ChemicalBook > CAS DataBase List > (1-Methyl-1H-imidazol-2-yl)methanol

(1-Methyl-1H-imidazol-2-yl)methanol

Product Name
(1-Methyl-1H-imidazol-2-yl)methanol
CAS No.
17334-08-6
Chemical Name
(1-Methyl-1H-imidazol-2-yl)methanol
Synonyms
RARECHEM AL BD 0638;1-Methyl-1H-Imidazol-2-yl;1-Methyl-1H-iMidazol-2-ol;1-Methylimidazol-2-methanol;1-Methyl-2-imidazolemethanol;(1-Methyl-2-iMidazolyl)Methanol;(1-methylimidazol-2-yl)methanol;Imidazole-2-methanol, 1-methyl-;1-Methyl-1H-imidazole-2-methanol;1-Methyl-2-imidazolemethanol,98%
CBNumber
CB0758105
Molecular Formula
C5H8N2O
Formula Weight
112.13
MOL File
17334-08-6.mol
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(1-Methyl-1H-imidazol-2-yl)methanol Property

Melting point:
116-119°C
Boiling point:
145 °C(Press: 1 Torr)
Density 
1.16±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
Solid
pka
13.41±0.10(Predicted)
color 
White to Almost white
Water Solubility 
Slightly soluble in water.
InChI
InChI=1S/C5H8N2O/c1-7-3-2-6-5(7)4-8/h2-3,8H,4H2,1H3
InChIKey
CDQDMLWGTVLQEE-UHFFFAOYSA-N
SMILES
C1(CO)N(C)C=CN=1
CAS DataBase Reference
17334-08-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39-37/39
HazardClass 
IRRITANT
HS Code 
2933299090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
H1370
Product name
2-Hydroxymethyl-1-methylimidazole
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$62
Updated
2025/07/31
TCI Chemical
Product number
H1370
Product name
2-Hydroxymethyl-1-methylimidazole
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$188
Updated
2025/07/31
TRC
Product number
M320968
Product name
(1-Methyl-1H-imidazol-2-yl)methanol
Packaging
500mg
Price
$75
Updated
2021/12/16
Matrix Scientific
Product number
043221
Product name
(1-Methyl-1H-imidazol-2-yl)methanol
Purity
95+%
Packaging
5g
Price
$13
Updated
2021/12/16
Apolloscientific
Product number
OR6426
Product name
2-(Hydroxymethyl)-1-methyl-1H-imidazole
Purity
97%
Packaging
5g
Price
$15
Updated
2021/12/16
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(1-Methyl-1H-imidazol-2-yl)methanol Chemical Properties,Usage,Production

Uses

1-Methyl-2-imidazolemethanol is used as intermediates.

Definition

ChEBI: (1-Methyl-1H-imidazol-2-yl)methanol is a member of imidazoles.

Synthesis

13750-81-7

17334-08-6

The general procedure for the synthesis of 1-methyl-2-hydroxymethyl-1H-imidazole is as follows: synthesis of (1-methyl-1H-imidazol-2-yl)methanol (BB6): to a solution of 1-methyl-1H-imidazole-2-carboxaldehyde (BB5) (40.5 g, 368 mmol) in methanol (300 mL) was added sodium borohydride (NaBH4) (20.89 g) in batches at 0 °C. . The reaction mixture was slowly warmed to room temperature and stirred for 5 hours. Upon completion of the reaction, the mixture was cooled to 0 °C, water (150 mL) was added and stirring was continued at 0 °C for 30 min. Subsequently, the mixture was concentrated under vacuum at room temperature. The crude product was dissolved in water (150 mL) and extracted with chloroform (4 x 200 mL). The organic layers were combined, dried over anhydrous sodium sulfate (Na2SO4) and concentrated. The residue was stirred with ether (Et2O, 150 mL) and filtered to give a white solid product (BB6) (36 g, 87% yield). Thin layer chromatography (TLC) showed an Rf value of 0.4 (15% methanol/chloroform spread).1H NMR (400 MHz, CDCl3) data: δ 6.89 (1H, apparent double peaks), 6.83 (1H, apparent double peaks), 4.66 (2H, single peak), 3.72 (3H, single peak); Mass Spectrometry (m/z): 113 (MH)+.

References

[1] Tetrahedron, 2000, vol. 56, # 4, p. 645 - 657
[2] Patent: US2012/322722, 2012, A1
[3] Bioorganic and Medicinal Chemistry, 2005, vol. 13, # 2, p. 363 - 386
[4] Tetrahedron, 1996, vol. 52, # 48, p. 15171 - 15188
[5] South African Journal of Chemistry, 2012, vol. 65, p. 231 - 238

(1-Methyl-1H-imidazol-2-yl)methanol Preparation Products And Raw materials

Raw materials

Preparation Products

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(1-Methyl-1H-imidazol-2-yl)methanol Suppliers

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View Lastest Price from (1-Methyl-1H-imidazol-2-yl)methanol manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(1-Methyl-1H-imidazol-2-yl)methanol 17334-08-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Career Henan Chemical Co
Product
(1-Methyl-1H-imidazol-2-yl)methanol 17334-08-6
Price
US $280.00/G
Min. Order
1G
Purity
99%
Supply Ability
customise
Release date
2018-08-01

17334-08-6, (1-Methyl-1H-imidazol-2-yl)methanolRelated Search:

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  • Imidazoles & Benzimidazoles
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