ChemicalBook > CAS DataBase List > TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
- Product Name
- TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
- CAS No.
- 13170-43-9
- Chemical Name
- TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
- Synonyms
- TRIMETHYLSILYLMETHYL;siL;(Trimethylsilyl)methylmagnesium;(20% in Ethyl Ether, ca. 1Mol/L);Trimethylsilylmethylchloromagnesium;Trimethylsiylmethylmagnesium chloride;(Trimethylsilylmethyl)chloromagnesium;TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE;(trimethylsilyl)methylmagnesium chl. sol;TriMethylsilylMethylMagnesiuM Chloride
- CBNumber
- CB6732457
- Molecular Formula
- C4H11ClMgSi
- Formula Weight
- 146.97
- MOL File
- 13170-43-9.mol
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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Property
- Melting point:
- 105.8-106.4 °C
- Density
- 1.04
- Flash point:
- -40°C
- storage temp.
- Flammables + water-Freezer (-20°C)e area
- solubility
- Sol ethereal solvents; reacts with protic solvents.
- form
- Low Melting Solid
- Specific Gravity
- 0.912
- color
- Clear colorless to yellow to greenish
- Sensitive
- Air & Moisture Sensitive
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- BRN
- 3587255
- CAS DataBase Reference
- 13170-43-9(CAS DataBase Reference)
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Safety
- Hazard Codes
- F+,C,F
- Risk Statements
- 12-14-22-34-66-67-19-11
- Safety Statements
- 16-26-36/37/39-43-45
- RIDADR
- UN 3399 4.3/PG 1
- WGK Germany
- 1
- F
- 10
- TSCA
- No
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29319090
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H302Harmful if swallowed
H313May be harmful in contact with skin
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H336May cause drowsiness or dizziness
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P405Store locked up.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 256021
- Product name
- (Trimethylsilyl)methylmagnesium chloride solution
- Purity
- 1.0 M in diethyl ether
- Packaging
- 100ml
- Price
- $182
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T1451
- Product name
- Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L)
- Packaging
- 100mL
- Price
- $108
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T2609
- Product name
- Trimethylsilylmethylmagnesium Chloride (ca. 18% in Tetrahydrofuran, ca. 1mol/L)
- Packaging
- 100mL
- Price
- $119
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- H54635
- Product name
- (Trimethylsilyl)methylmagnesium chloride
- Purity
- 0.5M in 2-MeTHF
- Packaging
- 100ml
- Price
- $137.65
- Updated
- 2024/03/01
TRC
- Product number
- T895985
- Product name
- (Trimethylsilyl)methylmagnesiumChloride,1.3MsolutioninTHF,J&KSeal
- Packaging
- 1mL
- Price
- $45
- Updated
- 2021/12/16
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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Chemical Properties,Usage,Production
Chemical Properties
Grey liquid
Uses
Trimethylsilylmethylmagnesium Chloride is used in the methylenation of carbonyl compounds; provides a variety of methods to prepare allylsilanes.It participates in the reactions of Peterson Alkenation, Reaction with Carboxylic Acid Derivatives, Reaction with Alkyl Halides, Reaction with Sulfur Compounds, Reaction with Other Electrophiles, Cross-coupling Reactions, Carbometalation, and as a Generator of Alkyl Radicals from Alkyl Halides in the Presence of Cobalt Catalysts etc.
Uses
Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.
Preparation
From (chloromethyl)trimethylsilane and magnesium in an ethereal solvent.
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Suppliers
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View Lastest Price from TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE manufacturers
Hebei Guanlang Biotechnology Co., Ltd.
- Product
- trimethylsilylmethylmagnesium chloride 13170-43-9
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2022-11-15
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- (Trimethylsilyl)methylmagnesium chloride solution 13170-43-9
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
Career Henan Chemical Co
- Product
- TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE 13170-43-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1kg,5kg,100kg
- Release date
- 2019-07-04
13170-43-9, TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDERelated Search:
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