ChemicalBook > CAS DataBase List > TERT-BUTYL 4-BROMOBENZYLCARBAMATE

TERT-BUTYL 4-BROMOBENZYLCARBAMATE

Product Name
TERT-BUTYL 4-BROMOBENZYLCARBAMATE
CAS No.
68819-84-1
Chemical Name
TERT-BUTYL 4-BROMOBENZYLCARBAMATE
Synonyms
N-BOC-4-broMobenzylaMine;4-Bromo-N-BOC-benzylamine;TERT-BUTYL 4-BROMOBENZYLCARBAMATE;tert-Butyl 4-bromobenzylcarbamate 98%;tert-Butyl N-(4-bromobenzyl)carbamate;tert-butyl N-[(4-bromophenyl)methyl]carbamate;N-(4-Bromobenzyl)carbamic acid tert-butyl ester;(4-BROMO-BENZYL)-CARBAMIC ACID TERT-BUTYL ESTER;Carbamic acid, (4-bromophenyl)methyl-, 1,1-dimethylethyl ester;N-[(4-Bromophenyl)methyl]-carbamic acid 1,1-dimethylethyl ester
CBNumber
CB6838195
Molecular Formula
C12H16BrNO2
Formula Weight
286.16
MOL File
68819-84-1.mol
More
Less

TERT-BUTYL 4-BROMOBENZYLCARBAMATE Property

Melting point:
86-88℃
Boiling point:
374.3±25.0 °C(Predicted)
Density 
1.319±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
solid
pka
12.05±0.46(Predicted)
color 
Off-white
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
22
HS Code 
2924297099
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

More
Less

N-Bromosuccinimide Price

TRC
Product number
B694555
Product name
tert-Butyl4-Bromobenzylcarbamate
Packaging
100mg
Price
$60
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB155794
Product name
tert-Butyl 4-bromobenzylcarbamate
Packaging
1g
Price
$80
Updated
2021/12/16
ChemScene
Product number
CS-W005364
Product name
tert-Butyl4-bromobenzylcarbamate
Purity
99.98%
Packaging
10g
Price
$110
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB155794
Product name
tert-Butyl 4-bromobenzylcarbamate
Packaging
2g
Price
$130
Updated
2021/12/16
Apolloscientific
Product number
OR315540
Product name
tert-Butyl4-bromobenzylcarbamate
Purity
98%
Packaging
5g
Price
$166
Updated
2021/12/16
More
Less

TERT-BUTYL 4-BROMOBENZYLCARBAMATE Chemical Properties,Usage,Production

Synthesis

Tert-Butyl 4-bromobenzylcarbamate is prepared by the reaction of di-tert-butyl dicarbonate and 4-bromobenzylamine hydrochloride. The specific synthesis steps are as follows:
To a stirred suspension of 4-bromo-benzylamine hydrochloride (968mg, 4.35mmol) and triethylamine (0.666ml, 4.79mmol) in chloroform (15ml) was added di-tert-butyldicarbonate (949mg, 4.35mmol). The resulting solution was stirred at ambient temperature for 2h and then diluted with DCM (40ml). The organic solution was washed sequentially with 10% aqueous citric acid (40ml) and brine (40ml). The organic phase was dried over anhydrous magnesium sulfate and the filtrate evaporated at reduced pressure to afford Tert-Butyl 4-bromobenzylcarbamate (1.23g, 99%). 1H NMR 7.48-7.43 (2H, m), 7.18 (2H, d, 8.4), 4.84 (1H, br s), 4.27 (2H, d, 5.7), 1.46 (9H, s).

TERT-BUTYL 4-BROMOBENZYLCARBAMATE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

TERT-BUTYL 4-BROMOBENZYLCARBAMATE Suppliers

China 104 India 1 United Kingdom 2 United States 10 Global 117
Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
Apollo Scientific Ltd.
Tel
--
Fax
--
Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
Advantage
88
More
Less

View Lastest Price from TERT-BUTYL 4-BROMOBENZYLCARBAMATE manufacturers

Career Henan Chemical Co
Product
TERT-BUTYL 4-BROMOBENZYLCARBAMATE 68819-84-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-02

68819-84-1, TERT-BUTYL 4-BROMOBENZYLCARBAMATERelated Search:

N-Boc-4-(Cyclopropylmethyl)piperazine 1-BOC-4-(1-PYRROLIDINYL)-3,6-DIHYDRO-2H-PYRIDINE 2(1H)-ISOQUINOLINECARBOXYLIC ACID, 3,4-DIHYDRO-7-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-, 1,1-DIMETHYLETHYL ESTER tert-butyl 4-(2-bromo-5-fluoropyridin-4-yl)-4-hydroxypiperidine-1-carboxylate 1-N-Boc-4-(Phenylamino)piperidine tert-butyl 4-(2-aminoethyl)-3,3-difluoropiperidine-1-carboxylate 4-(3-AMINO-PHENYL)-PIPERIDINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER 1-Boc-4-(2-hydroxyethyl)piperidine tert-butyl 4-(3-cyano-4-(methoxycarbonyl)phenyl)piperazine-1-carboxylate tert-butyl 5-tert-butylisoxazol-3-ylcarbamate 1-Piperazinecarboxylic acid, 4-[3-bromo-4-(methoxycarbonyl)phenyl]-, 1,1-dimethylethyl ester 5H-Pyrrolo[3,2-c]pyridine-5-carboxylic acid, 1,4,6,7-tetrahydro-4-oxo-2-(4-pyridinyl)-, 1,1-dimethylethyl ester INDEX NAME NOT YET ASSIGNED Pentanoic acid, 4,5-diamino-5-oxo-, 1,1-dimethylethyl ester Boc-4-Bromo-L-beta-phenylalanine Boc-4-Bromo-D-beta-phenylalanine (4-Bromophenyl)-tert-butoxycarbonylaminoacetic acid methyl ester (R,S)-Boc-3-amino-3-(4-bromophenyl)-propionic acid

  • TERT-BUTYL 4-BROMOBENZYLCARBAMATE
  • tert-Butyl 4-bromobenzylcarbamate 98%
  • Carbamic acid, (4-bromophenyl)methyl-, 1,1-dimethylethyl ester
  • (4-BROMO-BENZYL)-CARBAMIC ACID TERT-BUTYL ESTER
  • N-BOC-4-broMobenzylaMine
  • 4-Bromo-N-BOC-benzylamine
  • N-(4-Bromobenzyl)carbamic acid tert-butyl ester
  • tert-Butyl N-(4-bromobenzyl)carbamate
  • Carbamic acid, N-[(4-bromophenyl)methyl]-, 1,1-dimethylethyl ester
  • tert-butyl N-[(4-bromophenyl)methyl]carbamate
  • N-[(4-Bromophenyl)methyl]-carbamic acid 1,1-dimethylethyl ester
  • 68819-84-1
  • amine|alkyl bromide| carboxylic ester