(S)-(+)-Glycidyl nosylate

Uses

Product Name: (S)-(+)-Glycidyl nosylate
CAS No.: 115314-14-2
Chemical Name: (S)-(+)-Glycidyl nosylate
Synonyms: (S)-GLYCIDYL NOSYLATE;(S)-Oxiran-2-ylMethyl 3-nitrobenzenesulfonate;(S)-(+)-GLYCIDYL NOSYLATE;(S)-(+)-Glycidal nosylate;(S)-Glycidyl nosylate 98%;(S)-(+)-GLYCIDYL-3-NOSYLATE;(S)-Glycidyl Nosylate,98%e.e.;(S)-(+)-Glycidyl nosylate,98%;S-Glycidyl-3-Nitrobenzenesulfo;glycidyl 3-nitrobenzenesulfonate
CBNumber: CB1121317
Molecular Formula: C9H9NO6S
Formula Weight: 259.24
MOL File: 115314-14-2.mol

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(S)-(+)-Glycidyl nosylate Property

Melting point:: 61-65 °C
alpha: 21.5 º (c=2, CHCl3)
Boiling point:: 432.2±20.0 °C(Predicted)
Density: 1.5881 (rough estimate)
refractive index: 1.5270 (estimate)
storage temp.: Inert atmosphere,2-8°C
solubility: Soluble in chloroform, methylene chloride and tetrahydrofuran. Insoluble in hexane.
form: Needles or Powder
color: Off-white to yellow-brown
Sensitive: Moisture Sensitive
InChI: InChI=1S/C9H9NO6S/c11-10(12)7-2-1-3-9(4-7)17(13,14)16-6-8-5-15-8/h1-4,8H,5-6H2/t8-/m0/s1
InChIKey: AIHIHVZYAAMDPM-QMMMGPOBSA-N
SMILES: C1(S(OC[C@@H]2CO2)(=O)=O)=CC=CC([N+]([O-])=O)=C1
CAS DataBase Reference: 115314-14-2(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-5
Safety Statements: 37/39-26-36
RIDADR: UN 1325 4.1/PG II
RTECS: DB7192010
HazardClass: 4.1
PackingGroup: II
HS Code: 29209090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: G0287
Product name: (S)-Glycidyl 3-Nitrobenzenesulfonate
Purity: >98.0%(GC)
Packaging: 5g
Price: $75
Updated: 2025/07/31

TCI Chemical

Product number: G0287
Product name: (S)-Glycidyl 3-Nitrobenzenesulfonate
Purity: >98.0%(GC)
Packaging: 25g
Price: $220
Updated: 2025/07/31

TRC

Product number: G615980
Product name: (S)-(+)-GlycidylNosylate
Packaging: 25g
Price: $65
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK127037
Product name: (S)-(+)-Glycidylnosylate
Purity: 98%
Packaging: 1g
Price: $44
Updated: 2021/12/16

Chem-Impex

Product number: 39542
Product name: (S)-Glycidyl3-nitrobenzenesulfonate,98%(Chiralpurity,GC)
Purity: 98%(Chiralpurity,GC)
Packaging: 5G
Price: $78.4
Updated: 2021/12/16

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(S)-(+)-Glycidyl nosylate Chemical Properties,Usage,Production

Uses

(S)-(+)-Glycidyl Nosylate is a compound useful in organic synthesis.

Chemical Properties

white to light yellow crystal powde

Uses

(S)-(+)-Glycidyl Nosylate (cas# 115314-14-2) is a compound useful in organic synthesis.

Synthesis

121-51-7

57044-25-4

115314-14-2

General procedure for the synthesis of (S)-(+)-m-nitrobenzenesulfonic acid glycidyl ester from 3-nitrobenzenesulfonyl chloride and (R)-oxirane-2-methanol: at -20 °C, m-nitrobenzenesulfonyl chloride (12.6 g, 57 mmol) was slowly added to a solution containing (R)-(+)-glycidol (5.5 g, 74 mmol) and triethylamine (TEA, 10.3 mL. 74 mmol) in a cold solution. The reaction mixture was stirred continuously at -20 °C for 96 hours. Upon completion of the reaction, the reaction solution was filtered and the filtrate was washed sequentially with 10% (w/w) aqueous tartaric acid, saturated saline and deionized water. The washed organic phase was concentrated to afford the target product (S)-(+)-m-nitrobenzenesulfonic acid glycidyl ester in 97% yield. The structure of the product was confirmed by 1H NMR (CDCl3): δ 2.62 (dd, 1H), 2.84 (dd, 1H), 3.22 (m, 1H), 4.07 (dd, 1H), 4.49 (dd, 1H), 7.80 (t, 1H), 8.25 (m, 1H), 8.52 (m, 1H), 8.78 (m, 1H).

References

[1] Angewandte Chemie - International Edition, 2013, vol. 52, # 20, p. 5305 - 5308
[2] Angew. Chem., 2013, vol. 125, # 20, p. 5413 - 5416,4
[3] European Journal of Organic Chemistry, 2014, vol. 2014, # 19, p. 4053 - 4069
[4] Patent: US2004/229900, 2004, A1. Location in patent: Page 14
[5] Organic and Biomolecular Chemistry, 2006, vol. 4, # 16, p. 3067 - 3076

(S)-(+)-Glycidyl nosylate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (S)-(+)-Glycidyl nosylate manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: (S)-(+)-Glycidylnosylate 115314-14-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98
Supply Ability: 1KG 100KG 1MT
Release date: 2025-04-28

WUHAN FORTUNA CHEMICAL CO., LTD

Product: (S)-(+)-Glycidyl nosylate 115314-14-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-02

Shaanxi Dideu New Materials Co. Ltd

Product: (S)-(+)-Glycidylnosylate 115314-14-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2024-11-08

115314-14-2, (S)-(+)-Glycidyl nosylateRelated Search:

(R)-Glycidyl butyrate 1-Chloro-3-nitrobenzene ETHYLENE OXIDE Glycidyl tertcarbonate Sodium 3-nitrobenzenesulphonate Methanol 3-Nitrobenzaldehyde 4-Nitrophenyl chloroformate Glycidyl acrylate 3-Nitrobenzenesulfonyl chloride 3-NITROBENZENESULFONIC ACID 2,4,6-TRINITROBENZENESULFONIC ACID Benzenesulfonic acid (R)-(-)-GLYCIDYL NOSYLATE,(R)-GLYCIDYL NOSYLATE 1,3-Dinitrobenzene (R)-(+)-Glycidol Glycidol Glycerol

(2S)-OxiranylMethyl 3-Nitrobenzenesulfonate

(S)-Oxiran-2-ylMethyl 3-nitrobenzenesulfonate

(S)-(+)-Glycidyl nosylate, >=98.5%

Glycidyl (S)-(+)-3-nitrobenzenesulfonate

(S)-Glycidyl Nosylate,98%e.e.

(S)-(+)-OXIRANE-2-METHANOL 3-NITROBENZENESULFONATE

(S)-(+)-GLYCIDYL 3-NITROBENZENESULFONATE

(S)-GLYCIDYL 3-NITROBENZENESULFONATE

(S)-(+)-GLYCIDYL-3-NOSYLATE

(S)-(+)-GLYCIDYL NOSYLATE

(S)-GLYCIDYL NOSYLATE

(S)-(+)-GLYCIDYL 3-NITROBENZENESULFONATE 99%

(S)-(+)-Glycidyl 3-nitrobenzenesulfonate, (S)-(+)-Oxirane-2-methanol 3-nitrobenzenesulfonate

[(2S)-Oxiran-2-yl]methyl 3-nitrobenzenesulfonate

Benzenesulfonic acid, 3-nitro-, oxiranylmethyl ester, (S)

(S)-(+)-Glycidyl nosylate,98%

(S)-(+)-Glycidal nosylate

[(2S)-oxiran-2-yl]methyl 3-nitrobenzene-1-sulfonate

(S)-Glycidyl nosylate 98%

(S)-2,3-EPOXY-1-PROPYL-3-NITROBENZENESULFONATE

3-nitro-,oxiranylmethylester,(s)-benzenesulfonicaci

oxiranylmethyl(s)-3-nitrobenzenesulfonate

BENZENESULFONIC ACID, 3-NITRO-, (2S)-OXIRANYLMETHYL ESTER

3-NITROBENZENESULFONIC ACID (S)-GLYCIDYL ESTER

(2S)-(+)-GLYCIDYL-3-NITROBENZENESULFONATE

(2S)-(+)-GLYDICYL-3-NITROBENZENESULFONATE

(S)-Glycidol 3-Nitrobenzenesulfonate

3-Nitro-benzenesulfonic Acid Oxiranylmethyl Ester

S-Glycidyl-3-Nitrobenzenesulfo

glycidyl 3-nitrobenzenesulfonate

(S)-(+)-GLYCIDYL3-NITRO-BENZENESULPHONATE

GLYCIDYL3-NITROBENZENESULPHONATE

(2S)-glycidyl-3-nitrobenzenesulfonate (Landiolol)

(2S)-(+)-GLYCIDYL 3-NITROBENZENESULFONA

S(+)-GLYCIDYL 3-NITROBENZENELSULFONATE

3-NITRO-BENZENESULFONIC ACID (S)-1-OXIRANYLMETHYL ESTER

BENZENESULFONIC ACID, 3-NITRO-(2S)-2-OXIRANYL-METHYL ESTER

(S)-Glycidyl3-Nitrobenzenesulfonate&gt

(S)-(+)-Glycidyl nosylate ISO 9001：2015 REACH

TIANFUCHEM (S)-(+)-Glycidyl nosylate

(S)-(+)-Glycidylm-nitrobenzenesulfonate

115314-14-2

C9H9NO6S

Asymmetric Synthesis

Chiral Building Blocks

Epoxides

Organic Building Blocks

chiral

CHIRAL COMPOUNDS

Chiral Reagents

Heterocycles

Sulfur & Selenium Compounds

APIs Intermediate