ChemicalBook > CAS DataBase List > P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID

P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID

Product Name
P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID
CAS No.
156837-90-0
Chemical Name
P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID
Synonyms
P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID;[4-(4-Propylcyclohexyl)phenyl]boric acid;4-trans-Propylcyclohexylphenylboronic acid;Boronic acid,B-[4-(4-propylcyclohexyl)phenyl]-;trans-[4-(4-propylcyclohexyl)phenyl]boronic acid
CBNumber
CB71013189
Molecular Formula
C15H23BO2
Formula Weight
246.15
MOL File
156837-90-0.mol
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P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID Property

Boiling point:
394.9±35.0 °C(Predicted)
Density 
1.03±0.1 g/cm3 (20 ºC 760 Torr)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
8.70±0.17(Predicted)
Appearance
White to off-white Solid
InChI
InChI=1S/C15H23BO2/c1-2-3-12-4-6-13(7-5-12)14-8-10-15(11-9-14)16(17)18/h8-13,17-18H,2-7H2,1H3
InChIKey
QTBUVZSHCNAPRT-UHFFFAOYSA-N
SMILES
B(C1=CC=C(C2CCC(CCC)CC2)C=C1)(O)O
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
P835173
Product name
(4-(4-Propylcyclohexyl)phenyl)boronicAcid
Packaging
250mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
9353AF
Product name
p-(4-propylcyclohexyl)thenylboronicacid
Packaging
25g
Price
$217
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
BOR0000332
Product name
4-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID
Purity
95.00%
Packaging
5G
Price
$909.56
Updated
2021/12/16
Crysdot
Product number
CD41001916
Product name
(4-(4-Propylcyclohexyl)phenyl)boronicacid
Purity
97%
Packaging
100g
Price
$446
Updated
2021/12/16
Alichem
Product number
156837900
Product name
(4-(4-Propylcyclohexyl)phenyl)boronicacid
Packaging
100g
Price
$463.5
Updated
2021/12/16
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P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID Chemical Properties,Usage,Production

Chemical Properties

White powder

Synthesis

860639-66-3

156837-90-0

Under nitrogen protection, 4-(4-propylcyclohexyl)iodobenzene (50.0 g) was added to a reaction vial with anhydrous ether (800 mL) and cooled to -70 °C. Slowly n-butyllithium (1.63 M, n-hexane solution, 112 mL) was added dropwise, and after completion of the dropwise addition, the reaction was stirred at -70 °C for 2 hours. Subsequently, a solution of diethyl ether (50.0 mL) of trimethyl borate (22.8 g) was slowly added, gradually warmed to room temperature and continued stirring for 12 hours. Upon completion of the reaction, the reaction solution was cooled to -30°C, 6N hydrochloric acid (150 mL) was slowly added, gradually warmed to room temperature and stirred for 3 hours. The reaction mixture was poured into water and the aqueous layer was extracted with ethyl acetate. The organic layers were combined, washed with saturated brine and dried over anhydrous magnesium sulfate. The organic phase was concentrated under reduced pressure and the residue was purified by recrystallization from heptane to give (4-(4-propylcyclohexyl)phenyl)boronic acid (29.2 g, 78% yield).

References

[1] Patent: EP2957554, 2015, A1. Location in patent: Paragraph 0132

P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID Suppliers

A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
SL Drugs and Pharmaceuticals Pvt. Ltd.
Tel
--
Fax
--
Email
enquiry@sldrugs.com
Country
India
ProdList
2683
Advantage
50
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View Lastest Price from P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID 156837-90-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-28
Henan Fengda Chemical Co., Ltd
Product
[4-(trans-4-Propylcyclohexyl)phenyl]boronic acid 156837-90-0
Price
US $6.00-0.60/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-18
Career Henan Chemical Co
Product
P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID 156837-90-0
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2018-08-20

156837-90-0, P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACIDRelated Search:


  • [4-(4-Propylcyclohexyl)phenyl]boric acid
  • P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID
  • Boronic acid,B-[4-(4-propylcyclohexyl)phenyl]-
  • trans-[4-(4-propylcyclohexyl)phenyl]boronic acid
  • 4-trans-Propylcyclohexylphenylboronic acid
  • 156837-90-0