ChemicalBook > CAS DataBase List > 3-METHYL-4-NITROBENZONITRILE

3-METHYL-4-NITROBENZONITRILE

Product Name
3-METHYL-4-NITROBENZONITRILE
CAS No.
96784-54-2
Chemical Name
3-METHYL-4-NITROBENZONITRILE
Synonyms
-METHYL-4-NITROBENZO;4-NITRO-M-TOLUNITRILE;5-Cyano-2-nitrotoluene;3-METHYL-4-NITROBENZONITRILE;4-Nitro-3-methylbenzonitrile;Benzonitrile, 3-methyl-4-nitro-;3-Methyl-4-nitrobenzonitrile 97%;5-Cyano-2-nitrotoluene, 4-Nitro-m-tolunitrile;5-Cyano-2-nitrotoluene, 4-Cyano-2-methylnitrobenzene
CBNumber
CB6456984
Molecular Formula
C8H6N2O2
Formula Weight
162.15
MOL File
96784-54-2.mol
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3-METHYL-4-NITROBENZONITRILE Property

Melting point:
81-83°C
Boiling point:
322.2±30.0 °C(Predicted)
Density 
1.26±0.1 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
Appearance
White to light brown Solid
Water Solubility 
Insoluble in water
BRN 
2443778
CAS DataBase Reference
96784-54-2(CAS DataBase Reference)
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Safety

Hazard Codes 
T,Xi
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36/37/39-45-36
RIDADR 
3439
Hazard Note 
Toxic
HazardClass 
6.1
PackingGroup 
III
HS Code 
2926907090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Usbiological
Product number
281555
Product name
3-Methyl-4-nitrobenzonitrile
Packaging
1g
Price
$319
Updated
2021/12/16
AK Scientific
Product number
6780AC
Product name
3-Methyl-4-nitrobenzonitrile
Packaging
25g
Price
$388
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0023785
Product name
3-METHYL-4-NITROBENZONITRILE
Purity
95.00%
Packaging
5G
Price
$838.07
Updated
2021/12/16
Ambeed
Product number
A199491
Product name
3-Methyl-4-nitrobenzonitrile
Purity
97%
Packaging
250mg
Price
$7
Updated
2021/12/16
Ambeed
Product number
A199491
Product name
3-Methyl-4-nitrobenzonitrile
Purity
97%
Packaging
1g
Price
$19
Updated
2021/12/16
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3-METHYL-4-NITROBENZONITRILE Chemical Properties,Usage,Production

Uses

3-Methyl-4-nitrobenzonitrile is used to produce 4-amino-3-methyl-benzonitrile.

Synthesis

99584-85-7

96784-54-2

General procedure for the synthesis of 3-methyl-4-nitrobenzonitrile from 3-methyl-4-nitrobenzamide: 3-methyl-4-nitrobenzamide (5 g, 28 mmol) was dissolved in 300 ml of toluene under stirring conditions, followed by the slow addition of phosphorus oxychloride (POCl3, 22 g, 140 mmol). After the addition was completed, the reaction mixture was heated to reflux for 24 hours. Upon completion of the reaction, the mixture was carefully poured into ice water and extracted three times with ethyl acetate. The organic phases were combined, dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure. Finally, the residue was purified by ethanol recrystallization to afford the target product 3-methyl-4-nitrobenzonitrile (3.2 g, 70% yield).

References

[1] Patent: WO2014/172871, 2014, A1. Location in patent: Page/Page column 88
[2] Justus Liebigs Annalen der Chemie, 1867, vol. 144, p. 182
[3] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1973, p. 2940 - 2948
[4] Patent: US5034410, 1991, A

3-METHYL-4-NITROBENZONITRILE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-METHYL-4-NITROBENZONITRILE Suppliers

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View Lastest Price from 3-METHYL-4-NITROBENZONITRILE manufacturers

Career Henan Chemical Co
Product
3-METHYL-4-NITROBENZONITRILE 96784-54-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-11

96784-54-2, 3-METHYL-4-NITROBENZONITRILERelated Search:

3-METHYL-4-NITROBENZONITRILE 4-METHYL-2-NITROBENZONITRILE 4-METHYL-3-NITROBENZONITRILE 2-METHYL-6-NITROBENZONITRILE 3-FORMYL-4-NITROBENZONITRILE 2-METHYL-3-NITROBENZOYL CHLORIDE 2-METHYL-5-NITROBENZONITRILE 4-Methyl-3-nitrobenzoyl chloride 4-Nitrobenzoyl chloride m-Tolunitrile 4-Nitrobenzonitrile Benzoyl chloride 2-METHYL-4-NITROBENZONITRILE 98 4-BROMO-3-METHYL-5-NITROBENZONITRILE 5-CHLORO-4-METHYL-2-NITROBENZONITRILE 2-METHYL-3-NITROBENZONITRILE 3-Methyl-5-nitrobenzonitrile 3-Methyl-2-nitrobenzoyl chloride ,97%

  • 4-NITRO-M-TOLUNITRILE
  • 3-METHYL-4-NITROBENZONITRILE
  • 3-Methyl-4-nitrobenzonitrile 97%
  • 5-Cyano-2-nitrotoluene, 4-Cyano-2-methylnitrobenzene
  • -METHYL-4-NITROBENZO
  • 5-Cyano-2-nitrotoluene, 4-Nitro-m-tolunitrile
  • 4-Nitro-3-methylbenzonitrile
  • Benzonitrile, 3-methyl-4-nitro-
  • 5-Cyano-2-nitrotoluene
  • 96784-54-2
  • Aromatic Nitriles