Synthesis
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3-Fluorobenzonitrile

Synthesis
Product Name
3-Fluorobenzonitrile
CAS No.
403-54-3
Chemical Name
3-Fluorobenzonitrile
Synonyms
M-FLUOROBENZONITRILE;M-fluoronitrile;3-fluoronitrile;M-FLUOROBENZONITILE;3-fluoro-benzonitril;m-Cyanofluorobenzene;3-FLUOROBENZONITRILE;3-cyanofluorobenzene;Letrozole Impurity 19;Benzonitrile, m-fluoro-
CBNumber
CB7100462
Molecular Formula
C7H4FN
Formula Weight
121.11
MOL File
403-54-3.mol
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3-Fluorobenzonitrile Property

Melting point:
−16 °C(lit.)
Boiling point:
182-183 °C753 mm Hg(lit.)
Density 
1.133 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.5043(lit.)
Flash point:
154 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
Specific Gravity
1.133
color 
Clear colorless to yellow
BRN 
1858941
CAS DataBase Reference
403-54-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzonitrile, 3-fluoro-(403-54-3)
EPA Substance Registry System
Benzonitrile, 3-fluoro- (403-54-3)
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Safety

Hazard Codes 
Xn,T,Xi
Risk Statements 
22-37/38-41-36/37/38-20/21/22
Safety Statements 
26-39-36/37/39-36
RIDADR 
UN 3276 6.1/PG 3
WGK Germany 
3
Hazard Note 
Toxic
TSCA 
T
HazardClass 
6.1
PackingGroup 
III
HS Code 
29269090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
235822
Product name
3-Fluorobenzonitrile
Purity
98%
Packaging
10g
Price
$94.8
Updated
2023/01/07
TCI Chemical
Product number
F0219
Product name
3-Fluorobenzonitrile
Purity
>98.0%(GC)
Packaging
5g
Price
$45
Updated
2024/03/01
TCI Chemical
Product number
F0219
Product name
3-Fluorobenzonitrile
Purity
>98.0%(GC)
Packaging
25g
Price
$141
Updated
2024/03/01
Alfa Aesar
Product number
B23426
Product name
3-Fluorobenzonitrile, 98%
Packaging
5g
Price
$44.65
Updated
2024/03/01
Alfa Aesar
Product number
B23426
Product name
3-Fluorobenzonitrile, 98%
Packaging
25g
Price
$138.65
Updated
2024/03/01
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3-Fluorobenzonitrile Chemical Properties,Usage,Production

Synthesis

Many of the advances made in the Halex reaction have been applied to fluorodenitration reactions, for example, 3-nitrobenzonitrile reacts with KF and catalytic amounts of Ph4PBr to give 3-fluorobenzonitrile.

Chemical Properties

clear colorless to yellow liquid

Uses

3-Fluorobenzonitrile has been used in the preparation of bis(3-cyanophenoxy)phenylenes.

General Description

Microwave spectrum of 3-fluorobenzonitrile has been studied. Amination of 3-fluorobenzonitrile with morpholine in DMSO at 100°C has been investigated.

3-Fluorobenzonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

1-(3-CYANOBENZYL)PIPERAZINE 1-(3-CYANOPHENYL)PIPERAZINE
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3-Fluorobenzonitrile Suppliers

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View Lastest Price from 3-Fluorobenzonitrile manufacturers

Henan Fengda Chemical Co., Ltd
Product
3-Fluorobenzonitrile 403-54-3
Price
US $9.00-0.90/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-23
Zhuozhou Wenxi import and Export Co., Ltd
Product
3-Fluorobenzonitrile 403-54-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
3-Fluorobenzonitrile 403-54-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09

403-54-3, 3-FluorobenzonitrileRelated Search:

4-Fluorobenzaldehyde 1,3-Difluorobenzene Transfluthrin Florfenicol 3'-Fluoroacetophenone Tetrafluoroterephthalonitrile 3-Nitrobenzonitrile 3-Bromobenzonitrile 4-Fluorobenzonitrile Pentafluorobenzonitrile 2-methyl-5-fluorobenzonitrile 2,3,5,6-Tetrafluorobenzonitrile 3,5-Difluorobenzonitrile 3-Chloro-4-fluorobenzonitrile, 98+% 2-Fluoro-6-Chlorobenzonitrile 3,4-Difluorobenzonitrile FENFLURAMINE 2,6-Difluorobenzonitrile

  • 1-Cyano-3-fluorobenzene
  • 1-Fluoro-3-cyanobenzene
  • 3-Fluorobenzonitrile, 98% 10GR
  • 3-Fluorobenzonitrile, 97+%
  • M-FLUOROBENZONITRILE
  • Inter-fluorobenzonitrile
  • Benzonitrile, 3-fluoro-
  • Between fluorine benzene nitriles
  • 3-fluoro-benzonitril
  • Benzonitrile, m-fluoro-
  • m-Cyanofluorobenzene
  • 3-FLUOROBENZONITRILE
  • m-Fluorobenzonitrile 3-Fluorobenzonitrile
  • 3-Fluorobenzonitrile,98%
  • 3-cyanofluorobenzene
  • M-FLUOROBENZONITILE
  • Letrozole Impurity 19
  • 3-Fluorobenzonitrile&gt
  • M-fluoronitrile
  • 3-fluoronitrile
  • 403-54-3
  • 403-54-7
  • C7H4FClO2
  • C7H4FN
  • C7H4NF
  • Building Blocks
  • C6 to C7
  • Organic Building Blocks
  • Nitrogen Compounds
  • Cyanides/Nitriles
  • Aromatic Nitriles
  • FINE Chemical & INTERMEDIATES
  • Boron, Nitrile, Thio,& TM-Cpds
  • cyanide| alkyl Fluorine
  • Fluorobenzene
  • Nitrile
  • Fluorine Compounds
  • Nitriles
  • C6 to C7
  • Cyanides/Nitriles
  • Nitrogen Compounds