6-Chloro-2-mercaptobenzothiazole
- Product Name
- 6-Chloro-2-mercaptobenzothiazole
- CAS No.
- 51618-29-2
- Chemical Name
- 6-Chloro-2-mercaptobenzothiazole
- Synonyms
- 6-chlorobenzothiazole-2-thiol;6- Chloro-2-Mercaptobenzothiazol;6-Chlorobenzo[d]thiazole-2-thiol;6-Chloro-2-mercaptobenzothiazole;2-Mercapto-6-chlorobenzothiazole;6-Chlorobenzothiazole-2(3H)-thione;2(3H)-Benzothiazolethione, 6-chloro-;6-chloro-3H-1,3-benzothiazole-2-thione;6-Chloro-1,3-benzothiazole-2(3H)-thione;2(3H)-Benzothiazolethione,6-chloro-(9CI)
- CBNumber
- CB6930284
- Molecular Formula
- C7H4ClNS2
- Formula Weight
- 201.7
- MOL File
- 51618-29-2.mol
6-Chloro-2-mercaptobenzothiazole Property
- Melting point:
- 244-245 °C
- Boiling point:
- 341.8±44.0 °C(Predicted)
- Density
- 1.60±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C
- pka
- 9.07±0.20(Predicted)
- Appearance
- White to off-white Solid
Safety
- HS Code
- 2934208090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- C385458
- Product name
- 6-Chloro-1,3-benzothiazole-2(3H)-thione
- Packaging
- 2.5g
- Price
- $265
- Updated
- 2021/12/16
- Product number
- FC147535
- Product name
- 6-Chloro-2-mercaptobenzothiazole
- Packaging
- 2g
- Price
- $354
- Updated
- 2021/12/16
- Product number
- OR8320
- Product name
- 6-Chloro-1,3-benzothiazole-2(3H)-thione
- Packaging
- 500mg
- Price
- $109
- Updated
- 2021/12/16
- Product number
- FC147535
- Product name
- 6-Chloro-2-mercaptobenzothiazole
- Packaging
- 500mg
- Price
- $115
- Updated
- 2021/12/16
- Product number
- 7H67-5-X1
- Product name
- 6-Chloro-1,3-benzothiazole-2(3H)-thione
- Packaging
- 500mg
- Price
- $120
- Updated
- 2021/12/16
6-Chloro-2-mercaptobenzothiazole Chemical Properties,Usage,Production
Chemical Properties
Yellow solid
Synthesis
75-15-0
31183-89-8
51618-29-2
127 mg (0.40 mmol) of 4,4'-dichloro-2,2'-dithiodianiline and 11.2 mg (0.2 mmol) of NaHS were added to the reaction flask, followed by the addition of 2.5 mL of H2O as reaction solvent. Subsequently, 97 μL (1.6 mmol) of carbon disulfide was injected and the reaction mixture was stirred at 80 °C for 4 hours. The progress of the reaction was monitored by thin-layer chromatography (TLC) and after confirming the complete reaction of the disulfide feedstock, the reaction mixture was cooled to room temperature. The reaction mixture was extracted with ethyl acetate, the organic phases were combined and the solvent was removed under reduced pressure by rotary evaporator to give the crude product. The crude product was purified by column chromatography (200-300 mesh silica gel) using a gradient elution with dichloromethane as eluent. Finally, 122 mg of 6-chloro-2-mercaptobenzothiazole was obtained as a white powder with purity greater than 99%, isolated yield of 75.6%, and melting point of 239-241°C. The product was purified by column chromatography (200-300 mesh silica gel) using dichloromethane as eluent.
References
[1] Patent: CN105949147, 2016, A. Location in patent: Paragraph 0059; 0060
6-Chloro-2-mercaptobenzothiazole Preparation Products And Raw materials
Raw materials
Preparation Products
6-Chloro-2-mercaptobenzothiazole Suppliers
- Tel
- --
- Fax
- --
- sales@ajchem.in
- Country
- India
- ProdList
- 6100
- Advantage
- 58
View Lastest Price from 6-Chloro-2-mercaptobenzothiazole manufacturers
- Product
- 6-Chloro-2-Mercaptobenzothiazole 51618-29-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.5%
- Supply Ability
- 100 tons
- Release date
- 2022-01-14
- Product
- 6-Chloro-2-mercaptobenzothiazole 51618-29-2
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-08