ChemicalBook > CAS DataBase List > Cyclopropylmagnesium bromide

Cyclopropylmagnesium bromide

Product Name
Cyclopropylmagnesium bromide
CAS No.
23719-80-4
Chemical Name
Cyclopropylmagnesium bromide
Synonyms
CyclopropylMagnesiuM;opropyL;Cyclopropylbromomagnesium;Bromocyclopropylmagnesium;tri-n-butyl-cyclopropyltin;yclopropylmagnesium bromide;CYCLOPROPYLMAGNESIUM BROMIDE;CYCLOPROPYL MAGENSIUM BROMIDE;magnesium cyclopropane bromide;Cyclopropylmagnesium bromide in 0.5
CBNumber
CB6494654
Molecular Formula
C3H5BrMg
Formula Weight
145.28
MOL File
23719-80-4.mol
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Cyclopropylmagnesium bromide Property

Boiling point:
65 °C
Density 
0.968 g/mL at 25 °C
Flash point:
65°C
storage temp. 
2-8°C
form 
Turbid Liquid
color 
Yellow to green
Water Solubility 
Soluble in water (17 mg/ml), (25°C). Soluble in organic solvents.
Sensitive 
Air & Moisture Sensitive
InChIKey
QUPLLJGAJVXXBW-UHFFFAOYSA-M
CAS DataBase Reference
23719-80-4(CAS DataBase Reference)
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Safety

Hazard Codes 
F,Xi,C
Risk Statements 
11-14-19-36/37/38-40-37-34
Safety Statements 
16-26-45-36/37/39
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
1
HazardClass 
4.3
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H260In contact with water releases flammable gases which may ignite spontaneously

H261In contact with water releases flammable gas

H302Harmful if swallowed

H313May be harmful in contact with skin

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

H371May cause damage to organs

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P335+P334Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
526797
Product name
Cyclopropylmagnesium bromide solution
Purity
0.5 M in THF
Packaging
100ml
Price
$323
Updated
2024/03/01
Sigma-Aldrich
Product number
526797
Product name
Cyclopropylmagnesium bromide solution
Purity
0.5 M in THF
Packaging
800ml
Price
$1194
Updated
2024/03/01
TCI Chemical
Product number
C2039
Product name
Cyclopropylmagnesium Bromide (ca. 10% in Tetrahydrofuran, ca. 0.7mol/L)
Packaging
100g
Price
$231
Updated
2024/03/01
Alfa Aesar
Product number
H26273
Product name
Cyclopropylmagnesium bromide, 0.5M-0.7M in THF
Packaging
100ml
Price
$288
Updated
2024/03/01
Alfa Aesar
Product number
H26273
Product name
Cyclopropylmagnesium bromide, 0.5M-0.7M in THF
Packaging
25ml
Price
$85.2
Updated
2021/12/16
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Cyclopropylmagnesium bromide Chemical Properties,Usage,Production

Chemical Properties

Clear colorless solution

Uses

It often acts as the starting nutrient mix for dropout studies where fermentation conditions required the absence of one or more essential amino acids. For classifying Yeasts based on colonial characteristics and cell morphology.

Uses

Cyclopropylmagnesium bromide solution has been used in Grignard reaction that finds application as the key step in the preparation of aminopropylindenes, a chemotype of oxidosqualene cyclase (OSC) inhibitors from Grundmann′s ketone. It can react with trimethylborate to form cyclopropylboronic acid, which can undergo Suzuki-type coupling reactions with different aryl, and heteroaryl bromides to form the cyclopropyl adducts.

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

General Description

This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.

Cyclopropylmagnesium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Cyclopropylmagnesium bromide manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Cyclopropylmagnesium bromide 23719-80-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
Cyclopropylmagnesium bromide 23719-80-4
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-25

23719-80-4, Cyclopropylmagnesium bromideRelated Search:

Dicyclopropane methylamine Allyl bromide ETHYNYLMAGNESIUM BROMIDE Sodium bromate Ethidium bromide Propylthiouracil Cyclopropyl acetylene Cyclopropanecarbonitrile Methylmagnesium Bromide Cyclopropyl bromide Cyclopropyl methyl ketone Cyclopropanesulfonyl chloride Rocuronium bromide Allyl chloride Benzyl bromide Magnesium bromide 1,1-Bis(hydroxymethyl)cyclopropane ALPHA-CYCLOPROPYLBENZYL ALCOHOL

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  • 23719-80-4
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  • C3H5MgBr
  • C3H5BrMg
  • Cyclopropanes
  • Grignard Reagents & Alkyl Metals
  • Simple 3-Membered Ring Compounds
  • Grignard Reagents
  • Organometallic Reagents
  • Alkyl
  • Grignard Reagent
  • 25mL Sure/Seal Reagents
  • Chemical Synthesis
  • Organometallic Reagents
  • Cyclopropanes
  • Grignard Reagents
  • Grignard Reagents & Alkyl Metals
  • Simple 3-Membered Ring Compounds
  • Synthetic Organic Chemistry
  • Alkyl