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(1-METHYL-1H-IMIDAZOL-5-YL)METHANOL

Product Name
(1-METHYL-1H-IMIDAZOL-5-YL)METHANOL
CAS No.
38993-84-9
Chemical Name
(1-METHYL-1H-IMIDAZOL-5-YL)METHANOL
Synonyms
RARECHEM AL BD 0940;1-Methyl-5-imidazolemethanol;1-Methyl-1H-imidazol-5-methanol;(3-methylimidazol-4-yl)methanol;1-Methyl-1H-imidazole-5-methanol;1H-Imidazole-5-methanol,1-methyl-;1-METHYL-5-(HYDROXYMETHYL)IMIDAZOLE;(1-METHYL-1H-IMIDAZOL-5-YL)METHANOL;5-(HydroxyMethyl)-1-MethyliMidazole;(3-METHYL-3H-IMIDAZOL-4-YL)-METHANOL
CBNumber
CB6775364
Molecular Formula
C5H8N2O
Formula Weight
112.13
MOL File
38993-84-9.mol
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(1-METHYL-1H-IMIDAZOL-5-YL)METHANOL Property

Melting point:
113 °C
Boiling point:
324.9±17.0 °C(Predicted)
Density 
1.16±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO (Sparingly), Methanol (Slightly)
form 
Solid
pka
14.35±0.10(Predicted)
color 
Pale Yellow
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-22
Safety Statements 
26-36/37/39-37/39-36
HazardClass 
IRRITANT
HS Code 
2933299090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M321303
Product name
(1-Methyl-1H-imidazol-5-yl)methanol
Packaging
50mg
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
4H01-1-M8
Product name
5-(Hydroxymethyl)-1-methyl-1H-imidazole
Packaging
250mg
Price
$35
Updated
2021/12/16
SynQuest Laboratories
Product number
4H01-1-M8
Product name
5-(Hydroxymethyl)-1-methyl-1H-imidazole
Packaging
1g
Price
$105
Updated
2021/12/16
Matrix Scientific
Product number
057545
Product name
(1-Methyl-1H-imidazol-5-yl)methanol
Purity
95%
Packaging
1g
Price
$132
Updated
2021/12/16
Apolloscientific
Product number
OR10499
Product name
5-(Hydroxymethyl)-1-methyl-1H-imidazole
Packaging
1g
Price
$143
Updated
2021/12/16
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(1-METHYL-1H-IMIDAZOL-5-YL)METHANOL Chemical Properties,Usage,Production

Synthesis

39021-62-0

38993-84-9

General procedure for the synthesis of 1-methyl-1H-imidazol-5-yl)methanol from 1-methyl-1H-5-formyl-imidazole: 1-methyl-1H-5-formyl-imidazole (4.0 g, 15 mmol) was suspended in tetrahydrofuran (THF) (10 mL) and the resulting solution was cooled to 0 °C. Lithium aluminum hydride (300 mg, 32.0 mmol) was added in batches over 10 min and the resulting suspension was continued to be stirred for 10 min. Under vigorous stirring, the excess hydride was quenched by bulk addition of solid Na2SO4-10H2O (~1 g). Additional THF was added as needed to prevent the slurry from solidifying. The resulting suspension was continued to be stirred for 1 h. Subsequent filtration to remove the sulfate and solvent removal under reduced pressure afforded the target alcohol (1.3 g, 80% yield).1H NMR (400 MHz, CD3OD): δ 7.57 (s, 1H), 6.89 (s, 1H), 4.58 (s, 2H), 3.72 (s, 3H).13C NMR (100 MHz. CD3OD): δ140.1,132.7,128.1,31.9,31.0.

References

[1] Journal of Medicinal Chemistry, 2006, vol. 49, # 19, p. 5710 - 5727
[2] Patent: WO2006/102159, 2006, A2. Location in patent: Page/Page column 22
[3] Journal of the American Chemical Society, 1949, vol. 71, p. 2444,2447

(1-METHYL-1H-IMIDAZOL-5-YL)METHANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(1-METHYL-1H-IMIDAZOL-5-YL)METHANOL Suppliers

Belgium 1 China 89 France 1 Germany 3 India 3 Japan 1 Switzerland 1 United Kingdom 1 United States 12 Global 112
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
ABCR GmbH & CO. KG
Tel
--
Fax
--
Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75
Rare Chemicals GmbH
Tel
--
Fax
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Email
sales@rarechem.de
Country
Germany
ProdList
6297
Advantage
38
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View Lastest Price from (1-METHYL-1H-IMIDAZOL-5-YL)METHANOL manufacturers

Career Henan Chemical Co
Product
(1-METHYL-1H-IMIDAZOL-5-YL)METHANOL 38993-84-9
Price
US $9.80/KG
Min. Order
1g
Purity
≥99.0%
Supply Ability
100kg
Release date
2020-01-02

38993-84-9, (1-METHYL-1H-IMIDAZOL-5-YL)METHANOLRelated Search:

METHYL 1-METHYL-2-SULFANYL-1H-IMIDAZOLE-5-CARBOXYLATE ETHYL 2,7-DIMETHYLIMIDAZO[1,2-A]PYRIDINE-3-CARBOXYLATE 2-METHYL-IMIDAZO[1,2-A]PYRIDINE-3-CARBOXYLIC ACID ETHYL ESTER 1-(2-CYANOETHYL)-2-PHENYL-4,5-DI-CYANOETHOXYMETHYL IMIDAZOLE (2-Butyl-4-Chloro-1-((2'-(1-Trityl-1h-Tetrazole-5-Yl)Biphenyl-4-Yl)Methyl)-1h-Imidazol-5-Yl)Methanol (1-METHYL-1H-IMIDAZOL-2-YL)METHANOL (2-Butyl-4-chloro-1-((2'-(1-trityl-1H-tetrazol-5-yl)biphenyl-4-yl)methyl)-1H-imidazol-5-yl)methanol (5-METHYL-1H-IMIDAZOL-4-YL)METHANOL HYDROCHLORIDE,(4-METHYL-1H-IMIDAZOL-5-YL)METHANOL HYDROCHLORIDE (1-METHYL-1H-IMIDAZOL-4-YL)METHANOL (2-[(4-FLUOROBENZYL)SULFANYL]-1-METHYL-1H-IMIDAZOL-5-YL)METHANOL (2-([3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL]SULFANYL)-1-METHYL-1H-IMIDAZOL-5-YL)METHANOL ETHYL 6-METHYL-2-PHENYLIMIDAZO[1,2-A]PYRIDINE-3-CARBOXYLATE (2-MERCAPTO-1-METHYL-1H-IMIDAZOL-5-YL)METHANOL ETHYL 7-METHYL-2-PHENYLIMIDAZO[1,2-A]PYRIDINE-3-CARBOXYLATE ETHYL 6-CHLORO-2-PHENYLIMIDAZO[1,2-A]PYRIDINE-3-CARBOXYLATE 2,7-DIMETHYLPYRIDO[1,6-A]-1H-IMIDAZOLE-3-CARBOXYLIC ACID, ETHYL ESTER (2-[(2,6-DICHLOROBENZYL)SULFANYL]-1-METHYL-1H-IMIDAZOL-5-YL)METHANOL ETHYL 8-METHYL-2-PHENYLIMIDAZO[1,2-A]PYRIDINE-3-CARBOXYLATE

  • RARECHEM AL BD 0940
  • (3-METHYL-3H-IMIDAZOL-4-YL)-METHANOL
  • 5-HYDROXYMETHYL-1-METHYL-1H-IMIDAZOLE
  • (1-METHYL-1H-IMIDAZOL-5-YL)METHANOL
  • 1-METHYL-5-(HYDROXYMETHYL)IMIDAZOLE
  • (3-methylimidazol-4-yl)methanol
  • 1H-Imidazole-5-methanol,1-methyl-
  • 5-(HydroxyMethyl)-1-MethyliMidazole
  • 1-Methyl-1H-imidazole-5-methanol
  • 1-Methyl-5-imidazolemethanol
  • 1-Methyl-1H-imidazol-5-methanol
  • 38993-84-9
  • blocks
  • Imidazoles
  • Imidazol&Benzimidazole