ChemicalBook > CAS DataBase List > (2S)-(+)-GLYCIDYL 4-NITROBENZOATE

(2S)-(+)-GLYCIDYL 4-NITROBENZOATE

Product Name
(2S)-(+)-GLYCIDYL 4-NITROBENZOATE
CAS No.
115459-65-9
Chemical Name
(2S)-(+)-GLYCIDYL 4-NITROBENZOATE
Synonyms
Ccris 6396;Brn 0087687;(S)-(+)-GLYCIDYL-4-NITROBENZOATE;(2S)-(+)-GLYCIDYL 4-NITROBENZOATE;(2S)-(+)-Glycidyl 4-nitr0benzoate;4-nitrobenzoate,(s)-oxiranemethano;2,3-EPOXYPROPYLESTER-4-NITROBENZOATE;Oxiranemethanol, 4-nitrobenzoate, (S)-;(S)-(+)-Oxirane-2-methanol 4-nitrobenzoate;4-17-00-01007 (Beilstein Handbook Reference)
CBNumber
CB6722979
Molecular Formula
C10H9NO5
Formula Weight
223.18
MOL File
115459-65-9.mol
More
Less

(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Property

Melting point:
60-62 °C (lit.)
storage temp. 
2-8°C
optical activity
[α]19/D +37°, c = 1.08 in chloroform
BRN 
87687
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
RR0511020
F 
10-21
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
300446
Product name
(2S)-(+)-Glycidyl 4-nitrobenzoate
Purity
98%
Packaging
1g
Price
$78.5
Updated
2023/01/07
AHH
Product number
MT-14276
Product name
(2S)-(+)-Glycidyl4-nitr0benzoate
Purity
98%
Packaging
25g
Price
$430
Updated
2021/12/16
More
Less

(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Chemical Properties,Usage,Production

Purification Methods

Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D 20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D 20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.] Gramine.

(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(2S)-(+)-GLYCIDYL 4-NITROBENZOATE Suppliers

China 3 Germany 1 Switzerland 1 United Kingdom 1 United States 4 Global 10
SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91

115459-65-9, (2S)-(+)-GLYCIDYL 4-NITROBENZOATERelated Search:

2,5-(+)-GLYCIDYL 4-NITROBENZOATE (2R)-(-)-GLYCIDYL 4-NITROBENZOATE (2S)-(+)-GLYCIDYL 4-NITROBENZOATE,(S)-(+)-GLYCIDYL-4-NITROBENZOATE (S)-(+)-Benzyl glycidyl ether 2,3-epoxypropyl benzoate (R)-(+)-Glycidol (2R)-(+)-3 3-DIMETHYLGLYCIDYL (S)-(+)-Methyl glycidyl ether (2S)-(+)-2-METHYLGLYCIDYL 4-NITROBENZOATE PROPYL 4-NITROBENZOATE Ethyl p-nitrobenzoate (2R,3S)-(+)-3-(BENZYLOXYMETHYL)OXIRANE-2-METHANOL 4-NITROBENZOIC ACID ESTER S-Glycidyl Acetate BENZYL GLYCIDYL ETHER (2S)-(+)-GLYCIDYL 4-NITROBENZOATE

  • (2S)-(+)-GLYCIDYL 4-NITROBENZOATE
  • (S)-(+)-GLYCIDYL-4-NITROBENZOATE
  • (2s)-(+)-(2,3-epoxypropylester)-4-nitrobenzoate
  • 4-nitrobenzoate,(s)-oxiranemethano
  • (2S)-(+)-Glycidyl 4-nitr0benzoate
  • 4-17-00-01007 (Beilstein Handbook Reference)
  • 2,3-EPOXYPROPYLESTER-4-NITROBENZOATE
  • (S)-(+)-Glycidyl 4-nitrobenzoate, (S)-(+)-Oxirane-2-methanol 4-nitrobenzoate
  • (S)-(+)-Oxirane-2-methanol 4-nitrobenzoate
  • Brn 0087687
  • Ccris 6396
  • Oxiranemethanol, 4-nitrobenzoate, (S)-
  • 2-Oxiranemethanol, 2-(4-nitrobenzoate), (2S)-
  • 115459-65-9
  • Epoxides
  • Organic Building Blocks
  • Asymmetric Synthesis
  • Chiral Building Blocks