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Trospium chloride

Product Name
Trospium chloride
CAS No.
10405-02-4
Chemical Name
Trospium chloride
Synonyms
Trospium;Trosupium Chloride;Sanctura;asxvii;keptan;spasmex;spasmo3;relaspium;Spasmo-lyt;trospiuM-D8
CBNumber
CB6481397
Molecular Formula
C25H30ClNO3
Formula Weight
427.96
MOL File
10405-02-4.mol
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Trospium chloride Property

Melting point:
266-268°C
storage temp. 
Inert atmosphere,2-8°C
solubility 
Very soluble in water, freely soluble in methanol, practically insoluble in methylene chloride.
form 
Solid
color 
White to Off-White
Merck 
14,9786
InChIKey
RVCSYOQWLPPAOA-QKYUOBHYSA-M
SMILES
[N+]12(CCCC1)[C@@]1([H])CC[C@]2([H])C[C@@H](C1)OC(=O)C(O)(C1=CC=CC=C1)C1C=CC=CC=1.[Cl-] |&1:5,9,12,r|
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Safety

RTECS 
WH1424000
HS Code 
2939800000
Toxicity
Soly in water: ~1 g/2 ml. LD50 in mice (mg/kg): 12.3 i.v. (Antweiler)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
Y0000429
Product name
Trospium chloride
Purity
European Pharmacopoeia (EP) Reference Standard
Packaging
y0000429
Price
$220
Updated
2024/03/01
Sigma-Aldrich
Product number
PHR3378
Product name
Trospium chloride
Purity
certified reference material, pharmaceutical secondary standard
Packaging
200MG
Price
$344
Updated
2024/03/01
Sigma-Aldrich
Product number
1699300
Product name
Trospium chloride
Packaging
100mg
Price
$956
Updated
2024/03/01
TCI Chemical
Product number
T3305
Product name
Trospium Chloride
Purity
>98.0%(HPLC)(N)
Packaging
200mg
Price
$63
Updated
2024/03/01
TCI Chemical
Product number
T3305
Product name
Trospium Chloride
Purity
>98.0%(HPLC)(N)
Packaging
1g
Price
$188
Updated
2024/03/01
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Trospium chloride Chemical Properties,Usage,Production

Description

Trospium chloride (Sanctura) is an antimuscarinic that has been used in Europe for the management of OAB symptoms for over 30 years.Trospium chloride's chemical structure is such that it is unlikely to penetrate the brain and thus does not appear to affect cognitive function. Trospium chloride is usually administered orally twice a day in 20mg. Trospium chloride should be taken 1 hour before meals or on an empty stomach. It is not well absorbed if taken with food.An advantage of this medication is that it has little potential interaction with other medications.

Chemical Properties

White to Off-White Crystalline Solid

Originator

Keptan,Muller

Uses

Tropine derivative with anticholinergic activity, Trospium chloride can be used as Antispasmodic and used in treatment of urinary incontinence

Uses

An antimuscarinic compound that inhibits mAChR M

Uses

Labeled Trospium, intended for use as an internal standard for the quantification of Trospium by GC- or LC-mass spectrometry.

Definition

ChEBI: Trospium chloride is an organic chloride salt of trospium. It is an antispasmodic drug used for the treatment of overactive bladder. It has a role as a muscarinic antagonist and an antispasmodic drug. It is an organic chloride salt and a quaternary ammonium salt. It contains a trospium.

Manufacturing Process

12.7 g of nortropine and 21.6 g 1,4-dibrombutane are heated, with stirring,for 14 hours at 38-40°C in 200 ml 70% ethanol in the presence of a strongly basic ion exchanger. The reaction mixture is filtered, the filtrate brought to a pH of 4-5 by addition of dilute hydrochloric acid, then evaporated to dryness in a vacuum. The residue crystallized from ethanol-ether. Azoniaspiro-(3α- hydroxy-nortropan-8,1'-pyrrolidine) chloride is obtained in a yield of about 51%; melting point 294-297°C.
2.17 g azoniaspiro-(3α-hydroxy-nortropan-8,1'-pyrrolidine) chloride and 4.24 g acetyl mandelic acid chloride are heated in a vacuum (12 mm Hg) for 6n hours at 100°C. After the addition of 40 ml water, the reaction mixture is repeatedly extracted, the aqueous phase adjusted to pH 6.7-6.8 and continuously extracted with chloroform for 24 hours. After the addition of 20 ml concentrated hydrochloric acid, the residue of the chloroform extract is left to stand for 15 hours at room temperature. The hydrochloric acid is then removed in a vacuum, the residue taken up in absolute ethanol, filtered through aluminum oxide. The filtrate evaporated to dryness and the residue crystallized from methanol-acetone. Azoniaspiro(3α-benziloyloxy-nortropan- 8,1'-pyrrolidine)-chloride is obtained in a yield of about 20%; melting point 197-198°C.

brand name

Sanctura (Indevus).

Therapeutic Function

Anticholinergic, Spasmolytic

General Description

Trospium chloride, 3α-benziloyloxynortropane-8-spiro-1'-pyrrolidinium chloride, (Sanctura) was available in Europe for almost 20 years before gainingapproval in the United States in May 2004. Much likeoxybutynin, it too is a competitive antagonist for muscarinicreceptors and is used to manage overactive bladder. Thequaternary amine reduces the likelihood that this agent willcross the blood-brain barrier. In addition, it has a limitedmetabolic profile, largely a result of its highly water-solublecharacteristics.

Clinical Use

Antimuscarinic:
Symptomatic treatment of urinary incontinence, frequency or urgency

Drug interactions

Potentially hazardous interactions with other drugs
Anti-arrhythmics: increased risk of antimuscarinic side effects with disopyramide.

Metabolism

The metabolic pathway of trospium in humans has not been fully defined. Of the 10
% of the dose absorbed, metabolites account for approximately 40
% of the excreted dose following oral administration. The major metabolic pathway is hypothesised as ester hydrolysis with subsequent conjugation of benzylic acid to form azoniaspironortropanol with glucuronic acid.
The mean renal clearance for trospium (29 L/hour) is 4-fold higher than average glomerular filtration rate, indicating that active tubular secretion is a major route of elimination for trospium. There may be competition for elimination with other compounds that are also renally eliminated.

Trospium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Trospium chloride Suppliers

Beijing Mediking Biopharm Co., Ltd
Tel
010-81769521,89753524,81760121 15901403431
Fax
+86-10-81769652
Email
sales01@mediking.cn
Country
China
ProdList
704
Advantage
68
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Chembest Research Laboratories Limited
Tel
+86-21-20908456
Fax
021-58180499
Email
sales@BioChemBest.com
Country
China
ProdList
6005
Advantage
61
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10186
Advantage
62
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14103
Advantage
59
LGM Pharma
Tel
1-(800)-881-8210
Fax
615-250-9817
Email
inquiries@lgmpharma.com
Country
United States
ProdList
2123
Advantage
70
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768850
Email
1791901229@qq.com
Country
China
ProdList
8843
Advantage
52
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9815
Advantage
79
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View Lastest Price from Trospium chloride manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Trospium chloride 10405-02-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%-101%;BP
Supply Ability
100 kgs
Release date
2022-11-14
Wuhan Senwayer Century Chemical Co.,Ltd
Product
Trospium chloride 10405-02-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 TONS
Release date
2022-11-07
Zibo Hangyu Biotechnology Development Co., Ltd
Product
Trospium chloride 10405-02-4
Price
US $55.00-550.00/kg
Min. Order
10kg
Purity
0.99
Supply Ability
20tons
Release date
2023-11-20

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