ChemicalBook > CAS DataBase List > Benzyl thiocyanate
Benzyl thiocyanate
- Product Name
- Benzyl thiocyanate
- CAS No.
- 3012-37-1
- Chemical Name
- Benzyl thiocyanate
- Synonyms
- Troeolin;solvat14;Solvat 14;Tropeolin;Benzylrhodonid;BENZYL RHODANIDE;Benzylthiocyanide;Beazyl thiocyanate;BENZYL THIOCYANATE;a-Thiocyanatotoluene
- CBNumber
- CB6774554
- Molecular Formula
- C8H7NS
- Formula Weight
- 149.21
- MOL File
- 3012-37-1.mol
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Benzyl thiocyanate Property
- Melting point:
- 39-41 °C (lit.) 39-41 °C
- Boiling point:
- 230-235 °C (lit.)
- Density
- 1.32
- refractive index
- 1.6000 (estimate)
- Flash point:
- >230 °F
- storage temp.
- Store at <= 20°C.
- solubility
- diethyl ether: soluble0.5g/10 mL, clear to very faintly turbid, colorless to almost colorless
- form
- Solid
- color
- Orange-red crystals or solid
- Water Solubility
- insoluble
- Sensitive
- Moisture Sensitive
- BRN
- 1859726
- CAS DataBase Reference
- 3012-37-1(CAS DataBase Reference)
- NIST Chemistry Reference
- Thiocyanic acid benzyl ester(3012-37-1)
- EPA Substance Registry System
- Thiocyanic acid, phenylmethyl ester (3012-37-1)
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Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-32
- Safety Statements
- 13-36/37-50A
- RIDADR
- UN 1759 8/PG 2
- WGK Germany
- 3
- RTECS
- XK8155000
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29309070
- Toxicity
- LDLo ipr-rat: 40 mg/kg ARZNAD 16,870,66ipr-mus LD50:17 mg/kg PCBPBS 2,95,72scu-mus LD50:100 mg/kg JJPAAZ 3,99,54
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 13929
- Product name
- Benzyl thiocyanate
- Purity
- ≥95.0% (GC)
- Packaging
- 100g
- Price
- $63.3
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T0198
- Product name
- Benzyl Thiocyanate
- Purity
- >99.0%(GC)
- Packaging
- 25g
- Price
- $22
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T0198
- Product name
- Benzyl Thiocyanate
- Purity
- >99.0%(GC)
- Packaging
- 500g
- Price
- $170
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- B23902
- Product name
- Benzyl thiocyanate, 98+%
- Packaging
- 250g
- Price
- $93.7
- Updated
- 2021/12/16
TRC
- Product number
- B315070
- Product name
- Benzyl Thiocyanate
- Packaging
- 50g
- Price
- $1320
- Updated
- 2021/12/16
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Benzyl thiocyanate Chemical Properties,Usage,Production
Description
Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.
Chemical Properties
ALMOST WHITE TO YELLOW CRYSTALS OR CRYST. POWDER
Uses
Benzyl Thiocyanate is found to increase the protein production of Streptomyces aureofaciens. Inhibits methylazoxymethanol acetate-induced intestinal carcinogenesis and reduces unscheduled DNA synthesi s for some genotoxic carcinogens in rats.
Uses
Benzyl thiocyanate was used to study the effects of various dietary compounds on the α-hydroxylation of N-nitrosopyrrolidine in male F344 rats in vitro.
Definition
ChEBI: Benzyl thiocyanate is a member of thiocyanates.
Application
Benzyl thiocyanate was used to study the effects of various dietary compounds on the α-hydroxylation of N-nitrosopyrrolidine in male F344 rats in vitro.
Synthesis Reference(s)
Synthesis, p. 184, 1977
Tetrahedron Letters, 18, p. 4417, 1977 DOI: 10.1016/S0040-4039(01)83524-3
General Description
Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.
Hazard
Strong irritant to skin, tissue. Moderate fire hazard.
Safety Profile
Poison by subcutaneous andintraperitoneal routes. Whenheated to decomposition it emits very toxic fumes ofNOx, SOx, and CN??.
Purification Methods
Crystallise the thiocyanate from EtOH or aqueous EtOH. [Beilstein 6 H 460, 6 IV 2680.]
Benzyl thiocyanate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Benzyl thiocyanate manufacturers
Career Henan Chemical Co
- Product
- Benzyl thiocyanate 3012-37-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1kg,5kg,100kg
- Release date
- 2019-07-04
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