(1-Methyl-1H-imidazol-2-yl)methanol

Product Name: (1-Methyl-1H-imidazol-2-yl)methanol
CAS No.: 17334-08-6
Chemical Name: (1-Methyl-1H-imidazol-2-yl)methanol
Synonyms: RARECHEM AL BD 0638;1-Methyl-1H-Imidazol-2-yl;1-Methyl-1H-iMidazol-2-ol;1-Methylimidazol-2-methanol;1-Methyl-2-imidazolemethanol;(1-Methyl-2-iMidazolyl)Methanol;(1-methylimidazol-2-yl)methanol;Imidazole-2-methanol, 1-methyl-;1-Methyl-1H-imidazole-2-methanol;1-Methyl-2-imidazolemethanol,98%
CBNumber: CB0758105
Molecular Formula: C5H8N2O
Formula Weight: 112.13
MOL File: 17334-08-6.mol

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(1-Methyl-1H-imidazol-2-yl)methanol Property

Melting point:: 116-119°C
Boiling point:: 145 °C(Press: 1 Torr)
Density: 1.16±0.1 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
form: Solid
pka: 13.41±0.10(Predicted)
color: White to Almost white
Water Solubility: Slightly soluble in water.
InChI: InChI=1S/C5H8N2O/c1-7-3-2-6-5(7)4-8/h2-3,8H,4H2,1H3
InChIKey: CDQDMLWGTVLQEE-UHFFFAOYSA-N
SMILES: C1(CO)N(C)C=CN=1
CAS DataBase Reference: 17334-08-6(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36/37/39-37/39
HazardClass: IRRITANT
HS Code: 2933299090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: H1370
Product name: 2-Hydroxymethyl-1-methylimidazole
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $62
Updated: 2025/07/31

TCI Chemical

Product number: H1370
Product name: 2-Hydroxymethyl-1-methylimidazole
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $188
Updated: 2025/07/31

TRC

Product number: M320968
Product name: (1-Methyl-1H-imidazol-2-yl)methanol
Packaging: 500mg
Price: $75
Updated: 2021/12/16

ChemScene

Product number: CS-W002716
Product name: (1-methyl-1H-imidazol-2-yl)methanol
Purity: 99.79%
Packaging: 100g
Price: $112
Updated: 2021/12/16

Apolloscientific

Product number: OR6426
Product name: 2-(Hydroxymethyl)-1-methyl-1H-imidazole
Purity: 97%
Packaging: 25g
Price: $50
Updated: 2021/12/16

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(1-Methyl-1H-imidazol-2-yl)methanol Chemical Properties,Usage,Production

Uses

1-Methyl-2-imidazolemethanol is used as intermediates.

Definition

ChEBI: (1-Methyl-1H-imidazol-2-yl)methanol is a member of imidazoles.

Synthesis

13750-81-7

17334-08-6

The general procedure for the synthesis of 1-methyl-2-hydroxymethyl-1H-imidazole is as follows: synthesis of (1-methyl-1H-imidazol-2-yl)methanol (BB6): to a solution of 1-methyl-1H-imidazole-2-carboxaldehyde (BB5) (40.5 g, 368 mmol) in methanol (300 mL) was added sodium borohydride (NaBH4) (20.89 g) in batches at 0 °C. . The reaction mixture was slowly warmed to room temperature and stirred for 5 hours. Upon completion of the reaction, the mixture was cooled to 0 °C, water (150 mL) was added and stirring was continued at 0 °C for 30 min. Subsequently, the mixture was concentrated under vacuum at room temperature. The crude product was dissolved in water (150 mL) and extracted with chloroform (4 x 200 mL). The organic layers were combined, dried over anhydrous sodium sulfate (Na2SO4) and concentrated. The residue was stirred with ether (Et2O, 150 mL) and filtered to give a white solid product (BB6) (36 g, 87% yield). Thin layer chromatography (TLC) showed an Rf value of 0.4 (15% methanol/chloroform spread).1H NMR (400 MHz, CDCl3) data: δ 6.89 (1H, apparent double peaks), 6.83 (1H, apparent double peaks), 4.66 (2H, single peak), 3.72 (3H, single peak); Mass Spectrometry (m/z): 113 (MH)+.

References

[1] Tetrahedron, 2000, vol. 56, # 4, p. 645 - 657
[2] Patent: US2012/322722, 2012, A1
[3] Bioorganic and Medicinal Chemistry, 2005, vol. 13, # 2, p. 363 - 386
[4] Tetrahedron, 1996, vol. 52, # 48, p. 15171 - 15188
[5] South African Journal of Chemistry, 2012, vol. 65, p. 231 - 238

(1-Methyl-1H-imidazol-2-yl)methanol Preparation Products And Raw materials

Raw materials

Preparation Products

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(1-Methyl-1H-imidazol-2-yl)methanol Suppliers

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View Lastest Price from (1-Methyl-1H-imidazol-2-yl)methanol manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (1-Methyl-1H-imidazol-2-yl)methanol 17334-08-6
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: (1-Methyl-1H-imidazol-2-yl)methanol 17334-08-6
Price: US $280.00/G
Min. Order: 1G
Purity: 99%
Supply Ability: customise
Release date: 2018-08-01

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RARECHEM AL BD 0638

(1-METHYL-1H-IMIDAZOL-2-YL)METHANOL

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1-Methyl-1H-Imidazol-2-yl

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(1-Methyl-2-iMidazolyl)Methanol

1-Methyl-1H-iMidazol-2-ol

(1-Methyl-1<i>H</i>-imidazol-2-yl)methanol

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1-Methyl-2-imidazolemethanol

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1-Methyl-2-imidazolemethanol,98%

1-Methylimidazol-2-methanol

17334-08-6

17224-08-6

Imidazoles & Benzimidazoles

Pyrimidines

Heterocycle intermediates

Hydroxymethyl's

Imidazoles & Benzimidazoles

Imidazol&Benzimidazole

API intermediates

Alcohols and Derivatives

Heterocycles