4-Nitrobenzoyl chloride
- Product Name
- 4-Nitrobenzoyl chloride
- CAS No.
- 122-04-3
- Chemical Name
- 4-Nitrobenzoyl chloride
- Synonyms
- P-NITROBENZOYL CHLORIDE;PNBC;4-Nitrobenzoyl;SKL748;4-Nitrobenzoyl chlor;p-Nitrobenzoyl chlori;LABOTEST-BB LT00077260;4-nitro-benzoylchlorid;p-nitro-benzoylchlorid;NITROBENZOYL-4 CHLORIDE
- CBNumber
- CB2182076
- Molecular Formula
- C7H4ClNO3
- Formula Weight
- 185.56
- MOL File
- 122-04-3.mol
4-Nitrobenzoyl chloride Property
- Melting point:
- 71-74 °C (lit.)
- Boiling point:
- 202-205 °C/105 mmHg (lit.)
- Density
- 1.53
- refractive index
- 1.5890 (estimate)
- Flash point:
- 102 °C
- storage temp.
- Store below +30°C.
- solubility
- Soluble in terahydrofuran, dichloromethane, chloroform and pyridine.
- form
- Flakes or Crystals
- color
- Yellow
- Odor
- pungent odor
- Water Solubility
- Decomposes
- Sensitive
- Moisture Sensitive
- Merck
- 14,6589
- BRN
- 473192
- Stability:
- Stable, but moisture sensitive. Combustible. Incompatible with water, alcohols, strong oxidizing agents, strong bases.
- InChIKey
- SKDHHIUENRGTHK-UHFFFAOYSA-N
- CAS DataBase Reference
- 122-04-3(CAS DataBase Reference)
- NIST Chemistry Reference
- 4-Nitrobenzoic acid chloride(122-04-3)
- EPA Substance Registry System
- p-Nitrobenzoyl chloride (122-04-3)
Safety
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 2
- RTECS
- DM6651000
- F
- 9-19-21
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29163900
- Toxicity
- LD50 orally in Rabbit: 5600 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
N-Bromosuccinimide Price
- Product number
- 8.06772
- Product name
- 4-Nitrobenzoyl chloride
- Purity
- for synthesis
- Packaging
- 5G
- Price
- $26.2
- Updated
- 2024/03/01
- Product number
- 8.06772
- Product name
- 4-Nitrobenzoyl chloride
- Purity
- for synthesis
- Packaging
- 250g
- Price
- $111
- Updated
- 2024/03/01
- Product number
- 112208
- Product name
- 4-Nitrobenzoyl chloride
- Purity
- 98%
- Packaging
- 50g
- Price
- $43.7
- Updated
- 2024/03/01
- Product number
- 112208
- Product name
- 4-Nitrobenzoyl chloride
- Purity
- 98%
- Packaging
- 250g
- Price
- $93.8
- Updated
- 2024/03/01
- Product number
- N0176
- Product name
- 4-Nitrobenzoyl Chloride
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $22
- Updated
- 2023/06/20
4-Nitrobenzoyl chloride Chemical Properties,Usage,Production
Chemical Properties
yellow needles or powder
Uses
4-Nitrobenzoyl chloride is used in the preparation of polysubstituted furanonaphthoquinoines. It is also involved in Michael addition, Henry reaction, O-alkylation and cycloaddition reactions. Further, it is employed as an intermediate in active pharmaceutical ingredient and dyes.
Uses
4-Nitrobenzoyl Chloride is used inorganic syntheses such as Michael additions. Also used in the synthesis of polysubstituted furanonaphthoquinoines.
General Description
Yellow needles or powder with a pungent odor.
Air & Water Reactions
Unstable in moist surroundings and should be kept in a tightly-closed container. React with water or steam .
Reactivity Profile
4-Nitrobenzoyl chloride is incompatible with bases (including amines), with strong oxidizing agents, and with alcohols. May react with reducing agents. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
Health Hazard
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
Flash point data are not available for 4-Nitrobenzoyl chloride, but 4-Nitrobenzoyl chloride is combustible.
Safety Profile
Moderately toxic by ingestion. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx and Cl-. See also NITRO COhlPOUNDS OF AROMATIC HYDROCARBONS and CHLORIDES.
Purification Methods
Crystallise the acid chloride from dry pet ether (b 60-80o), *C6H6 or CCl4. Distil it under vacuum. Irritant. [Adama & Jenkins Org Synth Coll Vol I 394 1941, Beilstein 9 III 1709, 9 IV 1191.]
4-Nitrobenzoyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
4-Nitrobenzoyl chloride Suppliers
- Tel
- 028-83379370 13880556291
- Fax
- 028-87747383
- tcy@tcypharm.com
- Country
- China
- ProdList
- 6269
- Advantage
- 58
- Tel
- 021-2022843681 15618226720
- Fax
- +86-21-51601218
- lucy@atkchemical.com
- Country
- China
- ProdList
- 9920
- Advantage
- 58
- Tel
- 027-65526929 15102793023
- Fax
- 027-65526669
- hbhxry@foxmail.com
- Country
- China
- ProdList
- 2006
- Advantage
- 55
- Tel
- +8615866703830
- figo.gao@foxmail.com
- Country
- China
- ProdList
- 8497
- Advantage
- 58
- Tel
- +86-021-50456736 +8613761615711
- Fax
- 021-50761379
- yuki@riyngroup.com
- Country
- China
- ProdList
- 1028
- Advantage
- 58
- Tel
- 027-027-82752821 18186694582
- Fax
- 027-82752821
- 323495346@qq.com
- Country
- China
- ProdList
- 3583
- Advantage
- 58
- Tel
- 18072846723; 18072846723
- caigou1@witofly.com
- Country
- China
- ProdList
- 3037
- Advantage
- 58
- Tel
- 18171205315
- 1213219329@qq.com
- Country
- China
- ProdList
- 5087
- Advantage
- 58
- Tel
- +86-020-81960175-617 +8615602392859
- Intermediate@cato-chem.com
- Country
- China
- ProdList
- 8046
- Advantage
- 58