(R)-(+)-Glycidol

Product Name: (R)-(+)-Glycidol
CAS No.: 57044-25-4
Chemical Name: (R)-(+)-Glycidol
Synonyms: (R)-Oxiran-2-ylMethanol;(R)-GLYCIDOL;(R)-Oxiranemethanol;EOS-60676;R-Glycidoe;(R)-(+)-GL;(+)-Glycidol;(R)-GLYCIDOL,99%;(R)-(+)-GLYCIDOL;(r)-oxiranemethano
CBNumber: CB5205831
Molecular Formula: C3H6O2
Formula Weight: 74.08
MOL File: 57044-25-4.mol

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(R)-(+)-Glycidol Property

Boiling point:: 56-57 °C11 mm Hg(lit.)
Density: 1.116 g/mL at 20 °C(lit.)
refractive index: n20/D 1.43(lit.)
Flash point:: 178 °F
storage temp.: -20°C
Water Solubility: Completely miscible in water
solubility: Chloroform (Slightly), DMSO (Slightly)
pka: 14.62±0.10(Predicted)
color: Colorless to Light yellow
optical activity: [α]23/D +15°, neat
BRN: 79782
Stability:: Moisture Sensitive
InChIKey: CTKINSOISVBQLD-GSVOUGTGSA-N
CAS DataBase Reference: 57044-25-4(CAS DataBase Reference)
NIST Chemistry Reference: Oxiranemethanol, (R)-(57044-25-4)

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Safety

Hazard Codes: T,E
Risk Statements: 45-60-2-21/22-23-34-68-41-37/38
Safety Statements: 53-45-36/37/39-26
RIDADR: UN 2922 8/PG 2
WGK Germany: 3
RTECS: RR0508000
F: 10-21
HazardClass: 6.1
PackingGroup: Ⅲ
HS Code: 29109000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H227Combustible liquid

H242Heating may cause a fire

H302Harmful if swallowed

H312Harmful in contact with skin

H314Causes severe skin burns and eye damage

H315Causes skin irritation

H319Causes serious eye irritation

H330Fatal if inhaled

H331Toxic if inhaled

H335May cause respiratory irritation

H341Suspected of causing genetic defects

H350May cause cancer

H361Suspected of damaging fertility or the unborn child

H370Causes damage to organs

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P307+P311IF exposed: call a POISON CENTER or doctor/physician.

P310Immediately call a POISON CENTER or doctor/physician.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 480819
Product name: (R)-(+)-Glycidol
Purity: 97%, optical purity ee: 98% (GLC)
Packaging: 1g
Price: $50.1
Updated: 2023/06/20

TCI Chemical

Product number: G0363
Product name: (R)-(+)-Glycidol
Purity: >98.0%(GC)
Packaging: 5g
Price: $86
Updated: 2024/03/01

TCI Chemical

Product number: G0363
Product name: (R)-(+)-Glycidol
Purity: >98.0%(GC)
Packaging: 25g
Price: $291
Updated: 2024/03/01

TRC

Product number: G615695
Product name: (R)-(+)-Glycidol
Packaging: 10g
Price: $215
Updated: 2021/12/16

TRC

Product number: G615695
Product name: (R)-(+)-Glycidol
Packaging: 5g
Price: $135
Updated: 2021/12/16

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(R)-(+)-Glycidol Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

(R)-(+)-Glycidol may be used in the following synthesis:

heteroarylpropane-2,3-diols, useful for combinatorial oligomer synthesis
enantiomerically pure (2S,3S)- and (2S,3R)-threoninol and -hydroxyphenylalaninol
2-amino-1,4-anhydro-pentitol and 3-amino-1,5-anhydro-4-deoxy-hexitol with the arabino configuration
(S)-4-tosyloxymethyl-2-oxazolidinone, required for the synthesis of protected amino alcohol derivatives
1-(S)-[3-hydroxy-2-(phosphonomethoxy)propyl]cytosine [(S)-HPMPC]
chiral building block used to construct an epoxyvinyl iodide intermediate in a synthesis of a furanocembrane, a marine natural product

Uses

(R)-(+)-Glycidol can be used to construct chiral building blocks of epoxyvinyl iodide intermediates in the synthesis of furanocembrane, a marine natural product.

Definition

ChEBI: (R)-glycidol is a glycidol. It is functionally related to a (R)-1,2-epoxypropane. It is an enantiomer of a (S)-glycidol.

General Description

Enantioselective esterification of (R)-(+)-glycidol with n-butyric acid in organic media using hybrid gel-entrapped lipase on Celite has been reported.

Purification Methods

[S(-)-isomer, § also available on polymer support, has b 49-50o/7mm, 66-67o/19mm, [ ] D -1 5o(neat)], [R(+)-isomer has b 56 -5 6 . 5o/11mm, d 4 1.117, n D 1.429, [ ] D +15o (neat)]. Purify glycidol by fractional distillation.

(R)-(+)-Glycidol Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-(+)-Methyl glycidyl ether

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(R)-(+)-Glycidol Suppliers

Americas 1 Belgium 1 Canada 1 CHINA 214 China Hong Kong 1 Europe 4 Germany 3 India 16 Japan 1 South Korea 2 Switzerland 1 United Kingdom 12 United States 47 Global 304

Changzhou Huaren Chemical Co., Ltd

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Energy Chemical

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View Lastest Price from (R)-(+)-Glycidol manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (R)-(+)-Glycidol 57044-25-4
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: (R)-(+)-Glycidol 57044-25-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 95%-99%
Supply Ability: 2000kg
Release date: 2019-08-05

57044-25-4, (R)-(+)-GlycidolRelated Search:

Allyl glycidyl ether Ethylene glycol diglycidyl ether DIGLYCIDYL ETHER Propylene oxide 1,2,3-PROPANETRIOL GLYCIDYL ETHER CHLOROPHOSPHONAZO III ETHYLENE OXIDE Methanol Glycidol methyl ether (S)-Glycidol 3-Nitrobenzenesulfonate (S)-(+)-Benzyl glycidyl ether (2S)-(+)-Glycidyl tosylate (+/-)-GLYCIDOL,(RS)-Glycido BISPHENOL A DIGLYCIDYL ETHER RESIN Cinobufagin Cinobufotalin Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate Glycidol phenyl ether

EOS-60676

(r)-oxiranemethano

(R)-(+)-2,3-EPOXY-1-PROPANOL

(R)-(+)-GLYCIDOL

(R)-GLYCIDOL

R(+)-OXIRANE-2-METHANOL

(R)-Oxiranemethanol

OXIRANEMETHANOL, (2R)-

(R)-GLYCIDOL,99%

(R)-3-Hydroxy-1,2-epoxypropane

(R)-(+)-GLYCIDOL, 97% (98% EE/GLC)

R-Glycidoe

(R)-(+)-GLYCIDOL ((R)-(+)-2,3-EPOXY-1-PROPANOL)

(2R)-Oxirane-2-methanol

(R)-2-Hydroxymethyloxirane

(R)-(+)-Glycidol,(R)-(+)-Oxirane-2-methanol

(R)-Oxiran-2-ylMethanol

(R)-(+)-1-Hydroxy-2,3-epoxypropane (R)-(+)-2-(Hydroxymethyl)oxirane

(R)-(+)-Glycidol 97%, optical purity ee: 98% (GLC)

2-Oxiranemethanol, (2R)-

(R)-(+)-1-Hydroxy-2,3-epoxypropane

(R)-(+)-Glycidol≥ 99% (GC)

(R)-(+)-Oxirane-2-methanol (R)-(+)-1-Hydroxy-2,3-epoxypropane (R)-(+)-2-(Hydroxymethyl)oxirane

(R)-(+)-Glycidol&gt

(R)-(+)-GL

97%, optical purity ee: 98% (GLC)

(+)-Glycidol

57044-25-4

C3H6O2

Asymmetric Synthesis

Chiral Building Blocks

Organic Building Blocks

Epoxides

Chiral Compound

CHIRAL COMPOUNDS

chiral

API intermediates