Iodoform

Product Name: Iodoform
CAS No.: 75-47-8
Chemical Name: Iodoform
Synonyms: CHI3;TRIIODOMETHANE;CHIT1;CHIT;ioforme;Iodofrm;odoform;FLJ00314;IODOFORM;Jodoform
CBNumber: CB6854229
Molecular Formula: CHI3
Formula Weight: 393.73
MOL File: 75-47-8.mol

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Iodoform Property

Melting point:: 119 °C
Boiling point:: 218°C
Density: 4.008 g/mL at 25 °C(lit.)
refractive index: 1.4975 (estimate)
storage temp.: -20°C
solubility: chloroform: soluble5%
form: Crystalline Powder
color: Bright yellow to dark yellow
Odor: char. pungent odor
Water Solubility: Insoluble. <0.1 g/100 mL at 24 ºC
Sensitive: Light Sensitive
Merck: 14,5033
BRN: 1697010
Exposure limits: ACGIH: TWA 0.6 ppm
NIOSH: TWA 0.6 ppm(10 mg/m3)
Stability:: Stable. Incompatible with strong oxidizing agents, reducing agents. May explode when heated.
LogP: 3.510 (est)
CAS DataBase Reference: 75-47-8(CAS DataBase Reference)
NIST Chemistry Reference: Methane, triiodo-(75-47-8)
EPA Substance Registry System: Iodoform (75-47-8)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-36/37-36/37/39-22-24/25
RIDADR: UN 1851
OEB: B
OEL: TWA: 0.6 ppm (10 mg/m3)
WGK Germany: 3
RTECS: PB7000000
F: 13
TSCA: Yes
HS Code: 29033990
Hazardous Substances Data: 75-47-8(Hazardous Substances Data)
Toxicity: LD50 s.c. in mice: 1.6 mmoles/kg (Kutob, Plaa)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

H335May cause respiratory irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 109452
Product name: Iodoform
Purity: 99%
Packaging: 5g
Price: $42.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: SAB2501721
Product name: Anti-CHIT1 antibody produced in goat
Purity: affinity isolated antibody, buffered aqueous solution
Packaging: 100μg
Price: $568
Updated: 2024/03/01

Sigma-Aldrich

Product number: SAB1402723
Product name: Monoclonal Anti-CHIT1 antibody produced in mouse
Purity: clone 1D11, purified immunoglobulin, buffered aqueous solution
Packaging: 100μg
Price: $524
Updated: 2024/03/01

Sigma-Aldrich

Product number: 109452
Product name: Iodoform
Purity: 99%
Packaging: 100g
Price: $84.9
Updated: 2024/03/01

Alfa Aesar

Product number: A13664
Product name: Iodoform, 99%
Packaging: 50g
Price: $41.9
Updated: 2024/03/01

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Iodoform Chemical Properties,Usage,Production

Description

Iodoform is a stable, pale yellow crystalline solid. It is volatile with a characteristic pungent, unpleasant and penetrating odour, but with a sweetish taste. It is incompatible with strong oxidising agents, reducing agents, lithium, and metallic salts such as mercuric oxide, silver nitrate, strong bases, calomel, and tannin. Reports indicate that earlier iodoform was in use as a disinfectant and as an antiseptic or dressing and healing of wounds and sores for pets. Iodoform is the active ingredient in many antiseptic or dressing powders used for dogs and cats to prevent infection.

Chemical Properties

yellow solid with a characteristic pungent and

Chemical Properties

Iodoform is a yellow or greenish-yellow powder or crystalline solid that is volatile with steam and contains 96.69% iodine. It has a very characteristic pungent odor. An odor threshold of 0.005 ppm has been reported.

Uses

Iodoform has limited use as a chemical intermediate and for medicinal purposes as disinfectant and antiseptic and has been used in veterinary medicine.

Uses

Triiodomethane is a crystalline compound commonly used as a disinfectant. It can be used in the process of removing heavy metals such as mercury from fuids.

Uses

It is used as a topical anti-infective, applied to the skin.

Definition

A yellow crystalline compound made by warming ethanal with an alkaline solution of an iodide:
CH₃CHO + 3I^– + 4OH^– → CHI₃ +
HCOO^– + 3H₂O
The reaction also occurs with all ketones of general formula CH₃COR (R is an alkyl group) and with secondary alcohols CH₃CH(OH)R. Iodoform is used as a test for such reactions (the iodoform reaction).

General Description

Bright yellow or yellow powder or crystals. Penetrating odor. Unctuous touch. Odor threshold 0.4 ppb.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Iodoform decomposes at high temperatures. Decomposes slowly in light at room temperature. Reacts violently with lithium. Is incompatible with mercuric oxide, calomel, silver nitrate, tannin, and balsam Peru. Is also incompatible with strong bases, strong oxidizing agents and magnesium. Vigorous reactions occur with acetone in the presence of solid potassium hydroxide or calcium hydroxide, hexamethylenetetramine at 352° F, mercury(I) fluoride and finely divided reduced silver.

Hazard

Irritant. Decomposes violently at 400F (204C).

Health Hazard

Iodoform causes central nervous system depression and damage to the kidneys, liver, and heart.

Fire Hazard

Literature sources indicate that Iodoform is nonflammable.

Biochem/physiol Actions

Iodoform is an iodine containing compound, which is used in antiseptic applications in the medical and veterinary medicine fields. Iodoform improves fermentation in the biomass ensilage conversion system by improving lactic acid production and inhibiting butyric fermentation.

Carcinogenicity

Iodoform has been included in the NCI daily bioassay program. According to their summary: the high and low time-weighted average daily dosages of iodoform were, respectively, 142 and 71 mg/kg for male rats, 55 and 27 mg/kg for female rats, and 93 and 47 mg/kg for male and female mice. A significant positive association between dosage and mortality was observed in male rats but not in female rats or in mice of either sex. Adequate numbers of animals in all groups survived sufficiently long to be at risk from late-developing tumors. No statistical significance could be attributed to the incidences of any neoplasms in rats or mice of either sex when compared to their respective controls. Under the conditions of this bioassay, no convincing evidence was provided for the carcinogenicity of iodoform in Osborne–Mendel rats or B6C3F1 mice.

Purification Methods

Crystallise it from MeOH, EtOH or EtOH/EtOAc. It is steam volatile. It is a disinfectant. [Beilstein 1 IV 97.]

Iodoform Preparation Products And Raw materials

Raw materials

Sodium hypochlorite Acetone Sodium hydroxide Iodomethane

Preparation Products

Diiodomethane

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Iodoform Suppliers

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View Lastest Price from Iodoform manufacturers

Hebei Chuanghai Biotechnology Co,.LTD

Product: Iodoform 75-47-8
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-23

R&D Scientific Inc.

Product: Iodoform 75-47-8
Price: US $490.00/Kg
Min. Order: 0.100Kg
Purity: 98
Supply Ability: 1000 Kg
Release date: 2024-10-04

Weijer International Trade (Hebei) Co., Ltd

Product: Iodoform 75-47-8
Price: US $1.00/kg
Min. Order: 1kg
Purity: >99%
Supply Ability: 2000T
Release date: 2023-03-16

75-47-8, IodoformRelated Search:

Iodomethane Iodotrimethylsilane CARBON TETRAIODIDE TRIIODOACETIC ACID Isobutyronitrile IODOFORM-D 99 ATOM % D,IODOFORM-D Methyl iodoform PROTEOGEL IPG STRIP 7 CM PH 6-11 PROTEOGEL IPG STRIP 18 CM PH 3-5 PROTEOGEL IPG STRIP 18 CM PH 8-11 PROTEOGEL IPG STRIP 11 CM PH 3-10 PROTEOGEL IPG STRIP 11 CM PH 3-5 PROTEOGEL IPG STRIP 18 CM PH 6-11 PROTEOGEL IPG STRIP 7 CM PH 3-5 Iodoform PROTEOGEL IPG STRIP 11 CM PH 8-11 PROTEOGEL IPG STRIP 18 CM PH 4-7 PROTEOGEL IPG STRIP 18 CM PH 5-8

triiodo-methan

triiodomethane(iodoform)

Trijodmethan

Trijodmethane

IODOFORM

chitinase 1 (chitotriosidase)

CHIT

CHIT1

FLJ00314

MGC125322

TRIIODOMETHANE

IodoforM NF

IodoforM SynonyM: TriiodoMethane

IodoforM 99%

Methane,triiodo-

NCI-C04568

carbontriiodide

CHI3

dezinfektv

formenetriiode

iodoforme

ioforme

Jodoform

Three Methyl iodide

IodoformB.P.C.

Iodoform(Triiodomethane)

IodoformExtraPure

IodoformPure

Iodoform, 98+%

Iodofrm

Iodoform,99%

Iodoform (non-medicinal)

IODOFORM,REAGENT

IODOFORM,USP

odoform

Recombinant Human CHIT1 Protein, His Tag

Iodoform USP/EP/BP

Iodoform, Pure, SLR, Fisher Chemical

Anti-CHIT1 antibody produced in goat

Monoclonal Anti-CHIT1 antibody produced in mouse

Iodoform 99% Extrapure

Iodoform in methanol

IODOFORM (STABILISED)

75-47-8

74-47-8

75478

Halogenated Hydrocarbons

Organic Building Blocks

Building Blocks

Alkyl

Organics

Pharmaceutical Intermediates

Indolines ,Indoles ,Indazoles

75-47-8