1-Hexyne
- Product Name
- 1-Hexyne
- CAS No.
- 693-02-7
- Chemical Name
- 1-Hexyne
- Synonyms
- Hex-1-yne;Hexyne;Butylacetylene;1-Hexin;1-HEXYNE;5-Hexyne;1-Hexine;HEXYNE(1-);1-Hexyne98%;1-Hexyne>
- CBNumber
- CB6746670
- Molecular Formula
- C6H10
- Formula Weight
- 82.14
- MOL File
- 693-02-7.mol
1-Hexyne Property
- Melting point:
- -132 °C
- Boiling point:
- 71-72 °C(lit.)
- Density
- 0.715 g/mL at 25 °C(lit.)
- vapor pressure
- 253 mm Hg ( 37.7 °C)
- refractive index
- n20/D 1.399(lit.)
- Flash point:
- −6 °F
- storage temp.
- Store at +2°C to +8°C.
- solubility
- 0.36g/l (experimental)
- form
- Liquid
- Specific Gravity
- 0.715
- color
- Clear colorless
- Water Solubility
- Miscible with organic solvents. Immiscible with water.
- BRN
- 635687
- Stability:
- Stable. Incompatible with strong oxidizing agents. Highly flammable - readily forms explosive mixtures with air.
- CAS DataBase Reference
- 693-02-7(CAS DataBase Reference)
- NIST Chemistry Reference
- 1-Hexyne(693-02-7)
- EPA Substance Registry System
- 1-Hexyne (693-02-7)
Safety
- Hazard Codes
- F,Xn,Xi
- Risk Statements
- 11-36/37/38-65
- Safety Statements
- 16-26-36-62-9-33-7/9
- RIDADR
- UN 3295 3/PG 2
- WGK Germany
- 3
- RTECS
- MQ9691000
- F
- 10-23
- Autoignition Temperature
- 263 °C
- Hazard Note
- Irritant
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29012980
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H304May be fatal if swallowed and enters airways
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P331Do NOT induce vomiting.
N-Bromosuccinimide Price
- Product number
- 8.20643
- Product name
- 1-Hexyne
- Purity
- for synthesis
- Packaging
- 25mL
- Price
- $58.6
- Updated
- 2024/03/01
- Product number
- 8.20643
- Product name
- 1-Hexyne
- Purity
- for synthesis
- Packaging
- 100mL
- Price
- $177
- Updated
- 2024/03/01
- Product number
- 244422
- Product name
- 1-Hexyne
- Purity
- 97%
- Packaging
- 25ml
- Price
- $50.9
- Updated
- 2024/03/01
- Product number
- 244422
- Product name
- 1-Hexyne
- Purity
- 97%
- Packaging
- 100ml
- Price
- $153
- Updated
- 2024/03/01
- Product number
- H0140
- Product name
- 1-Hexyne
- Purity
- >97.0%(GC)
- Packaging
- 25mL
- Price
- $39
- Updated
- 2024/03/01
1-Hexyne Chemical Properties,Usage,Production
Chemical Properties
colourless liquid
Uses
1-Hexyne is used in the preparation of tricyclic isoindolinone scaffold by undergoing hydrozirconation and ring-closing metathesis. It is used to prepare trans-1,2-bis(5-thianthreniumyl)alkene tetrafluoroborate by reacting with thianthrene cation radical tetrafluoroborate.
Definition
ChEBI: 1-hexyne is a terminal acetylenic compound that is hexane carrying a triple bond at position 1. It is a terminal acetylenic compound, an alkyne and a volatile organic compound.
General Description
1-Hexyne reacted with thianthrene cation radical tetrafluoroborate to form trans-1,2-bis(5-thianthreniumyl)alkene tetrafluoroborate.
Hazard
Probably flammable.
Purification Methods
Distil it from NaBH4 to remove peroxides. Stand over sodium for 24hours, then fractionally distil it under reduced pressure. Also dry it by repeated vacuum transfer into freshly activated 4A molecular sieves, followed by vacuum transfer onto Na/K alloy and stirring for 1hour before fractionally distilling. [Beilstein 1 IV 1006.]
1-Hexyne Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1-Hexyne manufacturers
- Product
- 1-Hexyne 97% 693-02-7
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- 1-Hexyne 693-02-7
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%HPLC
- Supply Ability
- 10 tons/month
- Release date
- 2020-01-07