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Pentafluorobenzaldehyde

Product Name
Pentafluorobenzaldehyde
CAS No.
653-37-2
Chemical Name
Pentafluorobenzaldehyde
Synonyms
PERFLUOROBENZALDEHYDE;PENTAFLUORBENZALDEHYDE;PENTAFLUOROBENZALDEHYDE;Benzaldehyde, pentafluoro-;Pentafluorobenzaldehyde>Pentafluorobenzaldehyde 98%;Pentafluorobenzaldehyde ,97%;Pentafluorobenzaldehyde, 98+%;Pentafluorobenzaldehyde,Min.97%;2,3,4,5,6-Pentafluorobenzaldehy
CBNumber
CB6754598
Molecular Formula
C7HF5O
Formula Weight
196.07
MOL File
653-37-2.mol
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Pentafluorobenzaldehyde Property

Melting point:
24-28 °C(lit.)
Boiling point:
164-166 °C(lit.)
Density 
1.588 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.45(lit.)
Flash point:
172 °F
storage temp. 
Inert atmosphere,2-8°C
form 
Liquid After Melting
Specific Gravity
1.588
color 
Clear yellow
Water Solubility 
Sparingly Soluble in water (0.027 g/L at 25°C).
Sensitive 
Air Sensitive
BRN 
1876550
InChI
InChI=1S/C7HF5O/c8-3-2(1-13)4(9)6(11)7(12)5(3)10/h1H
InChIKey
QJXCFMJTJYCLFG-UHFFFAOYSA-N
SMILES
C(=O)C1=C(F)C(F)=C(F)C(F)=C1F
CAS DataBase Reference
653-37-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,F,Xi
Risk Statements 
20/22-36/37/38-20
Safety Statements 
26-37/39
RIDADR 
UN 2810 6.1/PG 3
WGK Germany 
3
RTECS 
CU7542000
Hazard Note 
Irritant
HazardClass 
6.1
PackingGroup 
III
HS Code 
29130000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
103748
Product name
2,3,4,5,6-Pentafluorobenzaldehyde
Purity
98%
Packaging
2.5g
Price
$59.6
Updated
2024/03/01
Sigma-Aldrich
Product number
103748
Product name
2,3,4,5,6-Pentafluorobenzaldehyde
Purity
98%
Packaging
10g
Price
$121
Updated
2024/03/01
TCI Chemical
Product number
P0746
Product name
Pentafluorobenzaldehyde
Purity
>96.0%(GC)
Packaging
5g
Price
$187
Updated
2024/03/01
TCI Chemical
Product number
P0746
Product name
Pentafluorobenzaldehyde
Purity
>96.0%(GC)
Packaging
25g
Price
$747
Updated
2024/03/01
Alfa Aesar
Product number
A15490
Product name
Pentafluorobenzaldehyde, 98%
Packaging
5g
Price
$58.5
Updated
2024/03/01
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Pentafluorobenzaldehyde Chemical Properties,Usage,Production

Chemical Properties

Freshly distilled pentafluorobenzaldehyde is a colourless liquid with a strong odour; clear yellowish liquid after melting; a lachrymator; soluble in common organic solvents and practically insoluble in water.

Uses

Pentafluorobenzaldehyde was used as derivatization reagent in a study to develop a sensitive method for the determination of primary amines in sewage sludge by headspace solid-phase micro extraction and gas chromatography-tandem mass spectrometry. It was used in the synthesis of novel, high molecular weight fluorinated aromatic polymers.

Preparation

Pentafluorobenzaldehyde is prepared by the reaction ofpentafluorophenylmagnesium bromide, iodide or chloride, or of pentafluorophenyllithium with ethyl-ortho-formiate or 3,4-dihydro-6-methyl-3-(para-tolyl)-quinazoline methiodide. Higher yields of pentafluorobenza1dehyde have been obtained by the reaction with N-methy1formanilide. Pentafluorobenzaldehyde may be prepared also by the reaction of pentafluorobenzonitrile with anhydrous SnClz in ethereal solution of HCl with subsequent hydrolsis of the intermediate (62% yield).

General Description

2,3,4,5,6-Pentafluorobenzaldehyde reacts with 5-(aryl)dipyrromethanes to form a variety of meso-aryl [26]hexaphyrins.

Precautions

Pentafluorobenzaldehyde is oxidized when exposed to light and air. It should be kept in a tightly stopped dark container. Pentafluorobenzaldehyde is about ten times as toxic as benzaldehyde, therefore it should be handled with caution.

Pentafluorobenzaldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

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Pentafluorobenzaldehyde Suppliers

Qi-Chem Co., Ltd.
Tel
0411-88165951 13601035838
Fax
0411-87406949
Email
marketing@qi-chem.com
Country
China
ProdList
148
Advantage
58
Shangfluoro
Tel
021-021-65170832 13331983812
Email
qinba_2@163.com
Country
China
ProdList
301
Advantage
58
Fluoropharm Co., Ltd.
Tel
0571-0571-85586753 13336034509
Fax
0571 85586753
Email
sales@fluoropharm.com
Country
China
ProdList
1290
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
Country
China
ProdList
7583
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35906
Advantage
56
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View Lastest Price from Pentafluorobenzaldehyde manufacturers

Henan Fengda Chemical Co., Ltd
Product
Pentafluorobenzaldehyde 653-37-2
Price
US $5.00-0.10/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-15
Shaanxi Dideu Medichem Co. Ltd
Product
Pentafluorobenzaldehyde 653-37-2
Price
US $0.00-0.00/KG
Min. Order
10mg
Purity
99%HPLC
Supply Ability
2000tons
Release date
2020-01-13
Henan Aochuang Chemical Co.,Ltd.
Product
Pentafluorobenzaldehyde 653-37-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-08

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