3-METHYL-4-NITROBENZONITRILE

Product Name: 3-METHYL-4-NITROBENZONITRILE
CAS No.: 96784-54-2
Chemical Name: 3-METHYL-4-NITROBENZONITRILE
Synonyms: -METHYL-4-NITROBENZO;4-NITRO-M-TOLUNITRILE;5-Cyano-2-nitrotoluene;3-METHYL-4-NITROBENZONITRILE;4-Nitro-3-methylbenzonitrile;Benzonitrile, 3-methyl-4-nitro-;3-Methyl-4-nitrobenzonitrile 97%;5-Cyano-2-nitrotoluene, 4-Nitro-m-tolunitrile;5-Cyano-2-nitrotoluene, 4-Cyano-2-methylnitrobenzene
CBNumber: CB6456984
Molecular Formula: C8H6N2O2
Formula Weight: 162.15
MOL File: 96784-54-2.mol

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3-METHYL-4-NITROBENZONITRILE Property

Melting point:: 81-83°C
Boiling point:: 322.2±30.0 °C(Predicted)
Density: 1.26±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
Appearance: White to light brown Solid
Water Solubility: Insoluble in water
BRN: 2443778
CAS DataBase Reference: 96784-54-2(CAS DataBase Reference)

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Safety

Hazard Codes: T,Xi
Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-36/37/39-45-36
RIDADR: 3439
Hazard Note: Toxic
HazardClass: 6.1
PackingGroup: III
HS Code: 2926907090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Usbiological

Product number: 281555
Product name: 3-Methyl-4-nitrobenzonitrile
Packaging: 1g
Price: $319
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0023785
Product name: 3-METHYL-4-NITROBENZONITRILE
Purity: 95.00%
Packaging: 5G
Price: $838.07
Updated: 2021/12/16

AK Scientific

Product number: 6780AC
Product name: 3-Methyl-4-nitrobenzonitrile
Packaging: 25g
Price: $388
Updated: 2021/12/16

Alichem

Product number: 96784542
Product name: 4-Cyano-2-methylnitrobenzene
Packaging: 250mg
Price: $484.8
Updated: 2021/12/16

Alichem

Product number: 96784542
Product name: 4-Cyano-2-methylnitrobenzene
Packaging: 500mg
Price: $831.3
Updated: 2021/12/16

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3-METHYL-4-NITROBENZONITRILE Chemical Properties,Usage,Production

Uses

3-Methyl-4-nitrobenzonitrile is used to produce 4-amino-3-methyl-benzonitrile.

Synthesis

99584-85-7

96784-54-2

General procedure for the synthesis of 3-methyl-4-nitrobenzonitrile from 3-methyl-4-nitrobenzamide: 3-methyl-4-nitrobenzamide (5 g, 28 mmol) was dissolved in 300 ml of toluene under stirring conditions, followed by the slow addition of phosphorus oxychloride (POCl3, 22 g, 140 mmol). After the addition was completed, the reaction mixture was heated to reflux for 24 hours. Upon completion of the reaction, the mixture was carefully poured into ice water and extracted three times with ethyl acetate. The organic phases were combined, dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure. Finally, the residue was purified by ethanol recrystallization to afford the target product 3-methyl-4-nitrobenzonitrile (3.2 g, 70% yield).

References

[1] Patent: WO2014/172871, 2014, A1. Location in patent: Page/Page column 88
[2] Justus Liebigs Annalen der Chemie, 1867, vol. 144, p. 182
[3] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1973, p. 2940 - 2948
[4] Patent: US5034410, 1991, A

3-METHYL-4-NITROBENZONITRILE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-METHYL-4-NITROBENZONITRILE Suppliers

Belgium 1 China 61 France 1 Germany 5 India 12 The Netherlands 1 United Kingdom 18 United States 28 Global 127

J & K SCIENTIFIC LTD.

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View Lastest Price from 3-METHYL-4-NITROBENZONITRILE manufacturers

Career Henan Chemical Co

Product: 3-METHYL-4-NITROBENZONITRILE 96784-54-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-11

96784-54-2, 3-METHYL-4-NITROBENZONITRILERelated Search:

3-METHYL-4-NITROBENZONITRILE 4-METHYL-2-NITROBENZONITRILE 4-METHYL-3-NITROBENZONITRILE 2-METHYL-6-NITROBENZONITRILE 3-FORMYL-4-NITROBENZONITRILE 2-METHYL-3-NITROBENZOYL CHLORIDE 2-METHYL-5-NITROBENZONITRILE 4-Methyl-3-nitrobenzoyl chloride 4-Nitrobenzoyl chloride m-Tolunitrile 4-Nitrobenzonitrile Benzoyl chloride 2-METHYL-4-NITROBENZONITRILE 98 4-BROMO-3-METHYL-5-NITROBENZONITRILE 5-CHLORO-4-METHYL-2-NITROBENZONITRILE 2-METHYL-3-NITROBENZONITRILE 3-Methyl-5-nitrobenzonitrile 3-Methyl-2-nitrobenzoyl chloride ,97%

4-NITRO-M-TOLUNITRILE

3-METHYL-4-NITROBENZONITRILE

3-Methyl-4-nitrobenzonitrile 97%

5-Cyano-2-nitrotoluene, 4-Cyano-2-methylnitrobenzene

-METHYL-4-NITROBENZO

5-Cyano-2-nitrotoluene, 4-Nitro-m-tolunitrile

4-Nitro-3-methylbenzonitrile

Benzonitrile, 3-methyl-4-nitro-

5-Cyano-2-nitrotoluene

96784-54-2

Aromatic Nitriles