TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE

Product Name: TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
CAS No.: 13170-43-9
Chemical Name: TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
Synonyms: TRIMETHYLSILYLMETHYL;siL;(Trimethylsilyl)methylmagnesium;(20% in Ethyl Ether, ca. 1Mol/L);Trimethylsilylmethylchloromagnesium;Trimethylsiylmethylmagnesium chloride;(Trimethylsilylmethyl)chloromagnesium;TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE;(trimethylsilyl)methylmagnesium chl. sol;TriMethylsilylMethylMagnesiuM Chloride
CBNumber: CB6732457
Molecular Formula: C4H11ClMgSi
Formula Weight: 146.97
MOL File: 13170-43-9.mol

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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Property

Melting point:: 105.8-106.4 °C
Density: 1.04
Flash point:: -40°C
storage temp.: Flammables + water-Freezer (-20°C)e area
solubility: Sol ethereal solvents; reacts with protic solvents.
form: Low Melting Solid
Specific Gravity: 0.912
color: Clear colorless to yellow to greenish
Sensitive: Air & Moisture Sensitive
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
BRN: 3587255
CAS DataBase Reference: 13170-43-9(CAS DataBase Reference)

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Safety

Hazard Codes: F+,C,F
Risk Statements: 12-14-22-34-66-67-19-11
Safety Statements: 16-26-36/37/39-43-45
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 1
F: 10
TSCA: No
HazardClass: 8
PackingGroup: II
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H313May be harmful in contact with skin

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H336May cause drowsiness or dizziness

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 256021
Product name: (Trimethylsilyl)methylmagnesium chloride solution
Purity: 1.0 M in diethyl ether
Packaging: 100ml
Price: $182
Updated: 2024/03/01

TCI Chemical

Product number: T1451
Product name: Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L)
Packaging: 100mL
Price: $108
Updated: 2024/03/01

TCI Chemical

Product number: T2609
Product name: Trimethylsilylmethylmagnesium Chloride (ca. 18% in Tetrahydrofuran, ca. 1mol/L)
Packaging: 100mL
Price: $119
Updated: 2024/03/01

Alfa Aesar

Product number: H54635
Product name: (Trimethylsilyl)methylmagnesium chloride
Purity: 0.5M in 2-MeTHF
Packaging: 100ml
Price: $137.65
Updated: 2024/03/01

TRC

Product number: T895985
Product name: (Trimethylsilyl)methylmagnesiumChloride,1.3MsolutioninTHF,J&KSeal
Packaging: 1mL
Price: $45
Updated: 2021/12/16

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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Grey liquid

Uses

Trimethylsilylmethylmagnesium Chloride is used in the methylenation of carbonyl compounds; provides a variety of methods to prepare allylsilanes.It participates in the reactions of Peterson Alkenation, Reaction with Carboxylic Acid Derivatives, Reaction with Alkyl Halides, Reaction with Sulfur Compounds, Reaction with Other Electrophiles, Cross-coupling Reactions, Carbometalation, and as a Generator of Alkyl Radicals from Alkyl Halides in the Presence of Cobalt Catalysts etc.

Uses

Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.

Preparation

From (chloromethyl)trimethylsilane and magnesium in an ethereal solvent.

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Suppliers

Belgium 3 China 128 Egypt 1 France 1 Germany 5 India 8 Japan 2 Singapore 2 South Korea 1 Switzerland 2 The Netherlands 1 United Kingdom 7 United States 19 Global 180

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
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Email: jkinfo@jkchemical.com
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Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
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Beijing Donghualituo Techonlogy Development Co.,Ltd.

Tel: 010-88425576
Fax: (+86)-10-88425546
Email: sales@dhltchem.com
Country: China
ProdList: 793
Advantage: 59

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
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BeiJing Hwrk Chemicals Limted

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Energy Chemical

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Beijing Ouhe Technology Co., Ltd

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Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696;
Email: info@hanhongsci.com
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Shandong Xiya Chemical Co., Ltd

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Email: 3007715519@qq.com
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View Lastest Price from TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE manufacturers

Hebei Guanlang Biotechnology Co., Ltd.

Product: trimethylsilylmethylmagnesium chloride 13170-43-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2022-11-15

Zhuozhou Wenxi import and Export Co., Ltd

Product: (Trimethylsilyl)methylmagnesium chloride solution 13170-43-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE 13170-43-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-07-04

13170-43-9, TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDERelated Search:

TRIMETHYLSILYLBENZENESULFONATE O-TOLYLMAGNESIUM BROMIDE 3,4,5-TRIMETHOXYPHENYLMAGNESIUM BROMIDE SOLUTION 0.5M IN TETRAHYDROFURAN 3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE Lithium diisopropylamide 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE 2-METHOXYBENZYLMAGNESIUM CHLORIDE 2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE 2-NAPHTHYLMAGNESIUM BROMIDE CYCLOPENTYLMAGNESIUM BROMIDE M-TOLYLMAGNESIUM CHLORIDE Zinc chloride Methylmagnesium Bromide TRIMETHYLSILANE Magnesium chloride TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Methylmagnesium chloride DIMETHYLETHYLSILYLMETHYLMAGNESIUM CHLORIDE

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE

(trimethylsilyl)methylmagnesium chl. sol

Trimethylsilylmethylmagnesium chloride (20% in ethyl ether

(TRIMETHYLSILYLMETHYL)MAGNESIUM CHLORIDE , 1.0M SOLUTION IN DIETHYL ETHER

(TRIMETHYLSILYL)METHYLMAGNESIUM CHL. SOL , 1 M IN DIETH.ETHER

[(Trimethylsilyl)methyl]magnesium Chloride 1.0 M In Diethyl Ether

[(Trimethylsilyl)methyl]magnesium Chloride, 1.0 M In Tetrahydrofuran

(Trimethylsilyl)methylmagnesium chloride, 1.1M solution in THF

(Trimethylsilyl)methylmagnesium chloride solution

Trimethylsiylmethylmagnesium chloride

Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L)

(TriMethylsilyl)MethylMagnesiuM chloride, 1.3 M solution in THF, SpcSeal

(trimethylsilyl) methyl magnesium chloride 1.3M tetrahydrofuran

(Trimethylsilyl)methylmagnesium chloride, 0.50 M in 2-MeTHF

(Trimethylsilyl)methylmagnesium chloride, 0.50 M in THF

(Trimethylsilyl)methylmagnesium chloride　1.3MTHF

(Trimethylsilyl)methylmagnesium chloride, 1,3m solution in THF

(Trimethylsilyl)methylmagnesium chloride1.3M solution in THFAcroSeal§3

(Trimethylsilylmethyl)chloromagnesium

Trimethylsilylmethylchloromagnesium

(Trimethylsilyl)methylmagnesium chloride solution 1.0 in diethyl ether

(Trimethylsilyl)methylmagnesium chloride, 1.3M solution in THF, AcroSeal

TriMethylsilylMethylMagnesiuM Chloride (ca. 18% in Tetrahydrofuran, ca. 1Mol/L)

(TriMethylsilyl)MethylMagnesiuM chloride, 1.3M solution in THF, AcroSeal 100ML

(TriMethylsilyl)MethylMagnesiuM chloride, 0.5M in 2-MeTHF

TRIMETHYLSILYLMETHYL

(20% in Ethyl Ether, ca. 1Mol/L)

TriMethylsilylMethylMagnesiuM Chloride&nbsp

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 3M in Methyltetrahydrofuran

(TriMethylsilyl)MethylMagnesiuM chloride, 1.0M solution in diethyl ether, J&KSeal

(TriMethylsilyl)MethylMagnesiuM chloride solution 1.0 M in diethyl ether

(TriMethylsilyl)MethylMagnesiuM chloride, 1.0 M solution in diethyl ether, SpcSeal

(TriMethylsilyl)MethylMagnesiuM chloride, 1.3 M solution in THF, J&KSeal

siL

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 3M in methyltetrahydrofuran (46-48 wt %)

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 1.0M in diethyl ether (19 wt %)

(Trimethylsilyl)methylmagnesium Chloride, Tetrahydrofuran Solution (abt. 1mol/l) [TMSCH2MgCl(THF)]

TIANFU CHEM-- TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE

Magnesium, chloro[(trimethylsilyl)methyl]- (7CI, 8CI, 9CI)

Trimethyl silyl methyl magnesium chloride 1. M in THF

(Trimethylsilyl)methylmagnesium

13170-43-9

CH33SiCH2MgCl

C4H11ClMgSi

Alkyl

Organometallic Reagents

Si-(C)4 Compounds

Grignard Reagents & Alkyl Metals

Grignard Reagents

Classes of Metal Compounds

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Typical Metal Compounds

Mg (Magnesium) Compounds

Si (Classes of Silicon Compounds)

Si-(C)4 Compounds

Silicon Compounds (for Synthesis)

Synthetic Organic Chemistry