ChemicalBook > CAS DataBase List > (R)-(+)-Glycidol

(R)-(+)-Glycidol

Product Name
(R)-(+)-Glycidol
CAS No.
57044-25-4
Chemical Name
(R)-(+)-Glycidol
Synonyms
(R)-Oxiran-2-ylMethanol;(R)-GLYCIDOL;(R)-Oxiranemethanol;EOS-60676;R-Glycidoe;(R)-(+)-GL;(+)-Glycidol;(R)-GLYCIDOL,99%;(R)-(+)-GLYCIDOL;(r)-oxiranemethano
CBNumber
CB5205831
Molecular Formula
C3H6O2
Formula Weight
74.08
MOL File
57044-25-4.mol
More
Less

(R)-(+)-Glycidol Property

Boiling point:
56-57 °C11 mm Hg(lit.)
Density 
1.116 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.43(lit.)
Flash point:
178 °F
storage temp. 
-20°C
Water Solubility 
Completely miscible in water
solubility 
Chloroform (Slightly), DMSO (Slightly)
pka
14.62±0.10(Predicted)
color 
Colorless to Light yellow
optical activity
[α]23/D +15°, neat
BRN 
79782
Stability:
Moisture Sensitive
InChIKey
CTKINSOISVBQLD-GSVOUGTGSA-N
CAS DataBase Reference
57044-25-4(CAS DataBase Reference)
NIST Chemistry Reference
Oxiranemethanol, (R)-(57044-25-4)
More
Less

Safety

Hazard Codes 
T,E
Risk Statements 
45-60-2-21/22-23-34-68-41-37/38
Safety Statements 
53-45-36/37/39-26
RIDADR 
UN 2922 8/PG 2
WGK Germany 
3
RTECS 
RR0508000
F 
10-21
HazardClass 
6.1
PackingGroup 
Ⅲ
HS Code 
29109000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H227Combustible liquid

H242Heating may cause a fire

H302Harmful if swallowed

H312Harmful in contact with skin

H314Causes severe skin burns and eye damage

H315Causes skin irritation

H319Causes serious eye irritation

H330Fatal if inhaled

H331Toxic if inhaled

H335May cause respiratory irritation

H341Suspected of causing genetic defects

H350May cause cancer

H361Suspected of damaging fertility or the unborn child

H370Causes damage to organs

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P307+P311IF exposed: call a POISON CENTER or doctor/physician.

P310Immediately call a POISON CENTER or doctor/physician.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
480819
Product name
(R)-(+)-Glycidol
Purity
97%, optical purity ee: 98% (GLC)
Packaging
1g
Price
$50.1
Updated
2023/06/20
TCI Chemical
Product number
G0363
Product name
(R)-(+)-Glycidol
Purity
>98.0%(GC)
Packaging
5g
Price
$86
Updated
2024/03/01
TCI Chemical
Product number
G0363
Product name
(R)-(+)-Glycidol
Purity
>98.0%(GC)
Packaging
25g
Price
$291
Updated
2024/03/01
TRC
Product number
G615695
Product name
(R)-(+)-Glycidol
Packaging
10g
Price
$215
Updated
2021/12/16
TRC
Product number
G615695
Product name
(R)-(+)-Glycidol
Packaging
5g
Price
$135
Updated
2021/12/16
More
Less

(R)-(+)-Glycidol Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

(R)-(+)-Glycidol may be used in the following synthesis:

  • heteroarylpropane-2,3-diols, useful for combinatorial oligomer synthesis
  • enantiomerically pure (2S,3S)- and (2S,3R)-threoninol and -hydroxyphenylalaninol
  • 2-amino-1,4-anhydro-pentitol and 3-amino-1,5-anhydro-4-deoxy-hexitol with the arabino configuration
  • (S)-4-tosyloxymethyl-2-oxazolidinone, required for the synthesis of protected amino alcohol derivatives
  • 1-(S)-[3-hydroxy-2-(phosphonomethoxy)propyl]cytosine [(S)-HPMPC]
  • chiral building block used to construct an epoxyvinyl iodide intermediate in a synthesis of a furanocembrane, a marine natural product

Uses

(R)-(+)-Glycidol can be used to construct chiral building blocks of epoxyvinyl iodide intermediates in the synthesis of furanocembrane, a marine natural product.

Definition

ChEBI: (R)-glycidol is a glycidol. It is functionally related to a (R)-1,2-epoxypropane. It is an enantiomer of a (S)-glycidol.

General Description

Enantioselective esterification of (R)-(+)-glycidol with n-butyric acid in organic media using hybrid gel-entrapped lipase on Celite has been reported.

Purification Methods

[S(-)-isomer, § also available on polymer support, has b 49-50o/7mm, 66-67o/19mm, [ ] D -1 5o(neat)], [R(+)-isomer has b 56 -5 6 . 5o/11mm, d 4 1.117, n D 1.429, [ ] D +15o (neat)]. Purify glycidol by fractional distillation.

(R)-(+)-Glycidol Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-(+)-Methyl glycidyl ether
More
Less

(R)-(+)-Glycidol Suppliers

Americas 1 Belgium 1 Canada 1 CHINA 211 China Hong Kong 1 Europe 4 Germany 3 India 16 Japan 1 South Korea 2 Switzerland 1 United Kingdom 12 United States 47 Global 301
Changzhou Huaren Chemical Co., Ltd
Tel
0519-88103998 13646148298
Fax
0519-88104456
Email
amy.zhou@huarenchem.com
Country
China
ProdList
56
Advantage
63
Sichuan Hainuowei Technology Co. Ltd.
Tel
13708085536
Fax
QQ : 121102042
Email
hanovichem@163.com
Country
China
ProdList
3389
Advantage
56
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94838
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40240
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15848
Advantage
69
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2341
Advantage
56
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1392
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44700
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12458
Advantage
60
Shanghai Scientia Pharmaceutical Technology Co., Ltd.
Tel
21-21-54301573 13917723525
Fax
(86)21-51861981
Email
sales@scientiapharm.com
Country
China
ProdList
263
Advantage
62
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9984
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9550
Advantage
66
ChengDu TongChuangYuan Pharmaceutical Co.Ltd
Tel
28-83379370 13880556291
Fax
028-87747383
Email
tcy@tcypharm.com
Country
China
ProdList
511
Advantage
57
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11660
Advantage
64
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9816
Advantage
59
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
18089
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
Country
China
ProdList
42982
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
13355009207 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18739
Advantage
57
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
6854
Advantage
65
BEST-REAGENT
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11726
Advantage
57
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14443
Advantage
57
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
+8613162137806 18575662672
Fax
021 51613951
Email
mzeng@3wpharm.com
Country
China
ProdList
9745
Advantage
57
Spectrum Chemical Manufacturing Corp.
Tel
021-021-021-67601398-809-809-809 15221380277
Fax
021-57711696
Email
marketing_china@spectrumchemical.com
Country
China
ProdList
9664
Advantage
60
Wuhan Haizheng Industry & Trade Development Co. Ltd
Tel
027-8866 0053/88660577/88660578
Fax
027-8899 1911
Country
China
ProdList
1076
Advantage
55
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9725
Advantage
55
Beijing HuaMeiHuLiBiological Chemical
Tel
010-56205725
Fax
010-65763397
Email
waley188@sohu.com
Country
China
ProdList
12338
Advantage
58
Shanghai Topbiochem Technology Co., Ltd
Tel
021-58170097
Email
info@topbiochem.com
Country
China
ProdList
9449
Advantage
58
Shanghai Topbiochem Technology Co., Ltd
Tel
+86-21-60341587
Fax
+86-21-61294319
Email
sales@topbiochem.com
Country
China
ProdList
6181
Advantage
58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66099280 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19918
Advantage
55
Shanghai Jian Chao Chemical Technology Co., Ltd.
Tel
18017383231 18017383231
Fax
qq：2817624287
Email
lyh_antaeus@163.com
Country
China
ProdList
9352
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22519
Advantage
55
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
18521735133 18521732826;
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25014
Advantage
65
Shanghai Arbor Chemical Co., Ltd.
Tel
021-021-60451683 15021268886
Fax
+86-21-60451682
Email
sales@arborchemical.com
Country
China
ProdList
922
Advantage
55
Shanghai Yolne Chemical Co., Ltd.
Tel
021-62960152
Fax
021-52212593
Email
934678158@qq.com
Country
China
ProdList
9906
Advantage
55
Wuxi Zhangkun Biochemical Technology Co., Ltd.
Tel
+86 0510-85629785
Fax
+86 0510-85625359
Country
China
ProdList
2331
Advantage
58
Bide Pharmatech Ltd.
Tel
400-1647117 15221909166
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41438
Advantage
60
Chongqing Xingcan Pharmaceutical Technology Co., Ltd.
Tel
15523000485
Email
xingcanyaoye@sina.com
Country
China
ProdList
1686
Advantage
58
Chengdu Firster Pharmaceutical Co., Ltd.
Tel
028-87078428 028-87074958
Fax
8772-8116
Email
chengzhenyong@cdfirster.com
Country
China
ProdList
1989
Advantage
60
Credit-Chem Co., Ltd.
Tel
400-821-5857 021-64326257
Fax
021-64393586 QQ;2798200800
Email
credit-chem@foxmail.com
Country
China
ProdList
5223
Advantage
58
Shanghai YuLue Chemical Co., Ltd.
Tel
021-60345187 13671753212
Fax
021-34702061
Email
lzz841106@aliyun.com
Country
China
ProdList
10287
Advantage
55
SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.
Tel
021-69106960 13701823733
Fax
021-69106780
Email
13701823733@163.com
Country
China
ProdList
4775
Advantage
60
Shanghai Jovan Biochemical Technology Co. Ltd.
Tel
+86-021-61654350
Fax
+86-021-61654350
Email
1245958370@qq.com
Country
China
ProdList
2984
Advantage
50
Beijing Holiyang Chemical Co. Ltd.
Tel
13718199399
Fax
QQ : 206661479
Email
holiyangchem@163.com
Country
China
ProdList
3387
Advantage
56
Shanghai YouPeng Chemical Co. Ltd.
Tel
021-69005955 13701776567
Fax
021-69005775
Email
youpengchem@163.com
Country
China
ProdList
4303
Advantage
56
Shanghai TongYuan Chemical Co., Ltd.
Tel
021-021-69182866 13701855675
Fax
021-69182022
Email
tongyuanchem@126.com
Country
China
ProdList
4331
Advantage
58
Shanghai Kaisai Chemical Co., Ltd
Tel
021-33516722 13701817765
Fax
021-33516776
Email
kaisaichem@163.com
Country
China
ProdList
4751
Advantage
58
Shanghai LanRun Chemical Co., Ltd.
Tel
021-69515658 ; 69515628 13701998368
Fax
021-69515998
Email
longrunchem@163.com
Country
China
ProdList
3920
Advantage
50
Shanghai Rolead Chemical Technology Co., Ltd.
Tel
021-69992220 13701886816
Fax
021-69992237
Email
roleadchem@163.com
Country
China
ProdList
4759
Advantage
50
More
Less

View Lastest Price from (R)-(+)-Glycidol manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(R)-(+)-Glycidol 57044-25-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
(R)-(+)-Glycidol 57044-25-4
Price
US $1.00/KG
Min. Order
1KG
Purity
95%-99%
Supply Ability
2000kg
Release date
2019-08-05

57044-25-4, (R)-(+)-GlycidolRelated Search:

Allyl glycidyl ether Ethylene glycol diglycidyl ether DIGLYCIDYL ETHER Propylene oxide 1,2,3-PROPANETRIOL GLYCIDYL ETHER CHLOROPHOSPHONAZO III ETHYLENE OXIDE Methanol Glycidol methyl ether (S)-Glycidol 3-Nitrobenzenesulfonate (S)-(+)-Benzyl glycidyl ether (2S)-(+)-Glycidyl tosylate (+/-)-GLYCIDOL,(RS)-Glycido BISPHENOL A DIGLYCIDYL ETHER RESIN Cinobufagin Cinobufotalin Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate Glycidol phenyl ether

  • EOS-60676
  • (r)-oxiranemethano
  • (R)-(+)-2,3-EPOXY-1-PROPANOL
  • (R)-(+)-GLYCIDOL
  • (R)-GLYCIDOL
  • R(+)-OXIRANE-2-METHANOL
  • (R)-Oxiranemethanol
  • OXIRANEMETHANOL, (2R)-
  • (R)-GLYCIDOL,99%
  • (R)-3-Hydroxy-1,2-epoxypropane
  • (R)-(+)-GLYCIDOL, 97% (98% EE/GLC)
  • R-Glycidoe
  • (R)-(+)-GLYCIDOL ((R)-(+)-2,3-EPOXY-1-PROPANOL)
  • (2R)-Oxirane-2-methanol
  • (R)-2-Hydroxymethyloxirane
  • (R)-(+)-Glycidol,(R)-(+)-Oxirane-2-methanol
  • (R)-Oxiran-2-ylMethanol
  • (R)-(+)-1-Hydroxy-2,3-epoxypropane (R)-(+)-2-(Hydroxymethyl)oxirane
  • (R)-(+)-Glycidol 97%, optical purity ee: 98% (GLC)
  • 2-Oxiranemethanol, (2R)-
  • (R)-(+)-1-Hydroxy-2,3-epoxypropane
  • (R)-(+)-Glycidol≥ 99% (GC)
  • (R)-(+)-Oxirane-2-methanol (R)-(+)-1-Hydroxy-2,3-epoxypropane (R)-(+)-2-(Hydroxymethyl)oxirane
  • (R)-(+)-Glycidol&gt
  • (R)-(+)-GL
  • 97%, optical purity ee: 98% (GLC)
  • (+)-Glycidol
  • 57044-25-4
  • C3H6O2
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Organic Building Blocks
  • Epoxides
  • Chiral Compound
  • CHIRAL COMPOUNDS
  • chiral
  • API intermediates