(2S)-(+)-GLYCIDYL 4-NITROBENZOATE

Product Name: (2S)-(+)-GLYCIDYL 4-NITROBENZOATE
CAS No.: 115459-65-9
Chemical Name: (2S)-(+)-GLYCIDYL 4-NITROBENZOATE
Synonyms: Ccris 6396;Brn 0087687;(S)-(+)-GLYCIDYL-4-NITROBENZOATE;(2S)-(+)-GLYCIDYL 4-NITROBENZOATE;(2S)-(+)-Glycidyl 4-nitr0benzoate;4-nitrobenzoate,(s)-oxiranemethano;2,3-EPOXYPROPYLESTER-4-NITROBENZOATE;Oxiranemethanol, 4-nitrobenzoate, (S)-;(S)-(+)-Oxirane-2-methanol 4-nitrobenzoate;4-17-00-01007 (Beilstein Handbook Reference)
CBNumber: CB6722979
Molecular Formula: C10H9NO5
Formula Weight: 223.18
MOL File: 115459-65-9.mol

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(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Property

Melting point:: 60-62 °C (lit.)
storage temp.: 2-8°C
optical activity: [α]19/D +37°, c = 1.08 in chloroform
BRN: 87687

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
RTECS: RR0511020
F: 10-21

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 300446
Product name: (2S)-(+)-Glycidyl 4-nitrobenzoate
Purity: 98%
Packaging: 1g
Price: $78.5
Updated: 2023/01/07

AHH

Product number: MT-14276
Product name: (2S)-(+)-Glycidyl4-nitr0benzoate
Purity: 98%
Packaging: 25g
Price: $430
Updated: 2021/12/16

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(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Chemical Properties,Usage,Production

Purification Methods

Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D 20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D 20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.] Gramine.

(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Suppliers

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115459-65-9, (2S)-(+)-GLYCIDYL 4-NITROBENZOATERelated Search:

2,5-(+)-GLYCIDYL 4-NITROBENZOATE (2R)-(-)-GLYCIDYL 4-NITROBENZOATE (2S)-(+)-GLYCIDYL 4-NITROBENZOATE,(S)-(+)-GLYCIDYL-4-NITROBENZOATE (S)-(+)-Benzyl glycidyl ether 2,3-epoxypropyl benzoate (R)-(+)-Glycidol (2R)-(+)-3 3-DIMETHYLGLYCIDYL (S)-(+)-Methyl glycidyl ether (2S)-(+)-2-METHYLGLYCIDYL 4-NITROBENZOATE PROPYL 4-NITROBENZOATE Ethyl p-nitrobenzoate (2R,3S)-(+)-3-(BENZYLOXYMETHYL)OXIRANE-2-METHANOL 4-NITROBENZOIC ACID ESTER S-Glycidyl Acetate BENZYL GLYCIDYL ETHER (2S)-(+)-GLYCIDYL 4-NITROBENZOATE

(2S)-(+)-GLYCIDYL 4-NITROBENZOATE

(S)-(+)-GLYCIDYL-4-NITROBENZOATE

(2s)-(+)-(2,3-epoxypropylester)-4-nitrobenzoate

4-nitrobenzoate,(s)-oxiranemethano

(2S)-(+)-Glycidyl 4-nitr0benzoate

4-17-00-01007 (Beilstein Handbook Reference)

2,3-EPOXYPROPYLESTER-4-NITROBENZOATE

(S)-(+)-Glycidyl 4-nitrobenzoate, (S)-(+)-Oxirane-2-methanol 4-nitrobenzoate

(S)-(+)-Oxirane-2-methanol 4-nitrobenzoate

Brn 0087687

Ccris 6396

Oxiranemethanol, 4-nitrobenzoate, (S)-

2-Oxiranemethanol, 2-(4-nitrobenzoate), (2S)-

115459-65-9

Epoxides

Organic Building Blocks

Asymmetric Synthesis

Chiral Building Blocks