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Silver tetrafluoroborate

Product Name
Silver tetrafluoroborate
CAS No.
14104-20-2
Chemical Name
Silver tetrafluoroborate
Synonyms
AGBF4;SILVER FLUOBORATE;ver tetrafL;SILVER BOROFLUORIDE;SILVER FLUOROBORATE;ilver tetrafluoroborat;Silvertetrafluoroborat;SILVER TETRAFLUOROBORATE;SLIVER TERTRAFLUOROBORATE;SilverTetrafluoroborate>
CBNumber
CB6437440
Molecular Formula
AgBF4
Formula Weight
194.67
MOL File
14104-20-2.mol
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Silver tetrafluoroborate Property

Melting point:
70-73 °C(lit.)
storage temp. 
Store below +30°C.
solubility 
Acetonitrile (Slightly), Methanol (Very Slightly)
form 
Crystalline Powder
color 
White to pale brown
Water Solubility 
SOLUBLE
Sensitive 
Hygroscopic
Exposure limits
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
InChI
InChI=1S/Ag.BF4/c;2-1(3,4)5/q+1;-1
InChIKey
CCAVYRRHZLAMDJ-UHFFFAOYSA-N
SMILES
[B+3]([F-])([F-])([F-])[F-].[Ag+]
CAS DataBase Reference
14104-20-2(CAS DataBase Reference)
EPA Substance Registry System
Borate(1-), tetrafluoro-, silver(1+) (14104-20-2)
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Safety

Hazard Codes 
C
Risk Statements 
34-22-20/21/22
Safety Statements 
26-36/37/39-45-27
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
RTECS 
ED2875000
3-8-10-21
Hazard Note 
Corrosive
TSCA 
TSCA listed
HazardClass 
6.1
PackingGroup 
III
HS Code 
28432900
Storage Class
8A - Combustible corrosive hazardous materials
Hazard Classifications
Eye Dam. 1
Skin Corr. 1B
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
208361
Product name
Silver tetrafluoroborate
Purity
98%
Packaging
1g
Price
$37.44
Updated
2025/07/31
Sigma-Aldrich
Product number
8.18881
Product name
Silver tetrafluoroborate
Purity
for synthesis
Packaging
5G
Price
$129
Updated
2025/07/31
Sigma-Aldrich
Product number
208361
Product name
Silver tetrafluoroborate
Purity
98%
Packaging
10g
Price
$139.84
Updated
2025/07/31
Sigma-Aldrich
Product number
8.18881
Product name
Silver tetrafluoroborate
Purity
for synthesis
Packaging
25g
Price
$493
Updated
2023/01/07
TCI Chemical
Product number
S0446
Product name
Silver Tetrafluoroborate
Purity
>98.0%(T)
Packaging
5g
Price
$99
Updated
2025/07/31
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Silver tetrafluoroborate Chemical Properties,Usage,Production

Chemical Properties

beige crystalline powder

Uses

Silver tetrafluoroborate finds applications as a useful reagent in inorganic, organic and organomettalic chemistry. It acts as a moderately strong oxidant in dichloromethane, replaces halide anions and ligands with weakly coordinating tetrafluoroborate anions, and behaves as a catalyst for cyclization reactions. It is a potent promoter for chemical glycosylation.

Application

Silver tetrafluoroborate is a transition metal salt extensively used in organic syntheses.
Gold Catalysts — 21st Century ′Gold Rush′
Displaces chloride from precious metal complexes used in the oxidation of alcohols by persulfate.
Provides a silver-ion template for improved macrolatamization of a linear dipeptide.

General Description

Silver tetrafluoroborate (AgBF4) is used as a Lewis acid in organic synthesis. It is known to have a high affinity towards organic halides. It is employed in organic reactions like activation of acyl chlorides, nucleophilic substitution, rearrangement, cycloaddition, cyclization, ring expansion and oxidation.

reaction suitability

reagent type: oxidant

Safety Profile

Poison by intravenous route. When heated to decomposition it emits toxic fumes of F-. Used for plating baths. See also SILVER COMPOUNDS, BORON COMPOUNDS, and FLUORIDES.

Synthesis

Preparation of silver tetrafluoroborate and MBDP
This reaction is completed with the lights off. In a 25 mL round-bottom flask covered with aluminum foil, AgBF4 (0.0397 g (0.20 mmol) is dissolved in 10 mL CH3CN. To the solution MBDP (0.0645 g, 0.20 mmol) is added and allowed to stir for 3 hours. The solution is concentrated under vacuum to approximately 3 mL then layered with Et2O. The flask is placed in the freezer. X-ray quality crystals are formed.

Silver tetrafluoroborate Preparation Products And Raw materials

Raw materials

Preparation Products

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Silver tetrafluoroborate Suppliers

Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
021-4009004166/18616739031 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52679
Advantage
58
Nanjing Pharmaluxury Co., Ltd.
Tel
025-83726959 15851816062
Fax
025-8666-0986
Email
goodsalejs@163.com
Country
China
ProdList
128
Advantage
58
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
SHANG FLUORO
Tel
021-65170832 15601903708
Email
qinba_1@163.com
Country
China
ProdList
405
Advantage
60
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
Tel
+86-21-54098501
Fax
+86-21-54096319
Email
sales@sinch.com.cn
Country
China
ProdList
11598
Advantage
64
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View Lastest Price from Silver tetrafluoroborate manufacturers

henan kanbei chemical co.,ltd
Product
Silver tetrafluoroborate 14104-20-2
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-22
Honest Joy Holdings Limited
Product
Silver tetrafluoroborate 14104-20-2
Price
US $0.00/KG
Min. Order
1KG
Purity
98.5%
Supply Ability
100 tons
Release date
2022-01-26
Zhuozhou Wenxi import and Export Co., Ltd
Product
Silver tetrafluoroborate 14104-20-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10

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