ChemicalBook > CAS DataBase List > TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE

Product Name
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
CAS No.
13170-43-9
Chemical Name
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
Synonyms
TRIMETHYLSILYLMETHYL;siL;(Trimethylsilyl)methylmagnesium;(20% in Ethyl Ether, ca. 1Mol/L);Trimethylsilylmethylchloromagnesium;Trimethylsiylmethylmagnesium chloride;(Trimethylsilylmethyl)chloromagnesium;TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE;(trimethylsilyl)methylmagnesium chl. sol;TriMethylsilylMethylMagnesiuM Chloride 
CBNumber
CB6732457
Molecular Formula
C4H11ClMgSi
Formula Weight
146.97
MOL File
13170-43-9.mol
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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Property

Melting point:
105.8-106.4 °C
Density 
1.04
Flash point:
-40°C
storage temp. 
Flammables + water-Freezer (-20°C)e area
solubility 
Sol ethereal solvents; reacts with protic solvents.
form 
Low Melting Solid
Specific Gravity
0.912
color 
Clear colorless to yellow to greenish
Sensitive 
Air & Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
BRN 
3587255
CAS DataBase Reference
13170-43-9(CAS DataBase Reference)
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Safety

Hazard Codes 
F+,C,F
Risk Statements 
12-14-22-34-66-67-19-11
Safety Statements 
16-26-36/37/39-43-45
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
1
F 
10
TSCA 
No
HazardClass 
8
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H313May be harmful in contact with skin

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H336May cause drowsiness or dizziness

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
256021
Product name
(Trimethylsilyl)methylmagnesium chloride solution
Purity
1.0 M in diethyl ether
Packaging
100ml
Price
$182
Updated
2024/03/01
TCI Chemical
Product number
T1451
Product name
Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L)
Packaging
100mL
Price
$108
Updated
2024/03/01
TCI Chemical
Product number
T2609
Product name
Trimethylsilylmethylmagnesium Chloride (ca. 18% in Tetrahydrofuran, ca. 1mol/L)
Packaging
100mL
Price
$119
Updated
2024/03/01
Alfa Aesar
Product number
H54635
Product name
(Trimethylsilyl)methylmagnesium chloride
Purity
0.5M in 2-MeTHF
Packaging
100ml
Price
$137.65
Updated
2024/03/01
TRC
Product number
T895985
Product name
(Trimethylsilyl)methylmagnesiumChloride,1.3MsolutioninTHF,J&KSeal
Packaging
1mL
Price
$45
Updated
2021/12/16
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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Grey liquid

Uses

Trimethylsilylmethylmagnesium Chloride is used in the methylenation of carbonyl compounds; provides a variety of methods to prepare allylsilanes.It participates in the reactions of Peterson Alkenation, Reaction with Carboxylic Acid Derivatives, Reaction with Alkyl Halides, Reaction with Sulfur Compounds, Reaction with Other Electrophiles, Cross-coupling Reactions, Carbometalation, and as a Generator of Alkyl Radicals from Alkyl Halides in the Presence of Cobalt Catalysts etc.

Uses

Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.

Preparation

From (chloromethyl)trimethylsilane and magnesium in an ethereal solvent.

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Suppliers

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View Lastest Price from TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE manufacturers

Hebei Guanlang Biotechnology Co., Ltd.
Product
trimethylsilylmethylmagnesium chloride 13170-43-9
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-11-15
Zhuozhou Wenxi import and Export Co., Ltd
Product
(Trimethylsilyl)methylmagnesium chloride solution 13170-43-9
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE 13170-43-9
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-07-04

13170-43-9, TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDERelated Search:

TRIMETHYLSILYLBENZENESULFONATE O-TOLYLMAGNESIUM BROMIDE 3,4,5-TRIMETHOXYPHENYLMAGNESIUM BROMIDE SOLUTION 0.5M IN TETRAHYDROFURAN 3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE Lithium diisopropylamide 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE 2-METHOXYBENZYLMAGNESIUM CHLORIDE 2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE 2-NAPHTHYLMAGNESIUM BROMIDE CYCLOPENTYLMAGNESIUM BROMIDE M-TOLYLMAGNESIUM CHLORIDE Zinc chloride Methylmagnesium Bromide TRIMETHYLSILANE Magnesium chloride TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Methylmagnesium chloride DIMETHYLETHYLSILYLMETHYLMAGNESIUM CHLORIDE

  • TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
  • (trimethylsilyl)methylmagnesium chl. sol
  • Trimethylsilylmethylmagnesium chloride (20% in ethyl ether
  • (TRIMETHYLSILYLMETHYL)MAGNESIUM CHLORIDE , 1.0M SOLUTION IN DIETHYL ETHER
  • (TRIMETHYLSILYL)METHYLMAGNESIUM CHL. SOL , 1 M IN DIETH.ETHER
  • [(Trimethylsilyl)methyl]magnesium Chloride 1.0 M In Diethyl Ether
  • [(Trimethylsilyl)methyl]magnesium Chloride, 1.0 M In Tetrahydrofuran
  • (Trimethylsilyl)methylmagnesium chloride, 1.1M solution in THF
  • (Trimethylsilyl)methylmagnesium chloride solution
  • Trimethylsiylmethylmagnesium chloride
  • Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L)
  • (TriMethylsilyl)MethylMagnesiuM chloride, 1.3 M solution in THF, SpcSeal
  • (trimethylsilyl) methyl magnesium chloride 1.3M tetrahydrofuran
  • (Trimethylsilyl)methylmagnesium chloride, 0.50 M in 2-MeTHF
  • (Trimethylsilyl)methylmagnesium chloride, 0.50 M in THF
  • (Trimethylsilyl)methylmagnesium chloride　1.3MTHF
  • (Trimethylsilyl)methylmagnesium chloride, 1,3m solution in THF
  • (Trimethylsilyl)methylmagnesium chloride1.3M solution in THFAcroSeal§3
  • (Trimethylsilylmethyl)chloromagnesium
  • Trimethylsilylmethylchloromagnesium
  • (Trimethylsilyl)methylmagnesium chloride solution 1.0 in diethyl ether
  • (Trimethylsilyl)methylmagnesium chloride, 1.3M solution in THF, AcroSeal
  • TriMethylsilylMethylMagnesiuM Chloride (ca. 18% in Tetrahydrofuran, ca. 1Mol/L)
  • (TriMethylsilyl)MethylMagnesiuM chloride, 1.3M solution in THF, AcroSeal 100ML
  • (TriMethylsilyl)MethylMagnesiuM chloride, 0.5M in 2-MeTHF
  • TRIMETHYLSILYLMETHYL
  • (20% in Ethyl Ether, ca. 1Mol/L)
  • TriMethylsilylMethylMagnesiuM Chloride&nbsp
  • TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 3M in Methyltetrahydrofuran
  • (TriMethylsilyl)MethylMagnesiuM chloride, 1.0M solution in diethyl ether, J&KSeal
  • (TriMethylsilyl)MethylMagnesiuM chloride solution 1.0 M in diethyl ether
  • (TriMethylsilyl)MethylMagnesiuM chloride, 1.0 M solution in diethyl ether, SpcSeal
  • (TriMethylsilyl)MethylMagnesiuM chloride, 1.3 M solution in THF, J&KSeal
  • siL
  • TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 3M in methyltetrahydrofuran (46-48 wt %)
  • TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 1.0M in diethyl ether (19 wt %)
  • (Trimethylsilyl)methylmagnesium Chloride, Tetrahydrofuran Solution (abt. 1mol/l) [TMSCH2MgCl(THF)]
  • TIANFU CHEM-- TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
  • Magnesium, chloro[(trimethylsilyl)methyl]- (7CI, 8CI, 9CI)
  • Trimethyl silyl methyl magnesium chloride 1. M in THF
  • (Trimethylsilyl)methylmagnesium
  • 13170-43-9
  • CH33SiCH2MgCl
  • C4H11ClMgSi
  • Alkyl
  • Organometallic Reagents
  • Si-(C)4 Compounds
  • Grignard Reagents & Alkyl Metals
  • Grignard Reagents
  • Classes of Metal Compounds
  • Si (Classes of Silicon Compounds)
  • Silicon Compounds (for Synthesis)
  • Typical Metal Compounds
  • Mg (Magnesium) Compounds
  • Si (Classes of Silicon Compounds)
  • Si-(C)4 Compounds
  • Silicon Compounds (for Synthesis)
  • Synthetic Organic Chemistry