENZENE CHROMIUM TRICARBONYL Preparation Products And Raw materials
Raw materials
Preparation Products
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