Silver tetrafluoroborate

Product Name: Silver tetrafluoroborate
CAS No.: 14104-20-2
Chemical Name: Silver tetrafluoroborate
Synonyms: AGBF4;SILVER FLUOBORATE;ver tetrafL;SILVER BOROFLUORIDE;SILVER FLUOROBORATE;ilver tetrafluoroborat;SILVER TETRAFLUOROBORATE;SLIVER TERTRAFLUOROBORATE;SilverTetrafluoroborate>Silvertetrafluoroborate,99%
CBNumber: CB6437440
Molecular Formula: AgBF4
Formula Weight: 194.67
MOL File: 14104-20-2.mol

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Silver tetrafluoroborate Property

Melting point:: 70-73 °C(lit.)
storage temp.: Store below +30°C.
solubility: Acetonitrile (Slightly), Methanol (Very Slightly)
form: Crystalline Powder
color: White to pale brown
Water Solubility: SOLUBLE
Sensitive: Hygroscopic
Exposure limits: ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
InChIKey: CCAVYRRHZLAMDJ-UHFFFAOYSA-N
CAS DataBase Reference: 14104-20-2(CAS DataBase Reference)
EPA Substance Registry System: Borate(1-), tetrafluoro-, silver(1+) (14104-20-2)

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Safety

Hazard Codes: C
Risk Statements: 34-22-20/21/22
Safety Statements: 26-36/37/39-45-27
RIDADR: UN 3260 8/PG 2
WGK Germany: 3
RTECS: ED2875000
F: 3-8-10-21
Hazard Note: Corrosive
TSCA: T
HazardClass: 6.1
PackingGroup: III
HS Code: 28432900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 208361
Product name: Silver tetrafluoroborate
Purity: 98%
Packaging: 1g
Price: $39.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.18881
Product name: Silver tetrafluoroborate
Purity: for synthesis
Packaging: 5G
Price: $126
Updated: 2024/03/01

Sigma-Aldrich

Product number: 208361
Product name: Silver tetrafluoroborate
Purity: 98%
Packaging: 10g
Price: $147
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.18881
Product name: Silver tetrafluoroborate
Purity: for synthesis
Packaging: 25g
Price: $493
Updated: 2023/01/07

TCI Chemical

Product number: S0446
Product name: Silver Tetrafluoroborate
Purity: >98.0%(T)
Packaging: 5g
Price: $99
Updated: 2024/03/01

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Silver tetrafluoroborate Chemical Properties,Usage,Production

Chemical Properties

beige crystalline powder

Uses

Silver tetrafluoroborate finds applications as a useful reagent in inorganic, organic and organomettalic chemistry. It acts as a moderately strong oxidant in dichloromethane, replaces halide anions and ligands with weakly coordinating tetrafluoroborate anions, and behaves as a catalyst for cyclization reactions. It is a potent promoter for chemical glycosylation.

Application

Silver tetrafluoroborate is a transition metal salt extensively used in organic syntheses.
Gold Catalysts — 21st Century ′Gold Rush′
Displaces chloride from precious metal complexes used in the oxidation of alcohols by persulfate.
Provides a silver-ion template for improved macrolatamization of a linear dipeptide.

General Description

Silver tetrafluoroborate (AgBF4) is used as a Lewis acid in organic synthesis. It is known to have a high affinity towards organic halides. It is employed in organic reactions like activation of acyl chlorides, nucleophilic substitution, rearrangement, cycloaddition, cyclization, ring expansion and oxidation.

reaction suitability

reagent type: oxidant

Safety Profile

Poison by intravenous route. When heated to decomposition it emits toxic fumes of F-. Used for plating baths. See also SILVER COMPOUNDS, BORON COMPOUNDS, and FLUORIDES.

Synthesis

Preparation of silver tetrafluoroborate and MBDP
This reaction is completed with the lights off. In a 25 mL round-bottom flask covered with aluminum foil, AgBF4 (0.0397 g (0.20 mmol) is dissolved in 10 mL CH3CN. To the solution MBDP (0.0645 g, 0.20 mmol) is added and allowed to stir for 3 hours. The solution is concentrated under vacuum to approximately 3 mL then layered with Et2O. The flask is placed in the freezer. X-ray quality crystals are formed.

Silver tetrafluoroborate Preparation Products And Raw materials

Raw materials

Preparation Products

N,N,N',N'-TETRAMETHYL-2-BUTENE-1,4-DIAMINE Suprofen Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

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Silver tetrafluoroborate Suppliers

Belgium 4 China 122 Europe 1 France 2 Germany 7 India 9 Japan 7 Slovakia 1 South Africa 1 Switzerland 1 The Netherlands 1 United Kingdom 10 United States 45 Global 211

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 4009004166/18616739031 18616739031
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Nanjing Pharmaluxury Co., Ltd.

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Energy Chemical

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Meryer (Shanghai) Chemical Technology Co., Ltd.

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Beijing Donghualituo Techonlogy Development Co.,Ltd.

Tel: 010-88425576
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Email: sales@dhltchem.com
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Alfa Aesar

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Email: saleschina@alfa-asia.com
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TCI (Shanghai) Development Co., Ltd.

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Beijing Ouhe Technology Co., Ltd

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Fax: +86-10-82967029
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Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

Shanghai Sinch Parmaceuticals Tech. Co. Ltd.

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Fax: +86-21-54096319
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ProdList: 11598
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View Lastest Price from Silver tetrafluoroborate manufacturers

henan kanbei chemical co.,ltd

Product: Silver tetrafluoroborate 14104-20-2
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-22

Honest Joy Holdings Limited

Product: Silver tetrafluoroborate 14104-20-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.5%
Supply Ability: 100 tons
Release date: 2022-01-26

Zhuozhou Wenxi import and Export Co., Ltd

Product: Silver tetrafluoroborate 14104-20-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

14104-20-2, Silver tetrafluoroborate Related Search:

NITROSONIUM TETRAFLUOROBORATE Potassium tetrafluoroborate Trimethyloxonium Tetrafluoroborate AZURE B TETRAFLUOROBORATE Zinc tetrafluoroborate Ammonium fluoborate Cupric tetrafluoroborate hydrate Mercury NITRONIUM TETRAFLUOROBORATE Silver Fluoroboric acid Lithium tetrafluoroborate Lead(II) tetrafluoroborate Cadmium fluoroborate Sodium tetrafluoroborate 1-BUTYLPYRIDINIUM TETRAFLUOROBORATE FERROUS FLUOBORATE Boron

Silver tetrafluoroborate 99%

SLIVER TERTRAFLUOROBORATE

Silver(I) tetrafluoroborate anhydrous, AgBF4

Silvertetrafluoroborate,99%

tetrafluoro-borate(1-silver(1+)

tetrafluoro-borate(1-silver(1++)

FLUOROBORIC ACID SILVER SALT

Fluoroboric acid silver(I) salt~Silver(I) fluoborate~Silver(I) fluoroborate

Silver tetrafluoroborate, 99.99+% metals basis

SILVER TETRAFLUOROBORATE ANHYDROUS

SILVER BOROFLUORIDE

SILVER FLUOBORATE

SILVER FLUOROBORATE

SILVER(I) TETRAFLUOROBORATE

SILVER TETRAFLUOROBORATE

TETRAFLUOROBORIC ACID SILVER SALT

AGBF4

Silver tetrafluoroborate, 99% 10GR

Silver tetrafluoroborate, 99% 1GR

Silver tetrafluoroborate, 99% 50GR

Silver tetrafluoroborate ,99% [55.6% Ag]

Silver tetrafluoroborate/ 95+%

Silver tetrafluoroborate,Silver borofluoride

Silver tetrafluoroborate ,99% [55.4% Ag]

Silver(I) tetrafluoroborate 99%

Silver tetrafluoroborate, 55.4% Ag

Silver tetrafluoroborate >=99.99% trace metals basis

Dichlorobis(cyclopentadienyl)hafnium-Silver(I) Salts

ilver tetrafluoroborat

Borate(1-),tetrafluoro-,silver(1+)

SILVER TETRAFLUOROBORATESILVER TETRAFLUOROBORATESILVER TETRAFLUOROBORATE

SilverTetrafluoroborate&gt

ver tetrafL

14104-20-2

Catalysis and Inorganic Chemistry

Tetrafluoroborates

Classes of Metal Compounds

Transition Metal Compounds

Ag (Silver) Compounds

B (Classes of Boron Compounds)

halometallate salts

Catalysis and Inorganic Chemistry

Chemical Synthesis

Materials Science

Metal and Ceramic Science

Salts

Silver

Silver Salts

Gold Catalysis

Silver Additives

Classes of Metal Compounds

Tetrafluoroborates

Transition Metal Compounds

Ag (Silver) Compounds

B (Classes of Boron Compounds)