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sec-Butylamine

Product Name
sec-Butylamine
CAS No.
13952-84-6
Chemical Name
sec-Butylamine
Synonyms
SBA;2-AB;2-AMINOBUTANE;2-BUTANAMINE;2-BUTYLAMINE;Tutane;Frucote;Butafume;Deccotane;sec-C4H9NH2
CBNumber
CB6853095
Molecular Formula
C4H11N
Formula Weight
73.14
MOL File
13952-84-6.mol
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sec-Butylamine Property

Melting point:
-104 °C
Boiling point:
63 °C(lit.)
Density 
0.724 g/mL at 25 °C(lit.)
vapor pressure 
22.13kPa at 20℃
FEMA 
4240 | SEC-BUTYLAMINE
refractive index 
n20/D 1.3928(lit.)
Flash point:
−3 °F
storage temp. 
Flammables area
solubility 
112g/l
form 
Liquid
pka
10.56(at 25℃)
color 
Clear colorless to light yellow
Specific Gravity
0.723 (20/4℃)
Odor
Ammonia-like.
Odor Threshold
0.17ppm
Odor Type
fishy
explosive limit
1.8-9.0%(V)
Water Solubility 
MISCIBLE
Sensitive 
Air Sensitive
Merck 
14,1544
JECFA Number
1584
BRN 
1361345
Stability:
Stable, but light sensitive. Incompatible with strong oxidizing agents, strong acids. Highly flammable.
LogP
0.7-0.74
CAS DataBase Reference
13952-84-6(CAS DataBase Reference)
NIST Chemistry Reference
2-Butanamine(13952-84-6)
EPA Substance Registry System
sec-Butylamine (13952-84-6)
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Safety

Hazard Codes 
F,C,N
Risk Statements 
11-20/22-35-50
Safety Statements 
9-16-26-28-36/37/39-45-61-28A
RIDADR 
UN 2733 3/PG 2
OEL
STEL: 5.0 ppm; 15.0 mg/m3
WGK Germany 
2
RTECS 
EO3325000
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29211980
Hazardous Substances Data
13952-84-6(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

H400Very toxic to aquatic life

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B89000
Product name
sec-Butylamine
Purity
99%
Packaging
100ml
Price
$48.4
Updated
2024/03/01
TCI Chemical
Product number
B0708
Product name
sec-Butylamine
Packaging
25ML
Price
$16
Updated
2024/03/01
TCI Chemical
Product number
B0708
Product name
sec-Butylamine
Packaging
500ML
Price
$52
Updated
2024/03/01
Alfa Aesar
Product number
A13014
Product name
(±)-2-Aminobutane, 98%
Packaging
500ml
Price
$31.3
Updated
2021/12/16
Alfa Aesar
Product number
A13014
Product name
(±)-2-Aminobutane, 98%
Packaging
2500ml
Price
$118
Updated
2021/12/16
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sec-Butylamine Chemical Properties,Usage,Production

Description

Sec-butylamine is an amine of butane. It can be used as a fungicide. It can be used as a fumigant for control of gangrene, skin spot and silver scurf diseases of potato tubers, citrus fruit decay. However, it is highly toxic to aquatic organisms.

Chemical Properties

Butyl amines are highly flammable, colorless liquids (n-turns yellow on standing) with ammoniacal or fishlike odors. n-isomer:

Chemical Properties

Colorless to yellow liquid; fishy ammonia aroma.

Chemical Properties

colourless liquid with an amine odour

Uses

Fungicide.

Uses

(+/-)-2-Aminobutane is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.

Production Methods

2-Butylamine is manufactured by the condensation of methyl ethyl ketone with ammonia–hydrogen in the presence of Ni catalyst. It has been used as a fungistat.

Definition

ChEBI: A primary aliphatic amine that is butane in which one hydrogen at position 2 is replaced by an amino group. A fumigant fungicide with a high potential for bioaccumulation, it is not approved for fungicidal use in the European Union.

Aroma threshold values

High strength odor; fishy type; recommend smelling in a 0.10% solution or less.

Hazard

Flammable, dangerous fire risk.

Health Hazard

Recommended Personal Protective Equipment: Chemical safety goggles; rubber gloves and apron; respiratory protective equipment; non-sparking shoes; Symptoms Following Exposure: Inhalation causes irritation of burns of the respiratory system; exposure to concentrated vapors can cause asphyxiation. Ingestion causes burns of mouth and stomach. Contact with eyes causes lachrymation, conjunctivitis, burns, corneal edema. Contact with skin causes irritation or burns, dermatitis; General Treatment for Exposure: INHALATION: remove patient from exposure; keep him quiet; contact physician. INGESTION: give large amount of water; induce vomiting; consult a physician. EYES: flush thoroughly with water for 15 min.; call physician immediately. SKIN: remove all contaminated clothing; flood affected area with large quantities of water; consult a physician; Toxicity by Inhalation (Threshold Limit Value): Data not available; Short-Term Exposure Limits: Data not available; Toxicity by Ingestion: Grade 3; oral LD50 = 380 mg/kg (rat); Late Toxicity: Data not available; Vapor (Gas) Irritant Characteristics: Vapors are moderately irritating such that personnel will not usually tolerate moderate or high concentrations; Liquid or Solid Irritant Characteristics: Severe skin irritant. Causes second- and third-degree burns on short contact and is very injurious to the eyes; Odor Threshold: Data not available.

Chemical Reactivity

Reactivity with Water: No reaction; Reactivity with Common Materials: May corrode some metals in presence of water; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Flush with water; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

A poison by ingestion. A powerful irritant. Moderately toxic by skin contact. Dangerous fire hazard when exposed to heat or flame. To fight fire, use alcohol foam, water spray or mist, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits toxic fumes of NOx. A fungicide.

Potential Exposure

Alert: (n-isomer): Possible risk of forming tumors, suspected of causing genetic defects, suspected reprotoxic hazard, Primary irritant (w/o allergic reaction), (sec-isomer): Drug. n-Butylamine is used in pharmaceuticals; dyestuffs, rubber, chemicals, emulsifying agents; photography, desizing agents for textiles; pesticides, and synthetic agents. sec-Butylamine is used as a fungistate. tert-Butylamine is used as a chemical intermediate in the production of tert-Butylaminoethyl methacrylate (a lube oil additive); as an intermediate in the production of rubber and in rust preventatives and emulsion deterrents in petroleum products. It is used in the manufacture of several drugs

Shipping

UN1125 n-Butylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material. UN2014 Isobutylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material

Incompatibilities

May form explosive mixture with air. May accumulate static electrical charges, and may causeignition of its vapors. n-Butylamine is a weak base; reacts with strong oxidizers and acids, causing fire and explosion hazard. Incompatible with organic anhydrides; isocyanates, vinyl acetate; acrylates, substituted allyls; alkylene oxides; epichlorohydrin, ketones, aldehydes, alcohols, glycols, phenols, cresols, caprolactum solution. Attacks some metals in presence of moisture. The tert-isomer will attack some forms of plastics

Waste Disposal

Use a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner andscrubber. All federal, state, and local environmental regulations must be observed.

References

Smilanick, J. L., and J. W. Eckert. "Growth, sporulation, and virulence of isolates of Penicillium digitatum resistant to the fungicide sec-butylamine. " Phytopathology 76.8(1986).
Graham, D. C., et al. "Use of 2-aminobutane as a fumigant for control of gangrene, skin spot and silver scurf diseases of potato tubers." Potato Research 16.2(1973):109-125.
Gutter, Y. "Combined treatment with thiabendazole and 2-aminobutane for control of citrus fruit decay." Crop Protection 4.3(1985):346-350.

sec-Butylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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sec-Butylamine Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9815
Advantage
79
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
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View Lastest Price from sec-Butylamine manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
sec-Butylamine 13952-84-6
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-04-26
Hebei Zhanyao Biotechnology Co. Ltd
Product
sec-Butylamine 13952-84-6
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2021-10-15
Qiuxian Baitai New Material Co., LTD
Product
sec-Butylamine 13952-84-6
Price
US $80.00/KG
Min. Order
100KG
Purity
99.9%
Supply Ability
100tons
Release date
2021-11-10

13952-84-6, sec-ButylamineRelated Search:


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